氧掺杂碳气体扩散电极用于电催化产活性氧抗菌防污研究

过氧化氢(H₂O₂)等活性氧(ROS)物质因具有绿色高效的特点,在废水处理、杀菌消毒等领域受到研究者广泛关注。利用电催化生成H₂O₂是一种实时提供活性氧物质的有用方法。然而,目前报道的大多数高性能催化材料都是粉体形式,不便于在实际场景中的应用。因此,制备可直接应用的电极材料显得尤为重要。本研究利用喷涂-热解的制备方法,制备了高活性氧催化活性的氧化炭黑(O−CB)/多孔碳毡电极,通过聚四氟乙烯(PTFE)的修饰优化电极表面的氧气传质,成功制备氧掺杂碳气体扩散电极。研究结果表明,O−CB/PTFE-5 wt%电极具有最高的催化性能,其合成H₂O₂的速率达27.19 mg·L^-1(mg catalyst)^-1·cm^-1·h^-1。海洋典型污损微生物假单胞菌(Pseudomonas sp.)的抗菌实验表明,该电极电催化作用60 min产生的活性氧对Pseudomonas sp.的杀菌率可达到97.69%,作用120 min的杀菌率可达到99.99%。     

Families of Asymmetric Periodic Orbits in Hill’s Problem of Three Bodies

We present five families of periodic solutions of Hill’s problem which are asymmetric with respect to the horizontal ξ axis. In one of these families, the orbits are symmetric with respect to the vertical η axis; in the four others, the orbits are without any symmetry. Each family consists of two branches, which are mirror images of each other with respect to the ξ axis. These two branches are joined at a maximum of Γ, where the family of asymmetric periodic solutions intersects a family of symmetric (with respect to the ξ axis) periodic solutions. Both branches can be continued into second species families for Γ → − ∞.     

湛江港附近海域赤潮生物的种类调查

以光学显微镜对在湛江港附近海域采集的浮游生物进行观察,初步鉴定出赤潮生物——— 硅藻31种、甲藻10种、蓝藻1种,简要介绍了几种主要的赤潮生物的习性、分布和形成赤潮后对渔 业生产造成的损失。     

北部湾海域秋、冬季甲壳类的种类组成及分布

根据 2 0 0 1年 11至 2 0 0 2年 1月间北部湾海域秋、冬季 2个航次的底拖网渔业资源调查资料 ,对北部湾海域甲壳类的种类组成及分布进行研究。本次调查共渔获虾类 2 4种 ,隶属于 6科 11属 ;蟹类 30种 ,隶属 9科 19属 ;虾蛄 9种 ,隶属 2科 6属。各种类沿水深和地理分布有明显变化 ,主要集中分布于湾中部水深 2 1～ 80m海域。     

Cylindrotheca closterium Is a Species Complex as Was Evidenced by the Variations of rbcL Gene and SSU rDNA

The genus Cylindrotheca consists of a small group of marine diatoms with a few species described. Eleven isolates of diatoms identified as Cylindrotheca closterium morphologically were obtained from Jiaozhou Bay with their nuclear-encoded small-subunit ribosomal RNA （SSU rDNA） and chloroplast-encoded rbcL gene sequences determined in this study. Interestingly, very high sequence divergences of SSU rDNA and rbcL gene were found among these isolates, and numerous nucleotide variation of rbcL gene caused relatively few variation of deduced amino acid sequence. Phylogenetic analyses based on SSU rDNA and rbcL gene, respectively, grouped the isolates into 6 clades. Phylogenetic tree of SSU rDNA placed all the Cylindrotheca isolates together, separating them into two lineages clearly. LineageⅠ was composed of the eleven C. closterium isolates obtained in this study together with another C. closterium isolate, but some clades were not well supported. LineageⅠwas contained two C. closterium isolates and one C. fusiformis isolate. Phylogenetic analysis of rbcL gene also separated the Cylindrotheca isolates into two well-defined lineages. The eleven C. closterium isolates formed a lineage and all clades were supported strongly. Statistical comparisons of SSU rDNA indicated that the average distance within lineageⅠwas significantly higher than that of other microalgae species （P 〈0.01）. These results suggested the existence of cryptic species within C. closterium.     

A New Cockroach Genus of the Family Fuziidae from Northeastern China (Insecta: Blattida)

A new genus and two new species of fossil Fuziidae are described and illustrated: Parvifuzia gen. nov., P. marsa sp. nov. and P. brava sp. nov.. Both species were collected from the Middle Jurassic Jiulongshan, Formation of Daohugou, Inner Mongolia of China. In conjunction with Fuzia Vr?ansky, Liang et Ren, 2009, the present findings allow us to demonstrate that members of the family were morphologically diverse, with body length ranging from medium (17 mm) in Fuzia to small (9.7 mm) in the present genus. Wing venation of F. dadao is complicated, but simple in the present species, and apex of male’s cerci are sharp and forceps-like in F. dadao, but strongly curved inward and round in the new genus.     

Spatial patterns of epifaunal communities in San Francisco Bay eelgrass (Zostera marina) beds

Epifaunal invertebrate species, such as amphipods and isopods, have been shown to play key but varying roles in the functioning of seagrass habitats. In this study, we characterized patterns in the poorly known epifaunal communities in eelgrass (Zostera marina) beds in San Francisco Bay as a first step in understanding the individual and collective importance of these species, while testing predictions on spatial patterns derived from previous studies in other regions. Surveys conducted at five beds across multiple time periods (April, June, August and October 2007) showed that San Francisco Bay eelgrass beds varied strongly in epifaunal community composition, total, and relative abundance, and that abundance differed markedly among time periods. In contrast to findings by others, morphologically complex flowering shoots frequently harbored greater numbers of epifauna (>2× and up to 10× more individuals) than vegetative shoots, but not different species assemblages. Similar to previous studies, several abiotic factors did not explain patterns in distribution and abundance among beds. The proportion of introduced species was very high (>90% of all individuals), a finding unique among seagrass epifaunal studies to date. Defining numerical patterns in epifaunal communities will inform related efforts to understand effects of epifaunal species and assemblages on eelgrass growth dynamics, seed production, and higher order trophic interactions over space and time.     

Coral colonization by the encrusting excavating Caribbean sponge Cliona delitrix

The Caribbean sponge Cliona delitrix is among the strongest reef space competitors; it is able to overpower entire coral heads by undermining coral polyps. It has become abundant in reefs exposed to organic pollution, such as San Andrés Island, Colombia, SW Caribbean. Forty‐four sponge‐colonized coral colonies were followed‐up for 13 months to establish the circumstances and the speed at which this sponge advances laterally into live coral tissue and the coral tissue retreats. Cliona delitrix presence and abundance was recorded at seven stations to interpret current reef space and coral species colonization trends. The spread of C. delitrix on a coral colony was preceded by a band of dead coral a few millimeters to several centimeters wide. However, the sponge was directly responsible for coral death only when live coral tissue was within about 2 cm distance; coral death became sponge advance‐independent at greater distances, being indirectly dependent on other conditions that tend to accelerate its retreat. Cliona delitrix advanced fastest into recently killed clean coral calices; however, sponge spread slowed down when these became colonized by algae. The lateral advance of C. delitrix was slower than other Cliona spp. encrusting excavating sponges, probably owing to the greater depth of its excavation into the substratum. Cliona delitrix prefers elevated portions of massive corals, apparently settling on recently dead areas. It currently inhabits 6–9% of colonies in reefs bordering San Andrés. It was found more frequently in Siderastrea siderea (the most abundant local massive coral), which is apparently more susceptible to tissue mortality than other corals. Current massive coral mortality caused by C. delitrix could initially change the relative proportions of coral species and in the long‐term favor foliose and branching corals.