湖南郴州南风坳银矿床银的赋存状态及分布规律

南风坳银矿是产于震旦系浅变质碎屑岩中受北北东—北东向断裂控制的热液充填交代型矿床。矿床中银主要以银矿物存在，次为类质同像。银的载体矿物主要为方铅矿，次为铁闪锌矿、黄铜矿、黄铁矿、毒砂等。已查明的银矿物15种，常见的10种，主要的银矿物为银黝铜矿和黝锑银矿，它们多呈显微包体分布在载银矿物中。银在矿区中部(03-17线)980m～1036m标高范围内富集。银与铅关系密切，银在富铅矿体中富集。     

Laser Ablation ICP-MS Analysis of Geological Materials Prepared as Lithium Borate Glasses

A simple, rapid and precise method is described for determining trace elements by laser ablation (LA)-ICP-MS analysis in bulk geological materials that have been prepared as lithium borate glasses following standard procedures for XRF analysis. This approach reliably achieves complete sample digestion and provides for complementary XRF and LA-ICP-MS analysis of a full suite of major and trace elements from a single sample preparation. Highly precise analysis is enabled by rastering an ArF excimer laser (λ= 193nm) across fused samples to deliver a constant sample yield to the mass spectrometer without inter-element fractionation effects during each analysis. Capabilities of the method are demonstrated by determination of twenty five trace elements (Sc, Ti, V, Ga, Rb, Sr, Y, Zr, Nb, Cs, Ba, REE, Hf, Ta, Pb, Th and U) in a diverse range of geological reference materials that includes peridotites, basalts, granites, metamorphic rocks and sediments. More than 90% of determinations are indistinguishable from published reference values at the 95% confidence level. Systematic bias greater than 5% is observed for only a handful of elements (Zr, Nb and U) and may be attributed in part to inaccurate calibration values used for the NIST SRM 612 glass in the case of Zr and Nb. Detection limits for several elements, most notably La, are compromised at ultra-trace levels by impurities in the lithium borate flux but can be corrected for by subtracting appropriate procedural blanks. Reliable Pb analysis has proved problematic due to variable degrees of contamination introduced during sample polishing prior to analysis and from Pt-crucibles previously used to fuse Pb-rich samples. Scope exists for extending the method to include internal standard element/isotope spiking, particularly where integrated XRF analysis is not available to characterise major and trace elements in the fused lithium borate glasses prior to LA-ICP-MS analysis.     

A Reappraisal of Rb, Y, Zr, Pb and Th Values in Geochemical Reference Material BHVO-1

The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1).     

河北省黄壁庄水库坝基渗漏单井示踪试验研究

以河北省黄壁庄水库副坝坝基的渗漏塌坑为例，利用“九五”国家重点科技成果推广项目“智能化地下水动态参数测量仪”在天然流场下，测量出水库自然渗漏量地下水的渗透流速流向、垂直向流速流向，每米含水层的渗透系数等工程必须的水文地质参数。确定性地诊断和检测出黄壁水库坝基渗漏隐患出现的具体位置和高程，从而为大坝的渗漏处理和安全处理提供详细的现场测量数据。     

Column Amounts of ClONO2, HCl, HNO3, and HF from Ground-Based FTIR Measurements Made Near Kiruna, Sweden, in Late Winter 1994

During SESAME phase I ground-based FTIR measurements were performed atEsrange near Kiruna, Sweden, from 28 January to 26 March 1994. Zenith columnamounts of ClONO₂, HCl, HF, HNO₃,O₃, N₂O, CH₄, and CFC-12 werederived from solar absorption spectra. Time series of ClONO₂and HCl indicate a chlorine activation at the end of January and around 1March. On 1 March a very low amount of HCl of 2.09times; 10¹⁵molec. cm^-2 was detected, probably caused by a second chlorineactivation phase starting from an already decreased amount of HCl. The ratioof column amounts of HCl to ClONO₂ decreased inside the vortexfrom about 1 in January to 0.4 in late March compared to values of about 2outside the vortex. Although the Arctic stratosphere was rather warm in winter1993/94 and PSCs occurred seldom, chlorine partitioning into its reservoirspecies HCl and ClONO₂ changed during that winter andClONO₂ is the major chlorine reservoir at the end of thewinter as in cold winters like 1991/92 and 1994/95.     

贵州贵阳地区下三叠统凝缩段的遗迹化石特征

贵阳地区下三叠统是一个完整的碳酸盐岩层序（相当于三级旋回层序）．该层序中的凝缩段由深色薄层（单层厚0．5cm～1cm）的泥晶灰岩和泥质条带灰岩组成．凝缩段中产丰富的遗迹化右．该遗迹群落为：Cochlichnus,Cosmorhaphe,Chondrites,Gordia,Huaxich－nus，Oldhamia,Phycosiphon.Protopaleodictyon,Pinnatpedus,Mammillichnus,Neonerites和生物扰动构造．遗迹化石组合与Nereites遗迹相相似。此外，文本还讨论了此遗迹群落的形成原因。     

锇粉中杂质元素分析方法研究

利用ＩＣＰ＿ＭＳ技术建立了锇粉中痕量杂质元素的分析方法。在浓ＨＮＯ３介质中，锇以ＯｓＯ４形式挥发除去，分离锇基体后，可直接测定的痕量元素达５０余种。取样量０．１ｇ，测定限为０．２～２４６ｎｇ／ｇ，可实现质量分数ｗ（Ｏｓ）为９９．９９９９％锇粉中杂质元素测定。结合ＩＣＰ＿ＡＥＳ测定Ｋ、Ｎａ、Ｃａ、Ｍｇ、Ａｌ、Ｆｅ、Ｓｉ和Ｐ，可实现锇粉原料及产品的纯度分析。     

新疆阿拉尔花岗岩MFC过程的微量元素综合效应

新疆阿拉尔花岗岩的微量元素比相关图显示了线性样点列与幂函数曲线形式的样点列相 复杂图型。该图型用简单混合或者单一结果分异模型都不能解释。本文建立了混合－结晶分异复合过程的微量元素综合效应模型。模型１：从初始混合线引起害虫函数曲线束形式的结晶分异线。特殊情况有结晶分异线简化为通过原点的直线束形式或者与初始混合线重合。     

粤东北嵩溪银锑矿床地质地球化学初步研究

粤东北嵩溪银锑矿床地质地球化学初步研究肖振宇郑庆年（广东有色金属地质勘查院，广州５１００８０）陈繁荣张湖（中国科学院广州地球化学研究所，广州５１０６４０）关键词地质地球化学银锑矿床嵩溪嵩溪银锑矿床发现于粤东北地区，有嵩溪、黄沙塘等矿床和梅子坑、仙客社...