基于可见—近红外反射光谱的典型农田重金属污染风险分类研究

对于人为因素或自然因素造成的农田土壤重金属元素污染,需要进行大面积的土壤环境质量调查和分类管控,然而传统的采样测试方法存在工作量大、代价高等问题。可见—近红外（Vis-NIR）反射光谱是一种快速低成本获取土壤理化信息的手段。为研究Vis-NIR反射光谱预测模型划分土壤重金属污染风险类别的能力,文章以典型人为污染地区（浙江温岭）和典型地质高背景地区（广西横县）的390份农田土壤为样本,测定8种重金属元素（As、Cd、Cr、Cu、Hg、Ni、Pb和Zn）的含量和pH值,并测定土壤Vis-NIR光谱。使用偏最小二乘（PLS）和支持向量机（SVM）算法建立回归模型,对土壤重金属含量和pH值进行预测,并基于预测值进行土壤重金属污染风险分类。结果显示,温岭土壤主要污染元素Cd和Cu的光谱模型回归预测偏差（RPD）分别为1.23和1.19,预测机制与有机质有关。横县土壤主要污染元素As和Cd的RPD分别为1.98和1.93,预测机制与铁氧化物和粘土矿物有关。地质高背景土壤重金属与铁氧化物的正相关性普遍较强,使得光谱模型对重金属含量预测准确度较高。温岭和横县土壤pH值的光谱模型RPD分别为1.76和1.68。土壤重金属污染风险光谱分类的总体 准确度分别为75.0%~100%（温岭）和80.0%~100％（横县）。将Vis-NIR光谱与遥感技术相结合,对农田土壤重金属污染风险进行快速分类总体是可行的。     

Heavy metal concentrations in soils and plants in the vicinity of Arufu lead-zinc mine,Middle Benue Trough,Nigeria

This study focused on the influence of base metal mining on heavy metal levels in soils and plants in the vicinity of Arufu lead-zinc mine, Nigeria. Soil samples (0-15 cm depth) and plant samples were collected from cul-tivated farmlands in and around the mine, the unmineralized site and a nearby forest (the control site). The samples were analyzed for heavy metals (Fe, Zn, Mn, Cu, Pb, Cr and Cd) by Atomic Absorption Spectrophotometry (AAS). The physical properties of soils (pH and LOI) were also measured. Results showed that soils from cultivated farm-lands have neutral pH values (6.5-7.5), and low organic matter contents (10%). Levels of Zn, Pb and Cd in culti-vated soils were higher than the concentrations obtained from the control site. These heavy metals are most probably sourced from mining and agricultural activities in the study area. Heavy metal concentrations measured in plant parts decreased in the order of rice leavescassava tuberspeelings. In the same plant species, metal levels decreased in the order of ZnFeMnCuPbCrCd. Most heavy metals were found in plant parts at average concentrations normally observed in plants grown in uncontaminated soil, however, elevated concentrations of Pb and Cd were found in a few cassava samples close to the mine dump. A stepwise linear regression analysis identified soil metal contents, pH and LOI as some of the factors influencing soil-plant metal uptake.     

大面积深厚杂填土地基处理技术

通过一项具体的工程实例,论述了深厚杂填土地基的基本工程特性。介绍了一种处理深厚杂填土地基的新技术———重锤冲扩挤密灰渣土桩复合地基技术,并对施工过程的控制,以及施工效果的检测结果进行了分析,得出了对于大面积深厚杂填土地基采用此技术处理后,能够消除地基深部湿陷性,复合地基承载力可以满足200 kPa。     

深厚砂质覆盖层土坝的弹塑性地震反应分析

由于可液化砂质土应力-应变特性模拟的复杂性及数值计算的不稳定性,深厚砂质覆盖层土坝的弹塑性地震反应分析是土坝抗震研究中的一个尚未完全解决的课题。采用u-p完全耦合的饱和多孔介质有限元分析方法和砂土多重机构弹塑性模型,对遭受M6.7级地震的国外某深厚砂质覆盖层土坝进行弹塑性地震反应分析,研究了坝体和地基的动力反应特性及其超静孔隙水压力产生、扩散和消散的变化规律。结果表明：计算得到的坝体加速度和永久变形与实测值存在一定的差异,但基本上反映了坝体加速度与永久变形的实际分布情况,从而说明采用的本构模型和计算方法具有一定的精度;由于坝体和坝基的超静孔隙水压力较小,且坝体永久变形不大,可以不对坝体和坝基进行加固处理;坝趾附近浅层地基的超静孔隙水压力较大,有可能发生液化,因此,须采取相应的抗液化加固措施。     

云南石林地区土壤侵蚀的石笋记录与现代观测

通过研究云南乃古石林地区的洞穴沉积物———石笋,结合土壤侵蚀观测结果,发现石笋中的每一个夹泥层代表一次地表快速剥蚀事件,进而讨论了土壤侵蚀事件在石林发育过程中的意义。结果表明:石林发育的自然过程之一是土体较长时期稳定、实现土下溶蚀,协同土壤阶段性的快速剥蚀过程,脉动式相对向上“生长”。石林地区全新世曾经历过数次快速剥蚀过程。     

北京市土壤Hg污染的区域生态地球化学评价

城市土壤Hg异常/污染是中国普遍存在的重大生态环境问题。文章对北京市近1000km2范围内的地表土壤、壤中气、大气干湿沉降、大气颗粒物、大气中的Hg含量水平和空间分布模式进行了系统研究,查明北京地表土壤Hg平均含量为0.41mg/kg,大气干湿沉降物中的Hg平均含量为0.194mg/kg,壤中气Hg的平均含量为559.65ng/m3,大气颗粒物PM10和PM2.5中的Hg含量分别为0.59和0.67ng/m3,大气中的Hg平均含量为3.13ng/m3。北京市自2000年起实现了由燃煤转变为燃气的减排措施,导致干湿沉降物中的Hg沉降通量显著减少,2006年大气干湿沉降物中Hg的沉降通量1.837mg·m-2·a-1,北京市城区(近1000km2)Hg全年沉降为1837kg,空气中总Hg浓度由1998年的8.3~24.7ng/m3下降到2006年的3.13ng/m3,大气颗粒物中Hg含量由2003年的1.18ng/m3下降到2006年的0.59ng/m3(PM10)和0.67ng/m3(PM2.5),表明北京市煤改气减排措施的实施显著改善了大气环境质量。通过对土壤中Hg的存在形式研究,发现土壤中有硫化物(辰砂)及各种Hg盐(HgCl2)的含Hg矿物,Hg也可以各种吸附方式或壤中气方式存在。研究证实北京壤中气Hg与大气Hg存在显著的相关性(n=131,R=0.267,p<0.01),表明壤中气Hg是大气Hg的重要来源之一。利用2005年地表土壤总Hg与Hg释放速率的线性方程估算,土壤Hg平均释放速率为102.42ng·m-2·h-1,2005年土壤释放进大气的Hg通量为936.70kg。在查明土壤中存在大量辰砂矿物的同时,还分布有大量具有高温熔融特征的金属微球粒和玻璃质微球粒,证明燃煤和冶金烟尘是地表土壤Hg的主要来源。土壤中Hg、S、pH和辰砂颗粒浓度在空间上的高度耦合性表明,碱性条件下,土壤中高含量的S和Hg是辰砂形成的重要原因。按国家土壤环境质量标准,北京市I级土壤Hg环境质量的面积为176km2,Ⅱ级为808km2,Ⅲ级为24km2,超Ⅲ为36km2。Ⅲ级、超Ⅲ级主要分布在二环路以内的中心城区。城南(长安街为界)大气Hg环境质量明显优于城北,在北四、北五环之间的部分地区,大气颗粒Hg的环境质量为Ⅲ级或超Ⅲ级。在地表土壤Hg含量较高的中心城区,居民每天因呼吸摄入的Hg高达364ng,对人体健康构成潜在风险。根据我国"十一五"规划中每年实现10%节能减排的目标,对北京市未来50年土壤Hg含量的时空演变趋势预测,预测2050年北京因干湿沉降带来的Hg输入量为16.03kg,地表土壤释放Hg的输出量为37.36kg,明显大于Hg的输入通量,土壤Hg的环境质量将得到根本改善。预测到2040年Ⅲ级土壤Hg环境质量的区域将完全消失,到2060年以Ⅰ级土壤为主。     

非饱和土三轴压缩应力路径试验的数值模拟研究

应力路径对土的强度和变形性质具有重要影响。相对于饱和土而言,控制吸力条件下的非饱和土三轴压缩状态的应力路径研究更加复杂。随着非饱和土本构理论的不断发展,理论和试验研究结果表明,非饱和土弹塑性本构模型可以用来近似地描述非饱和土的强度和变形性质。因而,运用非饱和土弹塑性本构模型对控制吸力条件下的3种非饱和土三轴压缩应力路径试验进行数值模拟是一种有效的理论研究手段。采用Barcelona模型能够对此类试验进行较好的数值模拟,其研究结果表明,在控制吸力条件的三轴压缩状态下应力路径对非饱和土的强度和变形性质具有重要影响。     

Effects of irrigation on geochemical processes in a paddy soil and in ground waters in Camargue (France)

In waterlogged soils, dynamics of water influence the redox conditions and thus the mobility of elements. Irrigation of rice in Camargue (South eastern France) induces yearly dynamics of water. In order to determine the impact of irrigation on the geochemical properties of ground waters, a continuously in situ record of physico-chemical parameters (pH, Eh, temperature and electric conductivity) is performed during 1 year in an irrigated rice field. Seasonal dynamics show large Eh and pH variations. An annual irrigation cycle generates fast precipitations of Ca–Mg carbonates and Fe oxides between 50 and 110 cm depth when the soil is waterlogged. The dissolution of these minerals is initiated during a year without irrigation.     

浅埋深地下水作用下苏打盐渍土水分动态变化特征

文章利用野外试验设施分别把地下水埋深控制在1.0,1.4,1.8,2.2和2.5m,研究在不同地下水埋深作用下苏打盐渍土土壤水分平衡和水分动态变化。同时,跟踪在地下水位不断波动条件下田间土壤水分的动态变化。结果表明:地下水埋深在1.0~2.5m时,苏打盐渍土土壤水和地下水的转化关系非常微弱,仅在长期干旱的条件下发生微量地下水毛细上升量;降雨和蒸散作用对苏打盐渍土体积含水量的影响深度不超过40cm,埋深大于1.0m的潜水对0~80cm深度苏打盐渍土体积含水量变化没有明显影响。     

Swelling behaviour of expansive soil treated with fly ash–GGBS based binder

In this article, the potential of a binder developed by admixing fly ash and ground granulated blast furnace slag (GGBS) to stabilise expansive soils is evaluated. Laboratory tests included determination of free swell index, swell potential and swelling pressure tests of the soil/binder mixtures at different mixing ratio. The test results showed decrease in the swelling behaviour of the soil with increase in binder content. The percent swell–time relationship was observed to fit the hyperbolic curves enabling us to predict the ultimate percent swell from few initial test results. Addition of 1% of lime to the binder showed further improvement in reducing swelling. A good linear relationship is established between percent oedometer swell and modified free swell index (MFSI) for soil/binder mixtures without lime but the same has not been observed in the presence of lime. The compressibility characteristics of the soil/binder mixtures reduced nominally with increase in binder content but in the presence of lime, the compressibility reduced significantly. Binder used in this study has been found to be effective and economic to stabilise expansive soils with lesser amount of chemical additives such as lime.