A New Reference Material for Tritium Organic Molecules in Sediment: Results of an International Intercomparison Exercise

Solid matrix ³H reference materials are challenging to prepare given the volatile nature of ³H and are often unrepresentative of the range of ³H forms that may be encountered during routine analysis. As a result, few ³H reference materials are currently available, undermining verification of analytical techniques for environmental ³H measurement. To address this, an International Working Group on Organically‐Bound Tritium Analysis determined to produce a tritium natural matrix reference material (NMRM). The reference material comprises marine sediment blended with sewage sludge contaminated with ³H‐organic species arising from authorised discharges from a radiopharmaceutical manufacturing site. Previous studies have demonstrated that the ³H species have persisted in the environment over three decades providing valuable supporting data to underpin the characterisation of the NMRM. The preparation and characterisation of the NMRM are described along with the subsequent application of the reference material in an international intercomparison exercise involving nineteen laboratories from nine countries. A reference value of 168 ± 22 Bq kg^?1 was derived from the data arising from the proficiency test.     

On the origin of bleaching phenomena in red bed sediments of Triassic Buntsandstein deposits in Central Germany

The Lower Triassic Buntsandstein in Central Germany comprises one of the major clastic, lithified hydrocarbon reservoirs, it is a major groundwater aquifer and it is considered as a potential underground gas storage lithology. Thus, sandstones of the Buntsandstein from Thuringia and NE Hesse were used to analyse their geochemical composition combined with mineralogical data in order to investigate the origin of several bleaching phenomena in primary red beds, since these give a hint for mineral alteration, mineral formation and mineral reactivity in the course of fluid-rock-interactions. This is relevant for e.g. recent Carbon Capture and Storage (CCS) efforts. The origin of the observed bleaching phenomena is diverse and it is linked to certain stages of diagenesis and different episodes of fluid flow: (1) eodiagenetic bleaching coupled with palaeosoil formation and iron mobilisation, (2) mesodiagenetic bleaching as a result of hydrocarbon migration, (3) Tertiary bleaching due to CO₂ degassing from Miocene volcanism, (4) Tertiary telodiagenetic bleaching due to weathering under humid climate conditions, and (5) weathering processes related to recent telodiagenesis/pedogenesis. This study emphasizes the multiple nature of fluids, which can induce iron mobilisation and bleaching of red beds.     

微波等离子体原子发射光谱法测定偏远矿区海泡石中的主微量元素

海泡石是具有层状结构的含水富镁硅酸盐黏土矿物,其中无机元素含量是揭示其成矿物质来源、成矿流体性质和矿床成因的重要依据,通常采用电感耦合等离子体发射光谱/质谱法(ICP-OES/MS)进行测定,等离子体(ICP)的高温激发会产生成大量谱线干扰,维持ICP稳定工作需使用高纯氩气,持续供气对于偏远矿区海泡石的检测还将面对气体采购和运输不便的问题。本文基于微波等离子体原子发射光谱(MP-AES)的低温激发技术减少光谱干扰,建立了准确测定偏远矿区海泡石中主量元素Mg、Al、Ca、Fe、K、Na和微量元素Cu、Zn、Mn、Pb含量的分析方法。利用硝酸-盐酸-氢氟酸混合酸对海泡石进行微波消解,避免了样品处理过程中分析元素的损失,加快了样品处理速度,同时提高了样品溶液的稳定性。通过选择各元素光谱线的分析波长,并利用快速线性干扰校正(FLIC)技术校正光谱干扰,以Lu为内标元素校正基体效应,提高了灵敏度和准确度。各元素的检出限为0.19～14.6μg/L。海泡石国家标准物质(GBW07138)各元素测定值与认定值的相对误差在-5.0%～6.7%之间。本方法具有检出限低、线性范围宽、结果准确等优点;MP-AES采用自带的氮气发生器为等离子体提供氮气作为工作气,无需引入复杂气体,提高了分析效率,尤其适用于气体采购和运输不便的偏远矿区。     

热屏障井对地下水源热泵换热影响模拟

对于场地受限的地下水源热泵项目,随着系统运行时间的增加易引发热贯通现象进而降低机组运行效率。地下水源热泵设计中,在抽灌水井连线间布设热屏障井可改变地下水流场,降低热量在抽灌井间的运移速度,有利于延长热贯通发生时间并缓解热贯通程度。通过构建地下水换热模型,模拟计算夏季制冷工况条件下36组热泵运行场景,分析了热屏障井的位置,过滤管长度及回灌量对热贯通和含水层温度场的影响规律。结果表明:热屏障井回灌量的增加有利于提升热屏障效果,但提升幅度随回灌量的增加逐渐减弱;最大水位降深值随着热屏障井回灌量的增加呈线性增长;增加热屏障井滤管长度可提升热屏障效果,提升效果随屏障井回灌量的增加逐渐增强。通过模型多周期、长时间模拟计算发现,热屏障井的运行可促使回灌的冷热量集中在回灌井一侧,对于采用冬夏季抽灌井交换运行模式的热泵系统,可充分利用含水层储能,提升机组运行效率。     

白涧铁矿南区复杂地层钻探施工技术

邢台白涧铁矿南区地层岩石破碎、部分地层含角砾、胶结性差、漏失严重,钻探施工中存在掉块卡钻、缩径、坍塌、埋钻及孔内泥浆全部漏失等难题。通过优化钻孔结构、使用新工艺、新方法,合理选择钻进参数,采用绳索取心钻进配合预留技术套管,有效解决了上部煤系地层的坍塌问题;采用反丝套管的方法,极大地减轻了由于地层缩径、掉块引起的套管下不到位、起拔困难等风险;常规型绳索取心钻杆替代套管方法的采用,提高了含角砾、松散地层的穿过速度,减少了钻探工作量的报废,加快了施工进度;特别是高胎体双水口钻头的使用,提高了钻进效率,节约了钻探施工成本,项目得以如期完成。     

Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.     

一次攀西地区飑线天气过程形成机制分析

利用地面气象常规观测资料、区域自动站观测资料、雷达及卫星资料和NCEP 1°×1°的逐6h再分析资料,对2018年5月13日攀西地区南部的飑线天气过程的形成机制进行分析。结果表明:飑线发生在高空槽前,高空槽逐渐东移推动冷性气流沿背风坡东移,然后与前方低层暖空气汇合抬升形成对流;露点锋触发了飑线天气过程的形成;产生飑线天气区域的大气具有上干下湿、不稳定能量高、垂直风切变强、高层风速大和形成之前存在逆温层的特点;高空急流和动量下传对飑线的发生和加强具有促进作用;地形对飑线的形成和天气现象的分布有影响。     

The nexus between nationally determined contributions and technology needs assessments: a global analysis

The role of technology in combatting climate change through mitigation and adaptation to its inevitable impacts has been acknowledged and highlighted by the Parties to the United Nations Framework Convention on Climate Change (UNFCCC). In the developing world, this has received particular attention through the technology needs assessment (TNA) process. As Parties put forward their national pledges to combat climate change, the scarcity of resources makes it important to assess (i) whether national processes designed to tackle climate change are working together and (ii) whether existing national processes should be terminated with the initiation of new ones. This study presents an assessment of the existing TNA process and its linkages to the nationally determined contributions (NDCs) under the Paris Agreement. The conclusions stem from an assessment of the TNAs completed to date, as well as 71 NDCs from developing countries at various stages of the TNA process. The analyses show that further developing the TNAs could play a vital role in filling gaps in the existing NDCs, specifically those relating to identifying appropriate technologies, their required enabling framework conditions and preparing implementation plans for their transfer and diffusion.

Key policy insights

• The full potential of the TNAs has still to be rolled out in many countries.

• Developing countries can maximize the potential of their TNAs by further developing them to explicitly analyse what is needed to implement existing NDCs, including by better aligning their focus, scope and up-to-dateness with the priority sectors included in the NDCs.

• Requests of developing countries for international assistance, through technology transfer, will be better guided by the completion of the TNA process.

• Policies for strengthening the NDCs will benefit from the results of completed, ongoing and future TNA processes.

     

基于ERA5的快速辐射传输模式与FY-4A成像仪观测结果的偏差分析

2016年12月发射升空的FY-4A是中国第二代静止轨道气象卫星,该星上搭载了可提供东半球近实时高分辨率卫星观测数据的扫描辐射成像仪——AGRI（Advanced Geostationary Radiation Imager）。在其观测数据应用于大气参数反演或同化前,数据偏差的定量化分析是一个必要环节。采用快速辐射传输模式RTTOV（Radiative Transfer for the TIROS Operational Vertical Sounder）,基于欧洲中期天气预报中心（ECMWF）第5个全球再分析数据产品（ERA5）对AGRI的7个红外通道（通道08—14）进行了模拟,并利用MODIS云检测产品对模拟结果进行了晴空筛选,以期得到一些对AGRI的定量应用有价值的偏差分析结果。观测-模拟（O-B）的偏差分析结果显示:海洋和陆地上,通道10（7.1 μm）存在明显大于其他红外通道的系统性偏差,这很可能来源于ERA5在对流层中层对水汽的高估。通道08为近红外短波通道,地表反射作用影响强烈,陆地上存在较大的平均偏差,而海洋上平均偏差小于0.4 K。通道14在ERA5近地层气温偏高及定标偏差的影响下,海洋存在接近1 K的平均偏差;陆地上存在2 K左右的平均偏差。其余各红外通道在海洋和陆地上的平均偏差分别在0.6和1.3 K以下。偏差影响因子分析结果显示:地表海拔高度、观测天顶角对偏差也存在一定程度的影响;海洋上偏差分布存在季节变化可能来源于再分析资料中海表温度估算的季节性误差。      

那曲高寒草地总体输送系数及地面热源特征

利用中国科学院那曲高寒气候环境观测研究站那曲/BJ观测点的野外观测数据,估算了青藏高原那曲地区典型高寒草地下垫面的热量和水汽总体输送系数以及地表大气相对湿度因子,在此基础上利用中国气象局那曲气象站1980-2016年的常规业务观测数据,采用总体输送法计算并分析了那曲高寒草地地表通量特征。研究结果表明:(1)那曲/BJ观测点地表大气相对湿度因子γ的数值在33%~62%,9月最大,2月最小,热量和水汽输送系数CH和Cλ的季节变化范围分别在1.6×10^-3~2.7×10^-3和1.0×10^-3~2.0×10^-3,两者存在较大的差异。(2)1980-2016年那曲高寒草地感热通量总体呈现减弱趋势,而潜热通量呈现增强趋势,导致地面热源变化趋势不明显;分阶段来看,感热通量的变化在2004年前后发生转折,转折点前后的趋势为先减弱后增加,潜热通量在1994-2005年下降趋势明显,这也导致地面热源在1995-2005年有一个明显的减少。(3)年内季节变化上潜热通量相较于感热通量更明显,地面热源的季节变化更依赖于潜热通量的季节变化。