利用奇异谱分析提高极移中长期预报精度

由于空间大地观测数据传输耗时及处理过程复杂, 导致极移测量值的获取存在时延, 无法满足对高精度的极移预报值有重大需求的应用领域. 针对极移复杂的时变特性, 提出一种基于奇异谱分析(singular spectrum analysis, SSA)的预报方法. 首先用SSA分离提取极移时序中的高频组分与低频组分; 其次建立最小二乘(least square, LS)外推与自回归(AutoreGressive, AR)模型对极移高频和低频组分进行组合预报. 结果表明, SSA方法能够准确地分离和提取极移低频和高频组分, 对低频和高频组分组合预报可以显著改善极移的中长期(30--365d)预报精度, 与国际地球自转和参考系服务局(International Earth Rotation and Reference Systems Service, IERS)提供的A公报中的极移预报值相比, SSA方法对极移PMX分量(本初子午线方向)和PMY分量(西90$^\circ$子午线方向)的中长期预报精度改进最高分别可达45.97%和62.44%. 研究结果验证了SSA方法对极移中长期预报改进的有效性.     

多媒体教学模式下大学英语课堂教师话语的调查与分析

通过课堂录音、课堂观察和问卷调查的方法,对多媒体教学模式下的大学英语课堂教师话语在话语量、话语内容、提问方式、反馈方式等方面的特点进行系统分析。研究结果表明,多媒体教学模式下,大学英语课堂教师话语呈现出传统的以教师为中心的主题教学模式的特点。     

Gold and Platinum-Group Element Analysis of Geochemical and Platinum Reference Materials Using Fluoroxidation Decomposition

A novel method is described for the rapid dissolution of various geological, geochemical and related reference samples for the determination of Au and the platinum-group elements. The decomposition procedure is based on reaction with the fluoroxidants, liquid bromine trifluoride or molten potassium tetrafluorobromate. Results by this novel procedure are compared with data obtained by traditional methods of sample decomposition, including fire assay, autoclave techniques and an aqua regia leach. The oxidative fluorination procedure with the subsequent conversion of fluorocomplexes into the chloride form was found to be an effective and rapid method for the quantification of all the precious metals in a range of sample types.     

硫化物矿物标准物质的研制

研制的黄铁矿、黄铜矿、方铅矿和闪锌矿４个标准物质是国内首次成功研制的硫化物矿物成分分析标准物质,样品采用重选,磁选和电磁选等选矿技术提纯矿物,获得纯度大于９５％的单矿物样品。黄铁矿和闪锌矿用棒磨机少量多级粉碎至０．１４７ＭＭ,方铅矿和黄铜矿用于小型玛瑙球磨机粉碎至０．０９７ＭＭ。经单因素方差分析检验,均匀性符合要求,采用小包装在干燥,充氩气气氛中保存样品,使样品稳定性有足够保证。连续４年定期监测了     

PLC控制的教学机械手

介绍一台可编程控制器（PLC）教学机械手的研制。它是一个水平／垂直位移的机械设备，用来将工件由左工作台搬到右工作台，在PLC控制下可实现手动及自动等多种工作方式，为学习PLC的原理及应用提供一种理想的示教装置。     

Determination of the Platinum-Group Elements and Gold in Twenty Rock Reference Materials by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) after Pre-Concentration by Nickel Sulfide Fire Assay

The platinum-group elements (PGE) and gold have been determined in twenty international rock reference materials by inductively coupled plasma-mass spectrometry (ICP-MS) after pre-concentration by a nickel sulfide fire assay. It was possible to achieve determination limits for a 50 g sample that ranged from 1 pg g^-1 (Rh) to 23 pg g^-1 (Au). Compared to published certified and recommended values for rock reference materials, the trueness of the method was found to be good. However, in some cases we observed large deviations for all elements in the sub 10 ng g^-1 range within individual reference sample splits. Our results show that the PGE and Au are inhomogeneously distributed in the reference materials analysed here, where they are present in low concentrations, using 50 g test portions.     

Platinum-Group Element Geochemical Certified Reference Materials (GPt1-7)

Unlike the situation for other elements, few reference materials certified for the platinum-group elements are currently available. Therefore, the GPt1-7 series of PGE geochemical CRMs, prepared by the IGGE, represent an important addition and comprise a range of matrix types, including a soil, stream sediment, Mg-rich ultramafic rock, Fe-rich ultramafic rock, platinoid ore depleted in Cu, Ni and Fe, and a chromitite. The concentration of PGE in these samples ranges over 4-5 orders of magnitude and the samples were shown to have good homogeneity as assessed by a variance test. Analytical methods based on different principles were used in sample certification, including several fire assay and wet chemical procedures used for decomposition and preconcentration. Certified values for the elements Pt, Pd, Os, Ru, Ir, Rh and Au were determined by AAS, catalytic colourimetry (COL), catalytic polarography (POL), atomic emission spectrometry (AES), ICP-MS and NAA. Recently, the GPt1-7 samples were approved as national primary CRMs by the State Bureau of Technical Supervision of China.     

In Situ Determination of Au and Cu in Natural Pyrite by Near‐Infrared Femtosecond Laser Ablation‐Inductively Coupled Plasma‐Quadrupole Mass Spectrometry: No Evidence for Matrix Effects

Gold and copper concentrations were determined in natural pyrite by near‐infrared femtosecond LA‐ICP‐QMS, using both sulfide reference materials (pyrrhotite Po‐726 and in‐house natural chalcopyrite Cpy‐RM) and NIST SRM 610 as external calibrators. Firstly, using NIST SRM 610 as the external calibrator, we calculated the Au concentration in Po‐726 and the Cu concentration in Cpy‐RM. The calculated concentration averages for Au and Cu were similar to the values published for Po‐726 and Cpy‐RM, respectively. Secondly, we calculated Au and Cu concentrations taking NIST SRM 610 as an unknown sample and using Po‐726 and Cpy‐RM as external calibrators. Again, the average values obtained closely reflected the preferred concentrations for NIST SRM 610. Finally, we calculated Au and Cu concentrations in natural pyrite using sulfide and silicate reference materials as external calibrators. In both cases, calculated concentrations were very similar, independent of the external calibrator used. The aforementioned data, plus the fact that we obtained very small differences in relative sensitivity values (percentage differences are between 5% and 17% for ⁵⁷Fe, ⁶³Cu and ¹⁹⁷Au) on analyses of silicate and sulfide RMs, indicate that there were no matrix effects related to the differences in material composition. Thus, it is possible to determine Au and Cu in natural sulfides using NIST silicate glasses as an external calibrator.     

Composition-Induced Variations in SIMS Instrumental Mass Fractionation during Boron Isotope Ratio Measurements of Silicate Glasses

An analytical artefact is reported here related to differences in instrumental mass fractionation between NIST SRM glasses and natural geological glasses during SIMS boron isotope determinations. The data presented demonstrated an average 3.4‰ difference between the NIST glasses and natural basaltic to rhyolitic glasses mainly in terms of their sputtering-induced fractionation of boron isotopes. As no matrix effect was found among basaltic to rhyolitic glasses, instrumental mass fractionation of most natural glass samples can be corrected by using appropriate glass reference materials. In order to confirm the existence of the compositionally induced variations in boron SIMS instrumental mass bias, the observed offset in SIMS instrumental mass bias has been independently reproduced in two laboratories and the phenomenon has been found to be stable over a period of more than one year. This study highlights the need for a close match between the chemical composition of the reference material and the samples being investigated.     

193nmLA-ICPMS对国际地质标准参考物质中42种主量和微量元素的分析

本文采用配备有 193nm Ar F准分子 (excimer)激光器的 Geo L as2 0 0 M剥蚀系统和 Elan6 10 0 DRC ICP- MS对 4个美国地质调查所 (USGS)玻璃标准参考物质以及 3个美国国家标准技术研究院 (NIST)人工合成硅酸盐玻璃标准参考物质中几乎覆盖整个质量数范围 (从 7L i到 2 38U)的 38个微量和 4个主量 (Na、Mg、Ti和 Mn)元素进行了分析。分析结果表明 ,无论是对 USGS还是 NIST玻璃 ,元素分析的相对标准偏差 RSDs和分析值与参考值之间的相对偏差 (RDs)一般优于 10 % ,RSD和RD较大的元素主要出现在含量很低或不均匀样品中。稀土元素的 RSD显示 ,除 AGV- 2 G可能存在不均匀现象外 ,其它所测样品在 6 0 μm尺度上 ,元素分布是均匀的。本研究证明 ,由于 ICP- MS具有 10 8cps(每秒计数 )的动态线性范围 ,本实验室的L A- ICPMS系统可定量分析含量在百分之几的主量元素及微量元素。分析精密度和准确度可与常规溶液雾化进样 ICP- MS方法相媲美