Metamorphic P–T conditions and thermal structure of Chinese Continental Scientific Drilling main hole eclogites: Fe–Mg partitioning thermometer vs. Zr-in-rutile thermometer

Core rocks recovered from the main hole (5158 m deep) of the Chinese Continental Scientific Drilling (CCSD‐MH) project, southern Sulu UHP terrane, east‐central China, consist of eclogites, various gneisses and minor metaperidotite cumulates; this lithological section underwent subduction‐zone UHP metamorphism. Coesite‐bearing eclogites are mainly present between the depths of 100–2000 m, but below 2000 m, mafic eclogites are rare. Selected elements (Zr, Nb, Cr, Fe, Si, Mg, Al & Ti) in rutile from 39 eclogite cores from 100 to 2774 m, and major elements of minerals from representative eclogites were analysed by electron microprobe. Zirconium and Nb concentrations of rutile cluster ～100–400 and 200–700 ppm respectively. However, Zr and Nb contents in rutile from strongly retrograded eclogites show larger variations than those of fresh or less retrograded eclogites, implying that somehow fluid infiltration affected rutile chemistry during retrograde metamorphism. Zr contents in rutile inclusions in garnet and omphacite are slightly lower than those of the matrix rutile, suggesting that the rutile inclusions formed before or close to the peak temperature. The P–T conditions of the CCSD‐MH eclogites were estimated by both Fe–Mg exchange and Zr‐in‐rutile thermometers, as well as by the Grt–Cpx–Phn–Ky geothermobarometer. The maximum temperature range of 700–811 °C calculated at 40 kbar using the Zr‐in‐rutile thermometer is comparable with temperature estimates by the Fe–Mg exchange thermometer. The temperature estimates of eclogites in a ～3000 m thick section define a continuous gradient, and do not show a distinct temperature gap, suggesting that the rocks from 100 to 3000 m depth might belong to a single, large‐scale UHP slab. These data combined with P–T calculations for CCSD‐MH peridotites yield a low geotherm (～5 °C km^?1) for the Triassic subduction zone between the Sino‐Korean and Yangtze cratons; it lies ～30–35 mW m^?2 conductive model geotherm.     

加拿大Slave 克拉通橄榄岩的平衡温压计算

加拿大Slave克拉通Jericho金伯利岩筒携带的橄榄岩包体提供了研究大陆岩石圈地幔物质组成和热结构的窗口。文章总结了地幔岩矿物温压计的研究进展,测量了Jericho金伯利岩携带的9个新鲜橄榄岩包体的矿物主量元素和微量元素,并使用不同的矿物温压计估算了平衡温度和压力。结果表明Nickel 和 Green（1985）的石榴子石—斜方辉石压力计可以较好地估算含石榴子石橄榄岩形成时的压力,Taylor（1998）二辉石温度计和Nimis 和 Taylor（2000）单斜辉石温度计的计算结果一致。具有粗粒变晶结构的尖晶石—石榴子石橄榄岩和石榴子石橄榄岩样品的平衡温度为575~843℃,压力为2.4~3.6 GPa,表明Slave克拉通岩石圈地幔温度较低。而残斑结构尖晶石—石榴子石二辉橄榄岩的平衡温度1109℃,压力为5.0 GPa,来源深度为~156 km,可能被早期金伯利岩浆携带到岩石圈地幔中部冷却,然后再被侏罗纪喷发的Jericho金伯利岩筒带到地表。使用石榴子石—单斜辉石稀土元素温压计获得的平衡温度高于主量元素温度计的结果,表明Slave克拉通岩石圈地幔经历了逐渐冷却的过程。此外,Slave克拉通浅部的尖晶石橄榄岩保留了强烈亏损的早期岩石圈地幔特征,而下部的岩石圈地幔经历了金伯利岩熔体和硅酸盐熔体的交代作用。     

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西沙珊瑚锶温度计：便捷高精度海洋古水温代用指标

西沙群岛现代滨珊瑚1976－1994年生长期间Sr含量的高精度热电离质谱测定结果表明，Sr含量随季节发生周期性的变化，并与当地同期实测海水月平均温度变化相吻合，其Sr含量与实测海水温度相关系数为－0．94。这18年冬夏极端Sr含量与同期月温的相关系数可高达－0．98。Sr温度计误差小于0．5℃。     

菱切面角温度计作为形变温度计在五台山区的应用

肖钠双晶主要在形变过程中产生,它的结合面是菱形切面。菱形切面的位置既取决于斜长石的化学成分,也取决于它的结构状态。后者本身就是温度的函数。因此,菱切面的位置取决于形变时的温度。在五台山区峨口花岗岩内获得了49个菱切面角温度值。从直方图上可以看出存在有520℃和480℃的两个峰。这温度与围岩的石榴石—黑云母对494—508℃的温度对应。它意味着形变温度与绿片岩相变质温度一致。在五台山区绿片岩相变质时观察到两期形变作用,这与两个温度峰相符。因此,利用菱切面角温度计可以研究形变与变质的关系。     

Petrographic features of a high-temperature granite just newly solidified magma at the Kakkonda geothermal field, Japan

A 3729-m-deep geothermal research well, WD-1a, provides us with a unique opportunity to study initial petrographic features of a high-temperature granite just after solidification of magma. The well succeeded in collecting three spot-cores of the Kakkonda Granite that is a pluton emplaced at a shallow depth and regarded as a heat source of the active Kakkonda geothermal system. The core samples were collected at the present formation temperatures of 370, 410 and over 500°C. These samples are granodiorite to tonalite consisting mainly of plagioclase, quartz, hornblende, biotite and K-feldspar. A sample collected at a formation temperature of over 500°C possesses the following remarkable petrographic features compared to the other two samples. Interstitial spaces are not completely sealed. K-feldspar exhibits no perthite by the exsolution of albite lamella. Quartz includes glassy melt inclusions without devitrification. Hornblende is less intensively altered to actinolite, and biotite is not altered. This study directly confirmed that perthite in K-feldspar is a recrystallization texture formed at 410–500°C based on a comparison of the in situ temperatures of the samples. Chemical compositions of minerals were analyzed to compare temperatures determined from geothermometers in several publications to the in situ temperatures of the samples.     

高精度温度计在同层水温平行观测中的互相干扰现象

在2015年4月24日一次意外供电故障中,发现宁波地震台高精度温度计在井水温度同层平行观测中有明显的互相干扰现象。认为目前水温观测到的是水井内实际温度与传感器工作时的"升温值"之和,而"升温值"是动态值,其取决于每套仪器的系统特性,一般可能会在0.01℃以上;相互影响可能在0.005℃以上,如果是捆绑式平行观测可能会更高。所以水温测值的波动范围为10~(-4)℃的观测井中,这种干扰不可忽视,并可能影响前兆异常的提取。因此,在水温波动比较小的观测井(泉)中,不主张做同层平行对比观测。最好在一个传感器内安装2套探测温度装置,既免互相干扰,又可相互验证。     

A new formulation of garnet–clinopyroxene geothermometer based on accumulation and statistical analysis of a large experimental data set

Published experimental data including garnet and clinopyroxene as run products were used to develop a new formulation of the garnet–clinopyroxene geothermometer based on 333 garnet–clinopyroxene pairs. Only experiments with graphite capsules were selected because of difficulty in estimating the Fe³⁺ content of clinopyroxene. For the calibration, a published subregular‐solution model was adopted to express the non‐ideality of garnet. The magnitude of the Fe–Mg excess interaction parameter for clinopyroxene (W_FeMg^Cpx), and differences in enthalpy and entropy of the Fe–Mg exchange reaction were regressed from the accumulated experimental data set. As a result, a markedly negative value was obtained for the Fe–Mg excess interaction parameter of clinopyroxene (W_FeMg^Cpx = ? 3843 J mol^?1). The pressure correction is simply treated as linear, and the difference in volume of the Fe–Mg exchange reaction was calculated from a published thermodynamic data set and fixed to be ?120.72 (J kbar^?1 mol^?1). The regressed and obtained thermometer formulation is as follows: where T = temperature, P = pressure (kbar), A = 0.5 X_grs (X_prp ? X_alm ? X_sps), B = 0.5 X_grs (X_prp ? X_alm + X_sps), C = 0.5 (X_grs + X_sps) (X_prp ? X_alm), X_prp = Mg/(Fe²⁺ + Mn + Mg + Ca)^Grt, X_alm = Fe/(Fe²⁺ + Mn + Mg + Ca)^Grt, X_sps = Mn/(Fe²⁺ + Mn + Mg + Ca)^Grt, X_grs = Ca/(Fe²⁺ + Mn + Mg + Ca)^Grt, X_Mg^Cpx = Mg/(Al + Fe^total + Mg)^Cpx, X_Fe^Cpx = Fe²⁺/(Al + Fe^total + Mg)^Cpx, K_D = (Fe²⁺/Mg)^Grt/(Fe²⁺/Mg)^Cpx, Grt = garnet, Cpx = clinopyroxene. A test of this new formulation to the accumulated data gave results that are concordant with the experimental temperatures over the whole range of the experimental temperatures (800–1820 °C), with a standard deviation (1 sigma) of 74 °C. Previous formulations of the thermometer are inconsistent with the accumulated data set; they underestimate temperatures by about 100 °C at >1300 °C and overestimate by 100–200 °C at <1300 °C. In addition, they tend to overestimate temperatures for high‐Ca garnet (X_grs ≈ 0.30–0.50). This new formulation has been tested against previous formulations of the thermometer by application to natural eclogites. This gave temperatures some 20–100 °C lower than previous formulations.     

热带海洋珊瑚Sr/Ca、Mg/Ca温度计的研究及其意义

珊瑚以其独特的生物学及生态学特性成为研究热带海洋环境的重要信息载体。阐明了珊瑚微量元素Sr／Ca、Mg／Ca温度计的建立基础、测定方法、研究成果、环境意义、争论问题及进一步研究的设想。多种海表温度计的对比研究,为现代和古海洋环境的重建、探索气候的变率与特征事件(冷暖、旱涝、ENSO等)的关联以及为预测未来气候变化的趋势提供科学的判据。     

长沙市夏季百叶箱内外温度特征

对长沙市2011、2012年夏季(6—9月)百叶箱内外温度同步观测资料进行统计分析,结果表明:百叶箱内外温度呈现白天箱外温度高于箱内,晚上低于箱内的日变化特征,但不同类型天气交替时间存在早晚不一。箱内外夏季平均温度、极端最高温度的变化趋势一致,但箱外温度高于箱内,且不同类型天气百叶箱内外温度存在差异,阴雨天平均相差1.2℃,多云差2.8℃,晴天差3.1℃,极端最高温差达6.4℃。特别是日最高温度大于等于35℃的高温日数,2年箱内共出现61天,而箱外多达125天;箱内极端最高温度为38.9℃,而箱外极端最高温度高达42.0℃。因此,在高温预报和公共气象服务工作中,应当要考虑外界温度(百叶箱外温度)与百叶箱内温度之间存在的差异。