大功率激电在鄂拉山口寻找隐伏矿体中的应用

鄂拉山口银多金属矿床位于鄂拉山成矿带东南端,第四系覆盖厚,沼泽发育,存在常年冻土层和碎石流,用常规物探在该区找矿效果不显著.后经大功率激电剖面测量,圈出了具一定规模的激电异常带1条,推断为矿异常,经工程验证,发现隐伏银铅锌矿（化）体多条,说明本区采用大功率激电指导找矿效果显著.     

Geochemistry of Subvolcanic-Type Copper-Silver Deposits in Eastern China

The metallogenesis of subvolcanic deposits is controlled by subvolcanic activities. The copper polymetallic deposits are genetically related to intermediate-acid rocks, and the silver polymetallic deposits are more closely related to acid rocks. The abundance of Cu is relatively high in the intermediate-acid rocks and subvolcanic rocks, whereas the abundances of Pb, An and Ag are high in acid rocks, indicating rich ore-forming elements in original magmas. The study of REEs shows that the magmatic type related to copper deposits is the syntectic type, and that related to silver polymetallic deposits is mainly the re-melting type. The deposits were formed under medium-low temperatures and low salinity. The metallogenic times were the late stage of the early Yanshanian or the late Yanshanian, dating 78-147 Ma.     

冀北隆化小罗卜沟金银矿床特征及找矿意义

冀北隆化县小罗卜沟中型金银矿床的发现是该地区找矿的重大突破。勘查区位于1∶20万和1∶5万Au、Ag等多元素综合异常内,通过以钻探、硐探为主的探矿工程,基本查明了矿体赋存于早白垩世九佛堂组复成分角砾岩和义县组安山岩及安山质火山角砾岩的构造裂隙内。矿体受断裂带控制,与围岩界线明显,对围岩没有选择性,矿床属燕山期与岩体有关的浅成中低温热液矿床。矿区内共圈定17个矿体,矿体长28～788 m,斜深8～489 m,平均厚度0.80～3.96 m,Ag平均品位68.44×10~(-6)～447.50×10~(-6),共生Au平均品位1.16×10~(-6)～6.25×10~(-6);伴生Au平均品位0.20×10~(-6)～1.00×10~(-6),伴生S平均品位2.34%～11.10%。主要矿体Ⅳ-1银资源储量达中型。矿区内及外围仍存在寻找多金属矿床的潜力。该矿床的发现对寻找同类矿床具有重要指示意义。     

河南桐柏县破山银矿和银洞坡金矿的硫同位素研究

河南桐柏县围山城金银成矿带的破山银矿和银洞坡金矿位于河前庄背斜的轴部和两翼,围岩为歪头山岩组,矿体受地层和构造的双重控制。两个矿床的矿石硫同位素δ34S值变化范围很窄,位于-1.8‰～5.3‰之间,具塔式效应,与围岩的硫同位素组成类似,具有深源硫的特征,由混合总体筛分可推测围岩提供了大部分硫源,破山银矿δ34S∑S为2.8‰左右。同时赋矿围岩的Au、Ag含量远远高于地壳丰度,因此可推断成矿物质主要来源于围岩歪头山岩组。     

西藏谢通门展咱木部异常区铅锌找矿前景

从区域地质、水系沉积物测量、土壤测量和高精度磁测等方面对西藏展咱木部地区的铅锌找矿前景做初步分析。出露地层主要为第三系始新统年波组的晶屑凝灰岩及安山玢岩,区内出露岩体主要为始新世花岗岩及小面积的花岗斑岩。利用1∶5万水系沉积物测量编制异常图,发现区内Pb、Zn、Ag、Au、Sb、Cu、Ba、Hg、Sn、As等元素有不同规模的明显异常,且Pb、Zn异常规模较大。通过土壤剖面可以看出Pb、Zn异常更显著。高精度磁测结果显示,化探异常位于磁异常附近。磁异常的定性分析对这些金属矿的深部找矿预测可以提供有利证据。磁异常显示该区是热液成矿的有利部位。通过研究元素间组合关系发现,Pb、Zn与Ag、As、Sb、Cu的关系密切,结合化探异常和地质特征,推断区内可能存在与火山岩有关的铅锌多金属矿床类型。研究表明研究区内寻找与火山岩有关的铅锌（银）多金属矿有较好的找矿前景。     

青海索拉沟银多金属矿床成矿特征及成因探讨

索拉沟地区位于青海省东昆仑东部与西秦岭造山带的接合部位,地质构造复杂,岩浆活动较强烈,成矿背景条件良好,是青海省贵金属、铜多金属重要的成矿带之一。根据矿床产出的地质构造环境、成矿特征、矿物组成、电子探针、流体包裹体温压测试及元素组合等特点分析,推测矿床的形成经历了热水沉积成矿和热液叠加改造成矿,索拉沟银多金属矿为热水沉积-热液叠加改造型。     

光谱样品中银的测定

样品经酸溶后,加碘化钾,银以AgI方式存在,有机试剂萃取分离,用原子吸收分光光度计测定有机相中银的含量,测定范围(1~1 000)×10-9。     

用双硫腙－泡沫塑料反相色层萃取原子吸收法测定废水中的微量银

本文研究了双硫腙负载的聚氨酯泡沫塑料对水溶液中银离子的反相色层萃取行为，试验了Ｐｈ，流速、洗脱液及洗脱方法的影响。回收率试验表明，该法能定量捕集废水中银离子，结果令人满意。     

热液中铅、锌、银共生分异的热力学探讨

通过元素基本性质的对比以及热力学计算分析，探讨了热液中银、铅、锌的共生分异机制。在酸性至近中性条件下，氯配合物是它们在热液中的存在形式，其中锌氯配合物最稳定；在近中性到碱性条件下，硫氢配合物占主导地位，此时，银硫氢配合物相对最稳定。温度下降、[Cr]降低、pH升高及f(O2)降低，引起银、铅、锌配合物溶解度减小，发生沉淀分离；对于硫氢配合物，其稳定性主要受pH及还原硫浓度的影响。因此，配合物的不同存在形式以及配合物稳定性之间的差异，使得它们对热液条件的改变做出不同的响应，从而导致了热液中银、铅、锌在成矿过程中的共生分异。     

Determination of Trace Silver in Polymetallic Ore Samples by Flame Atomic Absorption Spectrometry after Solid‐Phase Extraction Using a Microcolumn Comprising Eggshell Membrane

A rapid and inexpensive method was developed for the determination of trace silver in polymetallic ore samples by use of eggshell membrane (ESM), a natural biomaterial, as the solid‐phase extraction (SPE) adsorbent coupled with flame atomic absorption spectrometry (FAAS). The ESM was used for the separation/pre‐concentration of silver, and the parameters affecting sensitivity, such as pH, sample flow rate, eluent volume and eluent flow rate, were carefully investigated. ESM was found to be an effective solid phase extractant for the adsorption of trace silver over a wide range of acidity from 0.02 to 0.50 mol l^?1 HNO₃. The sample solution in 0.4 mol l^?1 HNO₃ was pumped through an ESM microcolumn at the rate of 1.0 ml min^?1. Silver was absorbed, and then eluted with a solution of 1.0% m/v thiourea–0.5% v/v HCl. Under these optimal conditions, ESM exhibited a good enrichment efficiency for silver with a dynamic adsorption capacity of 1.7 mg g^?1. The proposed method was applied to the FAAS determination of trace silver in polymetallic ores and geological reference materials, GSO‐2, 3 and 5, and GSD‐11, GSD‐12, and the determined values were in good agreement with certified values.