几丁糖酯原料药稳定性研究

该文建立高效凝胶渗透色谱法 (HPGPC) ,明胶比浊法 ,氧瓶燃烧法三种分析方法考察海洋硫酸多糖药物几丁糖酯的稳定性 ,采用这三种方法分别考察几丁糖酯原料药在高温、高湿、强光照射及加速条件下分子量及分布宽度、样品中硫酸根含量及样品含量的变化情况。结果表明 :三种方法均适用于几丁糖酯的稳定性考察 ,几丁糖酯在上述影响因素条件下稳定性良好     

南海东北部表层沉积中生源和矿物碎屑组分分析及其古环境意义

通过对南海东北部128个表层沉积样品的定量研究，揭示隆源和矿物碎屑各组分的分布，也显示了组分分析作为一种简单、快速的研究方法在海洋古环境研究中的潜力，研究区生源碎屑的分布明显受与水深相关的深海溶解作用所控制，水深3500-4000m的现代南海CCD以下，钙质生物的含量急剧减少，而硅质生物的含量急剧增加，研究区表层沉积中的碎屑矿物主要来源于亚洲大陆，吕宋镐的风化产物只起次要作用，且其分布主要受与离岸距离远近和海流相关的搬运作用所控制。     

东营城区高精度三维地震采集方法研究

根据东营城区内建筑物较多，环境干扰较大，地下构造复杂，断裂非常发育，目的层埋藏深，资料信噪比较低的特点，以地震老资料和钻井资料为基础，建立地震地质模型，利用射线追踪技术选取合适的观测系统参数。充分利用卫星数字地图，没计了灵活多变的观测系统，采用可控震源与炸药震源配合使用方法，及时对城区内地下面元的覆盖次数、方位角和炮检距的分布进行质量监控，利用现场处理系统对资料进行及时分析，提高了地震资料品质。所获得的东营城区高精度三维地震采集资料显示，其浅中层分辨率和中深层信噪比都有了明显改善，取得了良好的地质效果。     

北太平洋亚热带环流区表层水中226Ra和228Ra的分布与变化

对1999年9～10月采自北太平洋亚热带环流区的19份表层海水样品的Ra同位素分析表明。研究海域表层水中的^226Ra、^228Ra放射性比度分别介于0．67～0．92、0．08～0．30Bq／m^3之间，平均值分别为0．74、0．11Bq/m^3．^226Ra/^228Ra)A．R．活度比的变化范围为0．11～0．44，平均值为0．19．上述数值明显低于近岸海域水体的相应值，表现为典型的开阔大洋水的特征．从空间分布的特征看，研究海域Ra同位素含量与^226Ra/^228Ra)A.R.值均呈均匀分布态势．将本研究结果与历史数据进行对比后发现，本研究获得的^226Ra、^228Ra放射性比度比20世纪60～80年代得到的数据来得低，可能与水体层化作用加强导致的Ra补充量的减少以及生物生产力升高导致的Ra迁出量的增加有关．北太平洋亚热带环流区表层水中Ra同位素的时间变化与文献报道的该海域叶绿素a、硅酸盐、磷酸盐含量与初级生产力的历史变化趋势相吻合．     

Computation of Viscous Uniform and Shear Flow over A Circular Cylinder by A Finite Element Method

The incompressible viscous uniform and shear flow past a circular cylinder is studied. The two-dimensional Navier-Stokes equations are solved by a finite element method. The governing equations are discretized by a weighted residual method in space. The stable three-step scheme is applied to the momentum equations in the time integration. The numerical model is firstly applied to the computation of the lid-driven cavity flow for its validation. The computed results agree well with the measured data and other numerical results. Then, it is used to simulate the viscous uniform and shear flow over a circular cylinder for Reynolds numbers from lO0 to lO00. The transient time interval before the vortex shedding occurs is shortened considerably by introduction of artificial perturbation. The computed Strouhal number, drag and lift coefficients agree well with the experimental data. The computation shows that the finite element model can be successfully applied to the viscous flow problem.     

Sources and distribution of organic matter in a river-dominated estuary (Winyah Bay, SC, USA)

The sources and distribution of organic matter (OM) in surface waters and sediments from Winyah Bay (South Carolina, USA) were investigated using a variety of analytical techniques, including elemental, stable isotope and organic biomarker analyses. Several locations along the estuary salinity gradient were sampled during four different periods of contrasting river discharge and tidal range. The dissolved organic carbon (DOC) concentrations of surface waters ranged from 7 mg l⁻¹ in the lower bay stations closest to the ocean to 20 mg l⁻¹ in the river and upper bay samples. There was a general linear relationship between DOC concentrations and salinity in three of the four sampling periods. In contrast, particulate organic carbon (POC) concentrations were significantly lower (0.1–3 mg l⁻¹) and showed no relationship with salinity. The high molecular weight dissolved OM (HMW DOM) isolated from selected water samples collected along the bay displayed atomic carbon:nitrogen ratios ([C/N]a) and stable carbon isotopic compositions of organic carbon (δ¹³C_OC) that ranged from 10 to 30 and from −28 to −25‰, respectively. Combined, such compositions indicate that in most HMW DOM samples, the majority of the OM originates from terrigenous sources, with smaller contributions from riverine and estuarine phytoplankton. In contrast, the [C/N]a ratios of particulate OM (POM) samples varied significantly among the collection periods, ranging from low values of 5 to high values of >20. Overall, the trends in [C/N]a ratios indicated that algal sources of POM were most important during the early and late summer, whereas terrigenous sources dominated in the winter and early spring.In Winyah Bay bottom sediments, the concentrations of the mineral-associated OM were positively correlated with sediment surface area. The [C/N]a ratios and δ¹³C_OC compositions of the bulk sedimentary OM ranged from 5 to 45 and from −28 to −23‰, respectively. These compositions were consistent with predominant contributions of terrigenous sources and lesser (but significant) inputs of freshwater, estuarine and marine phytoplankton. The highest terrigenous contents were found in sediments from the river and upper bay sites, with smaller contributions to the lower parts of the estuary. The yields of lignin-derived CuO oxidation products from Winyah Bay sediments indicated that the terrigenous OM in these samples was composed of variable mixtures of relatively fresh vascular plant detritus and moderately altered soil OM. Based on the lignin phenol compositions, most of this material appeared to be derived from angiosperm and gymnosperm vascular plant sources similar to those found in the upland coastal forests in this region. A few samples displayed lignin compositions that suggested a more significant contribution from marsh C₃ grasses. However, there was no evidence of inputs of Spartina alterniflora (a C₄ grass) remains from the salt marshes that surround the lower sections of Winyah Bay.     

南海罗斯贝变形半径的地理及季节变化

根据南海 1°× 1°网格的标准层季节平均温、盐度资料 ,在未引入Boussinesq近似条件下 ,采用改进的Thompson Haskell算法求解线性化斜压海洋水平大尺度波的垂直结构方程 (重力内波方程 ) ,从而得到了南海各网格点的第一斜压重力波相速度和相应的罗斯贝变形半径 ,并探讨其地理分布和季节变化特征 ,以期有助于南海环流和中尺度涡旋以及有关海洋侧边界效应的研究。     

Triple diagram method for the prediction of wave height and period

Many formulations have been developed so far to predict the wave height and period from fetch length and wind blowing duration for a constant wind speed. This study aimed to predict wave parameters from fetch length and meteorological factors by using triple diagram methodology based on Kriging principles. Proposed model results were compared with Joint North Sea Wave Project (JONSWAP) model which is used so commonly in the ocean and coastal engineering studies. For the implementation of the methodology hourly wave and wind data were obtained from a buoy located in Lake Ontario. Numerical and graphical comparisons demonstrated that the proposed method outperforms the classical formulation.     

Resources calculation of cobalt-rich crusts with the grid subdivision and integral method

On the basis of three geological models and several orebody boundaries,a method of grid subdivision and integral has been proposed to calculate and evaluate the resources of cobalt-rich crusts on the seamounts in the central Pacific Ocean.The formulas of this method are deduced and the interface of program module is designed.The method is carried out in the software "Auto mapping system of submarine topography and geomorphology MBChart".This method and program will possibly become a potential tool to calculate the resources of seamounts and determine the target diggings for China's next Five-year Plan.     

东亚冬夏季风对热带印度洋秋季海温异常的响应

利用多年的Reynolds月平均海表温度资料和NCEP/NCAR全球大气再分析资料,分析了热带印度洋秋季海表温度距平(SSTA)与后期东亚冬夏季风强度变化的关系。结果表明,热带印度洋秋季SSTA的主要模态是全区一致(USB)型和偶极子(IOD)型,USB型模态主要代表热带印度洋秋季SSTA的长期变化趋势,而IOD型模态主要反映热带印度洋秋季SSTA的年际变化。热带印度洋秋季海温气候变率中既存在着明显的ENSO信号,也有独立于ENSO的变率特征,独立于ENSO的热带印度洋秋季SSTA变化的主要模态仍是USB型和IOD型。前期秋季USB模态与东亚冬季风及东亚副热带夏季风之间为负相关关系;与前期正(负)IOD模态相对应,南海夏季风强度偏弱(强),而东亚副热带夏季风强度偏强(弱)。USB型和IOD型模态对后期东亚冬、夏季风强度变化的影响是独立于ENSO的,但ENSO起到了调节二者相关显著程度的作用。