Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy

Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample).     

考虑地球曲率影响的重力中间层校正计算及其精度分析

介绍一种考虑地球曲率影响的“球冠模型” 重力中间层校正算法,并通过不同算例对比该算法与以往“圆柱体模型”算法之间的差值。结果表明,其差值的数量级最大可达0.4 mGal。     

Generalised observations of wave characteristics on near‐horizontal shore platforms: Synthesis of six case studies from the North Island,New Zealand

Most field studies of wave processes on shore platforms in front of eroding cliffs focus on a single site, revealing aspects of wave dynamics at that location. Here, we analyse data from six platforms around northeastern New Zealand and describe the fundamental control of shore platform width, gradient and elevation on wave processes, including greater attenuation of short‐period waves at lower tidal stages and increases in longer period wave energy towards the cliff toe. These data suggest that empirical formulae developed from coral‐reef environments provide better predictions of wave height on platforms than formulae currently used in shore platform models.     

Production and Certification of Synthetic Selenium Isotopic Reference Materials

Due to intensive research into selenium isotopes in recent years, the increasing requirement for reliable and comparable measurement results has created a strong demand for selenium isotopic certified reference materials (iCRM) that were previously not available. To address this, eleven selenium iCRMs were developed, including ten synthetic iCRMs (GBW 04447–GBW 04456) and one natural iCRM (GBW 04457). The synthetic iCRMs were prepared with ⁷⁶Se, ⁷⁸Se, ⁸⁰Se and ⁸²Se solutions and a natural selenium solution; the natural iCRM was prepared with highly pure selenium material. The property values of isotope ratios in these iCRMs were certified by calibrated mass spectrometry with a collision cell multi‐collector ICP‐MS. The mass discrimination effect of the instrument was corrected with corresponding ⁷⁸Se/⁷⁶Se isotope mixtures and ⁸²Se/⁷⁶Se isotope mixtures, which were gravimetrically prepared with purified, isotopically enriched selenium materials. Homogeneity and stability tests were performed, and no significant influences were found. The uncertainty of the property values of the iCRMs was evaluated according to the Guide to the Expression of Uncertainty in Measurement (GUM) of ISO/BIPM and ISO Guide 35. The δ^82/76Se value of GBW 04457 relative to NIST SRM 3149 was also calculated. These iCRMs are intended for use in calibration of instruments and evaluation of methods for the determination of selenium isotope ratios.     

庐枞矿集区中东部七家山—马口地区深部找矿潜力分析

为调查庐枞矿集区中东部七家山—马口地区深部矿产资源潜力,利用小波变换方法提取深源重磁场,通过对垂向一阶导数Z与水平方向导数模S进行参数变换,突出深源重磁场的局部异常; 结合频谱激电(spectrum induced polarization,SIP)、可控源音频大地电磁测深(controlled source audio-frequency magneto tellurics,CSAMT)成果,在调查区深部查明了一条长大于3.0 km、宽大于0.5 km的高重低磁、低阻高极化异常带; 根据调查区内外已知铜矿(化)体分布规律,结合已知矿(化)体在深源重磁异常中的分布及钻孔(zk4601)钻探验证结果,认为上述异常带是铜多金属矿化蚀变带的反映,是寻找铜多金属矿的有利部位,具有较好的找矿前景。     

蒙脱石伊利石化的水热实验模拟

以蒙脱石为初始材料,通过水热实验模拟在不同温度压力条件下蒙脱石的伊利石化过程。利用X射线粉末衍射及X射线荧光光谱、红外光谱和扫描电镜等方法对样品的矿物物相、化学成分、晶体结构与微观形貌等进行分析,其结果表明:(1)蒙脱石至伊利石的转化受温度和压力条件的控制;(2)随着温度和压力的增高,蒙脱石伊利石化沿着蒙脱石-无序伊蒙混层-有序伊蒙混层-伊利石的转化序列进行转化;(3)水热实验模拟表明蒙脱石至伊利石的转化以溶解重结晶机制为主。实验结果不仅有助于了解埋藏与低级变质作用中的蒙脱石伊利石化过程,同时为研究断层活动所致断层泥中黏土矿物的转化及反演断层形成时温度压力条件提供基本参数。     

波浪在珊瑚岸礁礁坪上传播变形的数值研究

波浪的传播变形对珊瑚岛礁附近的营养物质输送以及近岸珊瑚沙运动都起着关键的作用,同时也是礁盘顶部建筑物在设计和施工过程中需要重点考虑的因素,因此,对波浪在礁坪上的传播变形进行研究具有重要意义。利用FUNWAVE 2.0数值模型模拟了不规则波浪在不同形状岸礁上的传播变形过程,讨论了礁前斜坡坡度以及珊瑚底面粗糙程度对波浪在礁坪上传播变形的影响。结果显示,随着礁坡斜率增大,不对称度参数绝对值的增长趋势逐渐变缓,波浪在光滑礁坪上的不对称度绝对值要略大于粗糙底面上的值,而不同地形下计算得到的波浪偏度参数则基本相同。说明礁坡坡度对波浪的不对称度特征具有显著影响,礁坪粗糙度的影响则相对较小,而上述因素对波浪偏度的影响则完全可以忽略。给出了考虑这两个影响因素的礁坪区域内波浪偏度和不对称度经验公式。     

南秦岭柞山地区铅银锌矿成矿规律及找矿模型

南秦岭柞水银洞子—山阳桐木沟铅银锌矿带地处陕西柞山地区中部,位于中秦岭晚古生代弧前盆地的柞水—山阳矿集区内。该带东西长约71 km,南北宽1～7 km。对带内银洞子（铜）铅银菱铁矿床、黑沟铅锌菱铁矿床、桐木沟锌矿床、南沟（银）铅矿床和松林沟铅矿点的地质、矿体、蚀变、矿化规律进行总结,发现矿体均严格产于中-上泥盆统青石垭组,具有明显的时控、层控、岩控及后期热液改造成矿特征,属典型的海底热水喷流沉积-热液改造层控矿床,构成与晚古生代海底热水喷流沉积-热液改造作用有关的铅锌银成矿系列。建立以层控+热液改造为主控矿条件,以青石垭组热水沉积岩+断裂+化探异常+硫化物、重晶石、菱铁矿蚀变分带为组合的找矿模型,对柞山地区金属矿的找矿突破具有重要的指导意义。     

俄罗斯-蒙古地学断面地壳模型的地质-地球物理资料综合研究

地学断面是指地壳的垂直剖面,主要通过对地质和地球物理资料的综合分析来揭示构造带的性质及其空间关系。横断面的研究所采用的数据基本包括100 km宽区域地质图、上地壳的地质剖面图、重磁图(沿横断面的重磁剖面图)以及地壳的地震波速度、密度和其他地球物理属性的剖面图。这些数据被用于构建综合的数据剖面图(结果图),以展示各种地球动力学条件下(裂谷、海洋、碰撞带、造山盆地、大陆地台和岩浆弧,包括安第斯岛弧、活动大陆边缘、海沟、弧前和弧后盆地)的特定的岩石组构。本项目的研究目标是根据研究区现存的地质和地球物理数据的综合解释,统一图例,建立研究区深部剖面,以确定地体的空间关系及其在板块构造方面的地球动力学性质。 前人已分别对东西伯利亚南部和蒙古境内的多个地体进行了构造划分,并对它们的地球动力学性质和时空关系进行了分析。研究结果显示该系列地体为早古生代、中晚古生代和晚古生代—早中生代的岛弧和微大陆。此外,研究还识别出了中—晚古生代和晚古生代—早中生代安第斯型活动大陆边缘、晚古生代—早中生代被动大陆边缘和早白垩世裂谷。与岛弧和安第斯型活动大陆边缘相关的岩体被推覆至相邻大陆和微陆块上,部分推覆宽度可达150 km。目前已开展泥盆纪到晚侏罗世时期蒙古-鄂霍次克海地区的古地球动力学重建。 “非地槽”型花岗岩类岩浆作用在板块构造方面找到了直接且合理的解释,其中泥盆纪—石炭纪和二叠纪—三叠纪岩浆作用区域对应于安第斯型活动大陆边缘,中—晚侏罗世岩浆作用则与西伯利亚/蒙古-中国大陆板块碰撞有关。碰撞岩浆作用中亚碱性(地幔)元素的存在及其所在的构造区域在很大程度可以说明蒙古-鄂霍次克海闭合后,巨厚大陆岩石圈下曾经发生过持续的大洋裂谷活动(地幔热点)。在早白垩世时期,大陆裂谷活动影响到了同一时期正在发生的大陆汇聚作用。 西伯利亚南部边界大部分具有安第斯型活动大陆边缘性质,这也是蒙古—鄂霍次克缝合线沿线蛇绿岩数量较少的原因。因为当汇聚大陆一个具有安第斯类型的活动边缘,而另一个具有被动边缘时,前者的大陆地壳会最终逆冲到后者之上,并因此破坏掉先前出露的蛇绿杂岩体。部分被破坏的蛇绿岩块是俯冲带保留下来的海山残余,其可能成为增生-俯冲楔体的混沌复合体的一部分。然而,由于快速俯冲作用,这种楔形体在晚二叠世—早侏罗世的积累并不是西伯利亚活动边缘的典型特征。 沿地学断面综合的地质和地球物理资料分析表明,亚洲大陆是在显生宙时期由部分前寒武纪微陆块构造拼贴而成的。前寒武纪地块间存在不同宽度的已变形且剥蚀强烈的显生宙火山弧,它们也被归类为特定地体。     

煤炭地质勘查产业转型发展的思考与探讨

煤炭地质勘查工作关系国家能源安全,在国民经济发展中具有重要的战略地位。伴随煤炭行业绿色转型和新能源革命新形势,及时调整产业结构,向大地质、大资源、大生态方向拓展服务领域,为国家生态文明建设和煤炭产业绿色安全高效发展提供坚实的地质技术保障,成为煤炭地质勘查产业转型发展必然趋势和未来发展方向。结合煤田地质勘查工作发展历程及现状、发展趋势,对煤炭地质勘查产业转型发展方向进行深入剖析和探讨。