Molecular and bulk isotopic analyses of organic matter in marls of the Mulhouse Basin (Tertiary, Alsace, France)

Contents of 13C in kerogens and carbonates in 21 samples from a core of the MAX borehole, Mulhouse Evaporite Basin, range from -27.3 to -23.5 and -3.7 to -1.8% vs PDB, respectively. Organic nitrogen in the same samples is enriched in 15N relative to atmospheric N2 by 12.2-15.7%. Hydrogen indices and delta values for kerogens vary systematically with facies, averaging 493 mg HC/g Corg and -25.7% in the most saline facies (dominated by inputs from aquatic sources) and 267 mg HC/g Corg and -23.7% in the least saline facies (50/50 aquatic/terrigenous). Values of delta were measured for individual aliphatic hydrocarbons from three samples representing three different organic facies. For all samples, terrigenous inputs were unusually rich in 13C, the estimated delta value for bulk terrigenous debris, apparently derived partly from CAM plants, being -22.5%. In the most saline facies, isotopic evidence indicates the mixing of 13C-depleted products of photosynthetic bacteria with 13C-enriched products of halotolerant eukaryotic algae. At lower salinities, a change in the producer community is marked by a decrease in the 13C content of algal lipids. The content of 13C in algal lipids increases in the least saline facies, due either to succession of different organisms or to decreased concentrations of dissolved CO2.     

稳健总体最小二乘Helmert方差分量估计

对于总体最小二乘而言,经常需要处理不同精度或者不同类型的观测数据,根据先验方差来定权往往不准确,同时观测数据中可能含有粗差。针对这两个问题,提出稳健总体最小二乘Helmert方差分量估计,将稳健估计和Helmert方差分量估计同时应用于总体最小二乘中。最后通过两个实验的计算结果表明,该方法是可行的、有效的。     

我国地质勘查行业全要素生产率测算分解实证研究北大核心CSCD

研究地质勘查行业发展战略时应充分考虑技术进步对行业发展的贡献。本文以2010~2020年全国31省(区、市)非油气地质勘查单位的投入产出数据为样本,基于DEA-Malmquist指数法测算了我国地质勘查行业近十年的全要素生产率(TFP)变化,结合技术进步率(TP)、技术效率(EC)、纯技术效率(PC)和规模效率(SC)等分解项得出:我国地质勘查行业近十年平均全要素生产率指数偏低,其主要原因是技术进步率较低,因为技术进步率与我国地质勘查行业的发展水平关系密切。各地区地质勘查行业发展不平衡,西部地区地质勘查行业的TFP指数普遍高于东部地区和中部地区,但大量的资产和劳动力投入仍在东部地区,导致市场资源配置的扭曲,是我国地质勘查行业TFP指数整体偏低的重要原因。     

Bacterial contribution to sedimentary organic matter; a comparative study of lipid moieties in bacteria and Recent sediments

A systematic study of the lipid composition of thirteen bacterial species and three Recent sediments (methanogenic sediment, cyanobacterial mat and evaporative gypsum crust) was undertaken in an attempt to recognize bacterial organic matter in sediments. A sequential method, which distinguishes between three different modes of occurrence of lipid moieties (free, OH⁻- and H⁺-labile), was applied. The acid-labile fractions are discussed.The three main groups of bacteria, archaebacteria, gram-positive eubacteria and gram-negative eubacteria, are easily distinguished. Methanogenic and extremely halophilic archaebacteria are characterized by the presence of diphytanyl glyceryl ether and the absence of fatty acids. The gram-positive eubacteria contain primarily iso- and anteiso-branched fatty acids whereas the gram-negative bacteria and sediments are dominated by β- and α-hydroxy fatty acids. A wide variety of H⁺-labile hydroxy fatty acids was observed which included several, as yet unknown, structures.β-Hydroxy fatty acids in this H⁺-labile mode of occurrence are exclusively present in bacteria. Their distribution patterns in sediments are considered “fingerprints” of past and present bacterial populations. The specific differences in β -hydroxy fatty acid compositions observed in the different bacteria and the three sediments investigated, suggest that amide-linked β-hydroxy fatty acid patterns are useful as markers of bacterial populations and therefore of environmental conditions.     

Carbon isotopic studies of individual lipids in organisms from the Nansha sea area, China

Sediments contain abundant lipid compounds in general, which are used as biomarker compounds to study organic matter sources and reconstruct the pa-laeoenvironments[1—7]. However, lipid compounds in sediments are generally a mixture of various genetic components so that it is difficult to correctly decouple their biological sources only by the results of bio-chemical researches. Carbon isotopic studies of indi-vidual sedimentary lipid compounds can discover their genetic information, which pr…     

The importance of atmospheric input of terrestrial organic material to deep sea sediments

The concentrations of lipids were determined in atmospheric particle, gas and rain samples collected from the tropical North Pacific to assess lipid sources, transport mechanisms and fluxes to the ocean surface. Four lipid compound classes (aliphatic hydrocarbons, fatty alcohols, fatty acid esters, and salts) all unequivocally show a terrestrial vascular plant source. These aerosol lipids originate from wind erosion of Asian and American soils and direct emission from vegetation. The major fluxes result from rain rather than dry deposition. These fluxes are large enough to have a major potential impact on the inventory of terrestrially derived lipid material found in deep-sea sediments. This has been showm for n-alkanes, fatty alcohols, fatty acids, total lipids and for organic carbon. By comparing atmospheric and sediment trap fluxes with sediment accumulation rates, it is suggested that some biogenic terrestrial material is more protected from degradation than marine-derived material.     

应用全站仪进行淹没面积三角高程测量

使用跟踪杆配合全站仪测量高程的方法越来越普及,这是由于传统的三角高程测量方法已经显示出了局限性。经过对辽河淹没面积测量的探索,总结出一种新的方法进行三角高程测量,既结合水准测量任意置站的特点,减少了三角高程的误差来源,每次测量时不必量取仪器高、棱镜高,又使三角高程测量精度进一步提高,施测速度更快。     

水污染物总量综合权重系数分配方法研究

区域污染物排放总量分配是水污染总量控制的重要内容,分配合理与否将直接影响总量控制工作成效。以陆域排污-水体水质响应空间单元为基础,构建了综合考虑水环境质量、排污及污染治理水平、区域经济实力等因素的总量分配指标体系,提出一套单元的水污染物总量分配综合权重系数计算方法。并将该方法应用于北京市,结果表明本方法较好地解决了目前分配方法中总量目标与水质改善需求衔接不足、分配指标体系过于单一的问题。     

总氮对土物理力学性能影响的试验研究

通过室内试验,考察了去离子水及不同浓度总氮溶液对土体物理力学性能的影响,并通过土体矿物成分含量及微观形貌分析,对总氮溶液与土体作用机制进行了初步探讨。结果表明,总氮对土体物理力学性能影响明显：（1）土体塑性指数、相对密度和有效黏聚力随总氮溶液浓度增大而减小,有效内摩擦角随溶液浓度的增大而增大;（2）各浸泡条件下,土体应力-应变关系曲线变化规律基本一致,均呈应变硬化现象,土体剪切峰值随总氮溶液浓度的增大先减小后增大;（3）孔隙水压力随轴向应变的增加先增加,然后缓慢降低,最后曲线逐渐趋于水平,表现出较大的剪胀性;（4）总氮溶液与土体间相互作用主要包括离子交换作用、微生物分解作用和溶蚀及胶结作用,这些作用通过改变土体的矿物成分含量,使其微观形貌及孔隙特征发生明显变化,最终导致土体的宏观力学特性改变。