Sources of polycyclic aromatic hydrocarbons (PAHs) to northwestern Saskatchewan lakes east of the Athabasca oil sands

The past several decades have witnessed a significant expansion of mining activities in the Athabasca oil sands region, raising concerns about their impact on the surrounding boreal forest ecosystem. To better understand the extent to which distal sites are impacted by oil sands-derived airborne contaminants, we examine sources of polycyclic aromatic hydrocarbons (PAHs) in surface sediments and dated sediment cores from Saskatchewan lakes situated ∼100–220 km east–northeast of the main area of bitumen mining activities. The concentrations and fluxes of both parent and alkylated PAHs are low and show considerable variability over the past 70–100 years. Small yet discernible increases in PAH concentrations and fluxes occurred over the past 30 years, a trend which coincides with the rapid growth in bitumen production. However, several lines of evidence point to wildfires as the principal source of PAHs to these lakes: (1) the significant co-variations in most cores between retene (1-methyl-7-isopropyl phenanthrene) and other groups of parent and alkylated PAHs, (2) the similarity in compound specific δ¹³C signatures of the parent PAHs phenanthrene and pyrene in recently deposited surficial sediments and those corresponding to time intervals considerably pre-dating the large scale development of the oil sands and (3) the discernible up-core increases in the proportion of refractory carbon (i.e., char) in Rock-Eval 6 data. The collective evidence points to softwood combustion from boreal forest fires as the principal source of retene in sediments and the general increase in forest fire activity in this region over the past several decades as the source of refractory carbon. Mining activities associated with the Athabasca oil sands are thus not considered a major source of PAHs to these lakes.     

长江口现代潮滩沉积物粒度特征及其在沉积相识别中的应用

本研究通过对长江口现代潮滩6个柱状样沉积物的粒度精细分析,试图提取研究区潮滩沉积相识别的粒度敏感指标,并通过对长江三角洲南部平原一个全新世钻孔(SL67孔)潮滩沉积物的粒度研究,检验现代沉积粒度敏感指标在全新世钻孔潮滩沉积相识别中的应用。研究显示,长江口现代高潮滩和中潮滩的黏性颗粒(8μm)和粗粉砂(32~63μm)含量差异显著,可以成为区分高潮滩和中潮滩的敏感组分;在开敞型的中、低潮滩之间,砂(63μm)和细粉砂含量(8~32μm)也差异明显。长江口现代潮滩沉积物的粒度频率曲线及众数值也可以有效协助区分高潮滩、中潮滩和低潮滩沉积物。利用上述粒度敏感组分和众数指标检验SL67孔全新世早中期在海平面波动控制下的潮滩演替过程,并揭示了7.5 cal ka BP前后的一次海平面加速上升事件。     

A 16 ka climate record deduced from δ^13C and C/N ratio in Qinghai Lake sediments, northeastern Tibetan Plateau

1 INTRODUCTION δ13C in organic matters from lacustrine sedi- ments varies with several factors including aquatic plants, vegetation type in the catchment, atmos- pheric CO2 concentration, climate (temperature and precipitation), and properties of water, …     

Comparative application of two mathematical models to predict sedimentation in Yermasoyia Reservoir,Cyprus

The Yermasoyia Reservoir is located northeast of the town of Limassol, Cyprus. The storage capacity of the reservoir is 13·6 × 10⁶ m³. The basin area of the Yermasoyia River, which feeds the reservoir, totals 122·5 km². This study aims to estimate the mean annual deposition amount in the reservoir, which originates from the corresponding basin. For the estimate of the mean annual sediment inflow into the reservoir, two mathematical models are used alternatively. Each model consists of three submodels: a rainfall‐runoff submodel, a soil erosion submodel and a sediment transport submodel for streams. In the first model, the potential evapotranspiration is estimated for the rainfall‐runoff submodel, and the soil erosion submodel of Schmidt and the sediment transport submodel of Yang are used. In the second model, the actual evapotranspiration is estimated for the rainfall‐runoff submodel, and the soil erosion submodel of Poesen and the sediment transport submodel of Van Rijn are used. The deposition amount in the reservoir is estimated by means of the diagram of Brune, which delivers the trap efficiency of the reservoir. Daily rainfall data from three rainfall stations, and daily values of air temperature, relative air humidity and sunlight hours from a meteorological station for four years (1986–89) were available. The computed annual runoff volumes and mean annual soil erosion rate are compared with the respective measurement data. Copyright © 2006 John Wiley & Sons, Ltd.     

Modelling of sediment dynamics in a laboratory‐scale experimental catchment

The variability of hillslope form and function is examined experimentally using a simple model catchment in which most landscape development parameters are either known or controlled. It is demonstrated that there is considerable variability in sediment output from similar catchments, subjected to the same hydrological processes, and for which the initial hillslope profiles are the same. The results demonstrate that, in the case of catchments with a linear initial hillslope profile, the sediment output is initially high but reduces through time, whereas for a concave initial profile the sediment output was smaller and relatively constant. Concave hillslope profiles also displayed reduced sediment output when compared with linear slopes with the same overall slope. Using this experimental model catchment data, the SIBERIA landscape evolution model was tested for its ability to predict temporal sediment transport. When calibrated for the rainfall and erodible material, SIBERIA is able to simulate mean temporal sediment output for the experimental catchment over a range of hillslope profiles and rainfall intensities. SIBERIA is also able to match the hillslope profile of the experimental catchments. The results of the study provide confidence in the ability of SIBERIA to predict temporal sediment output. The experimental and modelling data also demonstrate that, even with all geomorphic and hydrological variables being known and/or controlled, there is still a need for long‐term stream gauging to obtain reliable assessments of field catchment hydrology and sediment transport. Copyright © 2005 John Wiley & Sons, Ltd.     

Runoff and sediment loss responses to rainfall and land use in two agricultural catchments on the Loess Plateau of China

Soil erosion is a severe problem hindering sustainable agriculture on the Loess Plateau of China. Plot experiments were conducted under the natural rainfall condition during 1995–1997 at Wangdongguo and Aobao catchments in this region to evaluate the effects of various land use, cropping systems, land slopes and rainfall on runoff and sediment losses, as well as the differences in catchment responses. The experiments included various surface conditions ranging from bare soil to vegetated surfaces (maize, wheat residue, Robinia pseudoacacia L., Amorpha fruticosa L., Stipa capillata L., buckwheat and Astragarus adsurgens L.). The measurements were carried out on hill slopes with different gradients (i.e. 0 ° to 36 °). These plots varied from 20 to 60 m in length. Results indicated that runoff and erosion in this region occurred mainly during summer storms. Summer runoff and sediment losses under cropping and other vegetation were significantly less than those from ploughed bare soil (i.e. without crop/plant or crop residue). There were fewer runoff and sediment losses with increasing canopy cover. Land slope had a major effect on runoff and sediment losses and this effect was markedly larger in the tillage plots than that in the natural grass and forest plots, although this effect was very small when the maximum rainfall intensity was larger than 58·8 mm/h or smaller than 2·4 mm/h. Sediment losses per unit area rose with increasing slope length for the same land slope and same land use. The effect of slope length on sediment losses was stronger on a bare soil plot than on a crop/plant plot. The runoff volume and sediment losses were both closely related to rainfall volume and maximum intensity, while runoff coefficient was mainly controlled by maximum rainfall intensity. Hortonian overland flow is the dominant runoff process in the region. The differences in runoff volume, runoff coefficient and sediment losses between the catchments are mainly controlled by the maximum rainfall intensity and infiltration characteristics. The Aobao catchment yielded much larger runoff volume, runoff coefficient and sediment than the Wangdongguo catchment. Copyright © 2001 John Wiley & Sons, Ltd.     

Spatial patterns of suspended sediment yields in a humid tropical watershed in Costa Rica

An Erratum has been published for this article in Hydrological Processes 16(5) 2002, 1130–1131. Humid tropical regions are often characterized by extreme variability of fluvial processes. The Rio Terraba drains the largest river basin, covering 4767 km², in Costa Rica. Mean annual rainfall is 3139±419_sd mm and mean annual discharge is 2168±492_sd mm (1971–88). Loss of forest cover, high rainfall erosivity and geomorphologic instability all have led to considerable degradation of soil and water resources at local to basin scales. Parametric and non‐parametric statistical methods were used to estimate sediment yields. In the Terraba basin, sediment yields per unit area increase from the headwaters to the basin mouth, and the trend is generally robust towards choice of methods (parametric and LOESS) used. This is in contrast to a general view that deposition typically exceeds sediment delivery with increase in basin size. The specific sediment yield increases from 112±11·4_sd t km^?2 year^?1 (at 317·9 km² on a major headwater tributary) to 404±141·7_sd t km^?2 year^?1 (at 4766·7 km²) at the basin mouth (1971–92). The analyses of relationships between sediment yields and basin parameters for the Terraba sub‐basins and for a total of 29 basins all over Costa Rica indicate a strong land use effect related to intensive agriculture besides hydro‐climatology. The best explanation for the observed pattern in the Terraba basin is a combined spatial pattern of land use and rainfall erosivity. These were integrated in a soil erosion index that is related to the observed patterns of sediment yield. Estimated sediment delivery ratios increase with basin area. Intensive agriculture in lower‐lying alluvial fans exposed to highly erosive rainfall contributes a large part of the sediment load. The higher elevation regions, although steep in slope, largely remain under forest, pasture, or tree‐crops. High rainfall erosivity (>7400 MJ mm ha^?1 h^?1 year ^?1) is associated with land uses that provide inadequate soil protection. It is also associated with steep, unstable slopes near the basin mouth. Improvements in land use and soil management in the lower‐lying regions exposed to highly erosive rainfall are recommended, and are especially important to basins in which sediment delivery ratio increases downstream with increasing basin area. Copyright © 2001 John Wiley & Sons, Ltd.     

Suspended sediment and phosphorus in proglacial rivers: bioavailability and potential impacts upon the P status of ice‐marginal receiving waters

This paper adopts standard tests developed in temperate catchment research to determine the total phosphorus (TP) and the algal available (base‐extractable) phosphorus (NaOH–P) content of a wide range of glaciofluvial sediments from the Northern Hemisphere. We find that the TP content of these sediments is broadly similar to the P content of major rock types in Earth's crust (230–670 µgP/g) and so the TP yields of glacier basins may be high owing to the efficacy of suspended sediment evacuation by glacial meltwaters. We show that this is best achieved where subglacial drainage systems are present. The NaOH–P pool of the sediments is found to be low (1–23 µgP/g) relative to the TP pool and also to the NaOH–P pool of suspended sediments in temperate, non‐glacierized catchments. This most probably reflects the restricted duration of intimate contact between dilute meltwaters and glacial suspended sediments during the ablation season. Thus, despite the high surface‐area:volume ratio of glacial suspended sediments, the potential for P adsorption to mineral surfaces following release by dissolution is also low. Further, sorption experiments and sequential extraction tests conducted using glacial suspended sediments from two Svalbard catchments indicate that the generation of reactive secondary minerals (e.g. Fe‐ and other hydroxides) with a strong capacity to scavenge P from solution (and thereby promote the continued dissolution of P) may also be limited by the short residence times. Most P is therefore associated with poorly weathered, calcite/apatite‐rich mineral phases. However, we use examples from the Svalbard glacier basins (Austre Brøggerbreen and Midre Lovénbreen) to show that the high sediment yields of glaciers may result in appreciable NaOH–P loading of ice‐marginal receiving waters. Again, the importance of subglacial drainage is highlighted, as it produces a major, episodic release of NaOH–P at Midre Lovénbreen that results in a yield (8·2 kg NaOH–P/km²/year) more than one order of magnitude greater than that at Austre Brøggerbreen (where subglacial drainage is absent and the yield is 0·48 kg NaOH‐P/km²/year). Therefore, as since both detrimental and beneficial effects of sediment‐bound P loading in ice marginal receiving waters are possible (i.e. either reduced primary productivity owing to increased turbidity or P fertilization following desorption) there is a pressing need to assess the ambient P status of such environments and also the capacity for ice‐marginal ecosystems to adapt to such inputs. Copyright © 2004 John Wiley & Sons, Ltd.     

Importance of soil surface characteristics on water erosion in a small grazed Sahelian catchment

This study concerns the problem of water erosion in the Sahel. Surface water and sediment yields (suspended matter and bedload) were monitored for 3 years (1998–2000) at the outlet of a small grazed catchment (1·4 ha) in the northern part of Burkina Faso. The catchment consists of about 64% sandy deposits (DRY soil surface type), which support most of the vegetation, and about 34% of crusted bare soils (ERO soil surface type). The annual solid‐matter export is more than 90% suspended sediment, varying between 4·0 and 8·4 t ha^?1. The bedload represents less than 10% of soil losses. In a single flood event (10 year return period), the sediment yield can reach 4·2 t ha^?1. During the period studied, a small proportion (20 to 32%) of the floods was thus responsible for a large proportion (80%) of the solid transport. Seasonal variation of the suspended‐matter content was also observed: high mean values (9 g l^?1) in June, decreasing in July and stabilizing in August (between 2 and 4 g l^?1). This behaviour may be a consequence of a reorganization of the soil surfaces that have been destroyed by trampling animals during the previous long dry season, vegetation growth (increase in the protecting effect of the herbaceous cover) and, to a lesser extent, particle‐supply limitation (exhaustion of dust deposits during July). The particle‐size distribution in the suspended matter collected at the catchment outlet is 60% made up of clay: fraction ≤2 µ m. The contribution of this clay is maximum when the water rises and its kaolinite/quartz ratio is then close to that of the ERO‐type surfaces. This indicates that these surfaces are the main source of clay within the catchment. Copyright © 2003 John Wiley & Sons, Ltd.     

Short‐term spatial and temporal patterns of suspended sediment transfer in proglacial channels,small River Glacier,Canada

Alpine glacial basins are a significant source and storage area for sediment exposed by glacial retreat. Recent research has indicated that short‐term storage and release of sediment in proglacial channels may control the pattern of suspended sediment transfer from these basins. Custom‐built continuously recording turbidimeters installed on a network of nine gauging sites were used to characterize spatial and temporal variability in suspended sediment transfer patterns for the entire proglacial area at Small River Glacier, British Columbia, Canada. Discharge and suspended sediment concentration were measured at 5 min intervals over the ablation season of 2000. Differences in suspended sediment transfer patterns were then extracted using multivariate statistics (principal component and cluster analysis). Results showed that each gauging station was dominated c. 80% of days by diurnal sediment transfer patterns and ‘low’ suspended sediment concentrations. ‘Irregular’ transfer patterns were generally associated with ‘high’ sediment concentrations during snowmelt and rainfall events, resulting in the transfer of up to 70% of the total seasonal suspended sediment load at some gauging stations. Suspended sediment enrichment of up to 600% from channel storage release and extrachannel inputs occurred between the glacial front and distal proglacial boundary. However, these patterns differed significantly between gauging stations as determined by the location of the gauging station within the catchment and meteorological conditions. Overall, the proglacial area was the source for up to 80% of the total suspended sediment yield transferred from the Small River Glacier basin. These results confirmed that sediment stored and released in the proglacial area, in particular from proglacial channels, was controlling suspended sediment transfer patterns. To characterize this control accurately requires multiple gauging stations with high frequency monitoring of suspended sediment concentration. Accurate characterization of this proglacial control on suspended sediment transfer may therefore aid interpretation of suspended sediment yield patterns from glacierized basins. Copyright © 2004 John Wiley & Sons, Ltd.