半空间埋置动点源荷载问题的传递矩阵法

引用了流体饱和两相多孔介质的动力控制方程分析半空间埋置动点源荷载问题的位移和变形。经过Laplace Hankel变换 ,控制方程化成常微分方程组。利用数学软件mathmatic对上述方程组求解 ,可以得到单层砂土的传递矩阵。分析过程中 ,假设在两层面上 ,位移与应力相互连续 ,可以借鉴有限元的思想进行耦合计算。这样就获得了在饱和砂土中施加竖向动荷载问题的Laplace Hankel变换解 ,其最终的解还需要通过Laplace Hankel逆变换得到     

Triaxial stress state deep in orogenic belts: an example from Turkey

A rare metachert pebble containing amphibole grains with microboudin structures in a wide range of orientations provides an opportunity to perform stress analysis in two orthogonal orientations on the foliation surface. The sample was analysed by the microboudin method to infer the triaxial stress state during microboudinage. Stress parameters proportional to the far-field differential stress were determined for sodic amphibole grains in the two orientations. The ratio of the stresses in the two orthogonal orientations (σ₁−σ₂)/(σ₁−σ₃) was calculated to be 0.64, indicating that σ₂ lies closer to the midpoint between σ₁ and σ₃ than to σ₃.     

Direct Current Plasma Emission Spectrometric Determination of Major, Minor and Trace Elements in Microwave Oven Acid Leachates of Powdered Whole Coal Samples

Major concentrations of Al₂O₃, Fe₂O₃, MgO, CaO, Na₂O and K₂O, minor levels of TiO₂, P₂O₅ and thirty petrologically, geochemically and environmentally significant trace elements have been determined in microwave oven acid leachates of whole powdered coal samples by direct current plasma‐atomic emission spectrometry (DCP‐AES). A single sample preparation procedure was suitable for all the determinations with no additional dilution step for major elements solution. Dried samples (0.5 g) were treated in low‐pressure PFA digestion vessels with HF/HCl/HNO₃/HClO₄ acids to quantitatively extract the analytes from the bulk material, while leaving the major part of organic matrix as a residue. The major constituents of geological samples, in particular the easily ionised elements (EIEs) such as alkali and alkaline earths, may complicate the instrumental determinations in DCP‐AES because of differential enhancements of elemental emission intensities and stray light interferences. Taking account of these factors, the coal matrix is considered to have very low major oxide totals as compared to many other common geo‐environmental and related materials (rocks, sediments, soil, ashes etc.). The sample size employed here, while yielding a relatively concentrated solution to cover a wide range of elemental determinations, provided a sample matrix that significantly diminished interferences for DCP measurements. The need for closely matching the unknowns and calibrators was eliminated except for overall acidity and an excess quantity of caesium for EIE buffering. Calibration of the spectrometer was accomplished by simple aqueous single element solutions as high concentration calibrators in addition to a reagent blank as a low concentration calibrator. Two point working curves were established to allow for the maximum concentrations of each element expected in the unknowns. The precision of determinations under routine conditions as well as the reproducibility of the leaching and precision of instrumental measurements have been evaluated. Relative standard deviations (RSD) were of 1–2% for those elements whose concentrations in solid samples were well above the limits of quantification. Method detection limits in the buffered solutions were also evaluated. To evaluate the accuracy of the microwave oven‐DCP method a suite of eight certified coal reference materials of differing rank, were analysed with good agreement with the certified and/or available published data. Results are presented for the uncertified major oxides in the AR series reference materials.     

某城地下水地表水联合优化调度管理模型实例

本文阐述了利用响应矩阵法建立地下水、地表水优化调度管理模型的约束条件、并用目标规划法进行管理模型计算的一个实例。这是一个位于黄河之滨的城市,市内有许多名泉。近年来大量开采地下水已使泉水干涸,而黄河水在某些月份含沙量很大,不宜全年开采。本计算求得了这个城市几个水源地与黄河水在一个枯水年(或丰水年)内各月份的优化开采量分配方案,使之既可保证泉水全年喷涌;叉可提供所需水量。     

多接收电感耦合等离子体质谱Cu同位素测定中的干扰评估

多接收电感耦合等离子体质谱（MC—ICP—MS）是高精度测定铜同位素的新方法,然而在测定中也可能存在干扰。为此对MC—ICPMS Cu同位素测定中的可能干扰进行了评估。主要包括以下方面的内容：（1）对所用标准物质和试剂进行了纯化,所用标准物质和试剂对Cu同位素的同质异位素干扰可以忽略;（2）运用K和／参数进行了讨论,其中K为样品中的Cu浓度与标准溶液中Cu浓度的比值,f为在一定Cu浓度的标准溶液中干扰信号相对于^63Cu真实信号的比值。理论模拟表明,当K值小于1时,即使在质量为63处的干扰很小,对ε^65 Cu的影响也可能很大;（3）通过对理论模拟结果与实际测定结果的对比,发现对所用的试剂而言质量数为65的干扰可以忽略不计;（4）实际测定结果表明,当样品中Cu的浓度是标样中Cu的浓度的0．5～4倍时,测试获得的样品的ε^65值与其真值在误差范围内一致;（5）对潜在的基质效应重点研究了Fe和Co对Cu同位素测定的影响。实验结果表明,当Fe／Cu〈100,Co／Cu〈7时,Fe,Co不影响Cu同位素比值的测定;（6）10个月的重现性研究结果为ε^65=3．5±1．0（2SD）。该测定值在误差范围内与文献报道的值一致     

考虑温度和密度影响的非饱和黄土土-水特征曲线研究

取扰动黄土进行试验研究,测试得到了不同密度和温度黄土土样的土-水特征曲线。试验资料揭示出：密度变化引起基质吸力的变化非常显著。相对而言,温度变化引起基质吸力的变化不显著。对于一定含水率的土样,温度变化引起的吸力变化值在高含水率时较小,可以忽略不计,而在低含水率时较大;温差越大,吸力变化越大。进一步基于试验资料的分析,得到了考虑密度和温度影响的土-水特征曲线的表达式,并通过计算和测试结果的对比分析,验证了表达式的合理性。     

关于薄壁金刚石钻头胎体性能的探讨

对薄壁金刚石钻头胎体进行了性能分析和配方设计探讨，尤其根据被钻切介质对钻头胎体性能的要求作了较详细的分析，从理论分析结合实践经验筛选出了钻切建筑石材和各种钢筋砼的钻头胎体配方，在生产中满足了钻头工作条件的要求。     

Analysis of Sediments and Soils by X-Ray Fluorescence Spectrometry Using Matrix Corrections Based on Fundamental Parameters

Wavelength dispersive X-ray fluorescence spectrometry (WD-XRF) is widely used for the analysis of soils and sediments using well characterised procedures. However, difficulties can occur with samples such as unknowns containing small amounts of ore materials and samples collected from contaminated sites where trace elemental concentrations can exceed the concentration range for routine analysis. We studied the performance of a commercially available method, based on fundamental parameters (FP) to correct matrix effects. The spectrometer was originally calibrated with elemental or simple compound calibrants. Samples were analysed as pressed powder pellets. Eighteen sediment and soil reference materials, three of them with certified values for some of their constituents, were used to evaluate accuracy, by comparing results with recommended values and their standard deviations (RV ± 2s) or certified values and their confidence intervals (CV ± Cl). When results fell systematically outside these intervals, calibrations were refined with geochemical reference materials. The best agreement of results with recommended and certified values was obtained when the contents of H₂O and C in each sample were included as matrix constituents during calculations. The detection limits of trace elements tended to be relatively high, because the measuring conditions employed were not maximised for sensitivity. The main advantage of the method tested was that it enabled the analysis of samples with high concentrations of trace elements and the determination of elements such as F, Bi, Sb and W, which are not commonly included in quantitative XRF analysis of geological samples.     

沙漠地区无人机影像连接点提取

提出了一种纹理自适应的影像连接点提取方法,有针对性地解决沙漠地区无人机影像对比度低、相似性强、纹理信息不均衡,经常会造成连接点过少甚至提取、匹配失败的突出问题。该方法利用影像金字塔进行粗匹配,建立影像之间近似单应变换关系;通过对原始影像分块计算灰度共生矩阵的熵来评估影像纹理指标,并据此实现特征点的自适应提取与匹配。实验表明,该方法能够得到数量较多、分布均匀、可靠性强的同名点。     

太湖入湖河口和开敞区CDOM吸收和三维荧光特征

应用吸收和三维荧光光谱对2007年夏季太湖入湖河口和大太湖开敞区有色可溶性有机物(CDOM)浓度及来源进行研究.结果表明,河口区和开敞区CDOM吸收系数a(355)存在显著空间差异,河口区明显大于开敞(ANOVA,P<0.001),a(355)最大值出现在大浦河口和竺山湾漕桥河几附近,最小值出现在东太湖和胥口湾.a(355)与溶解性有机碳、化学耗氧量浓度存在显著正相关.所有样品一般都含有4个明显的荧光峰,包括1个可见光区的类腐殖质荧光C峰,1个紫外光区的类腐殖酸荧光A峰,2个类蛋白荧光B峰和D峰.河口区外源输入的类腐殖质荧光非常强,最著大于开敞区(ANOVA,P<0.05).而河口区和开敞区类蛋白荧光没有显著性差异,反映开敞区除外源河流输入外,内源生物降解等对类蛋白荧光贡献增加.在河口区B、C峰的比值r(B/C)/b于1,均值为0.62±0.14、在开敞区r(B/C)除12#是0.92,其他值均大于1,均值为1.12±0.13,初步判断r(B/C)可以作为区分CDOM来源的重要参数.CDOM吸收a(355)与类腐殖质荧光C峰、A峰均存在极显著的正相关,而与类蛋白荧光相关性则明显下降,与D峰存在显著正相关,与B峰没有显著相关.