青海省祁漫塔格地区1∶5万水系沉积物测量衬值异常圈定实例

青海省祁漫塔格地区位于柴达木盆地西南缘,是青海省重要的铁多金属成矿基地之一。利用88442个野外采样点1∶5万水系沉积物测量数据,采用Geo Expl软件圈定了该地区的衬值异常。衬值是指各元素0.5 km×0.5 km网格化数据与其园域搜索半径5km、移动步长0.5km移动平均值的比值。选用自定义累频"90、95、98、100"确定了异常的外、中、内带。通过常规方法和衬值圈定的异常的对比,表明衬值异常能够削弱不同地质背景差异,使异常形态更为规整,浓集中心更为明显,并且可能发现新异常。     

时变参数灰色模型背景值重构及实现

针对时变参数灰色模型PGM(1,1)的背景值重构收敛速度及稳定性问题,该文运用积分的方法综合序列在Δt内不同变化趋势,导出背景值模型的准确表达式。实现了反映序列对新老信息偏爱程度的最优权值介于(0,1)内,且非不能越过某一阈值;给出了背景值重构模型最优解准确求取的具体算法步骤。基于MATLAB语言的实验结果表明:改进模型预测精度高,易于实现;所研究的带权灰色模型GM(1,n)背景值模型的重构及计算方法验证了PGM(1,1)模型重构及计算实现方法的有效性和实用性。     

Remote sensing and information value (IV) model for regional mapping of fluvial channels and topographic wetness in the Saudi Arabia

This study aims to map regions of near surface fluvial channels, mega-basins and topographic wetness in Saudi Arabia using remote sensing data and an information value (IV) model, which is a modified approach of weight of evidence. We used the new version of the Shuttle Radar Topographic Mission (SRTM) to delineate the fluvial channels, mega-basin, and slope. These hydrological parameters were used to index the topographic wetness of each mega-basin in the region based on IV in a Geographic Information System. We validated our method using the Space Imaging Radar-C and Landsat 8 images and compared the textural features (fluvial channels) evident from SRTM digital elevation model and to determine whether these patterns were different. Our results revealed that the region is drained by nine tributaries and that the Err Rub Al Khali and Sahba mega-basins have the highest value of the IV and topographic wetness values; the Arran and coastal mega-basins have the lowest value of the IV and topographic wetness values. An integrated approach is timely and economically effective and can be applied throughout the arid and semi-arid regions to help hydrologists and urban developers.     

河元背地区绳索取心钻进泵压计算模型的建立与应用

泵压是反映金刚石绳索取心钻进时井内作业是否正常的重要参数。为了进一步研究泵压波动变化与实际钻进作业之间的关系,指导钻进工作的快速、安全开展,结合江西相山河元背地区CUSD2井实际泵压波动数据及相关钻进资料,建立了适用于本井的循环系统压力损失计算模型。对比分析模型计算的理论泵压与实际泵压的波动变化趋势,将模型应用于实际钻进,在此基础上预测后续地层的泵压波动区域范围,发现7 MPa的泵压安全值不再适用于后续地层钻进,调整设置泵压安全值为10 MPa,并利用邻井泵压波动数据进一步验证其可靠性。适当调整修正理论模型,使其可应用于河元背以及相山地区绳索取心钻进中,指导该地区钻探工作。     

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy

Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample).     

High Precision Sr‐Nd‐Hf‐Pb Isotopic Compositions of USGS Reference Material BCR‐2

The Lamont‐Doherty Earth Observatory radiogenic isotope group has been systematically measuring Sr‐Nd‐Pb‐Hf isotopes of USGS reference material BCR‐2 (Columbia River Basalt 2), as a chemical processing and instrumental quality control monitor for isotopic measurements. BCR‐2 is now a widely used geochemical inter‐laboratory reference material (RM), with its predecessor BCR‐1 no longer available. Recognising that precise and accurate data on RMs is important for ensuring analytical quality and for comparing data between different laboratories, we present a compilation of multiple digestions and analyses made on BCR‐2 during the first author's dissertation research. The best estimates of Sr, Nd and Hf isotope ratios and measurement reproducibilities, after filtering at the 2s level for outliers, were ⁸⁷Sr/⁸⁶Sr = 0.705000 ± 11 (2s, 16 ppm, n = 21, sixteen digestions, one outlier), ¹⁴³Nd/¹⁴⁴Nd = 0.512637 ± 13 (2s, 25 ppm, n = 27, thirteen digestions, one outlier) and ¹⁷⁶Hf/¹⁷⁷Hf = 0.282866 ± 11 (2s, 39 ppm, n = 25, thirteen digestions, no outliers). Mean Nd and Hf values were within error of those reported by Weis et al. (2006, 2007) in their studies of RMs; mean Sr values were just outside the 2s uncertainty range of both laboratories. Moreover, a survey of published Sr‐Nd‐Hf data shows that our results fall within the range of reported values, but with a smaller variability. Our Pb isotope results on acid leached BCR‐2 aliquots (n = 26, twelve digestions, two outliers) were ²⁰⁶Pb/²⁰⁴Pb = 18.8029 ± 10 (2s, 55 ppm), ²⁰⁷Pb/²⁰⁴Pb = 15.6239 ± 8 (2s, 52 ppm), ²⁰⁸Pb/²⁰⁴Pb = 38.8287 ± 25 (2s, 63 ppm). We confirm that unleached BCR‐2 powder is contaminated with Pb, and that sufficient leaching prior to digestion is required to achieve accurate values for the uncontaminated Pb isotopic compositions.     

Task-oriented information value measurement based on space-time prisms

Recent years have witnessed a large increase in the amount of information available from the Web and many other sources. Such an information deluge presents a challenge for individuals who have to identify useful information items to complete particular tasks in hand. Information value theory (IVT) from economics and artificial intelligence has provided some guidance on this issue. However, existing IVT studies often focus on monetary values, while ignoring the spatiotemporal properties which can play important roles in everyday tasks. In this paper, we propose a theoretical framework for task-oriented information value measurement. This framework integrates IVT with the space-time prism from time geography and measures the value of information based on its impact on an individual’s space-time prisms and its capability of improving task planning. We develop and formalize this framework by extending the utility function from space-time accessibility studies and elaborate it using a simplified example from time geography. We conduct a simulation on a real-world transportation network using the proposed framework. Our research could be applied to improving information display on small-screen mobile devices (e.g., smartwatches) by assigning priorities to different information items.     

Student Perceptions of a Recreation Trail Assignment as a Valuable Learning Experience for Geography Undergraduates

Charging undergraduate geography students with the task of designing a recreational trail in their local community offers an engaging experiential opportunity with potential to advance geographic learning in a real-world setting. This article presents an assignment in which students were asked to develop a recreational trail proposal for an undeveloped local conservation area and the results of a survey that asked the students to reflect and report upon the educational value of this experience one year later. Results of the survey validated the assignment's lasting value to the students across the cognitive, psychomotor, and affective learning domains.