中子活化测井在萤石矿勘探中应用效果

本文简要叙述了中子活化测井原位测定萤石矿(CaF_2)含量的原理及方法技术,以及在两个萤石矿区试生产的成果实例。并着重指出: 1.该方法适用于各种不同类型的萤石矿。选择F作为CaF_2的特征指示元素,在萤石矿无其它元素干扰,方法反映单解。 2.工作证明:该方法可防止由于岩矿心破碎造成的地质取心中漏失的矿体,发现地质工作未确定的薄矿层。并能提供CaF_2含量。 3.在取心率很低的钻孔,提供了真实可靠的CaF_2含量和矿层上下顶板确切位置,避免了钻孔报废、取得了良好的经济效益。最后文章指出:该方法的精度、灵敏度和工作效率完全满足生产工作的需要。     

Platinum-Group Element Geochemical Certified Reference Materials (GPt1-7)

Unlike the situation for other elements, few reference materials certified for the platinum-group elements are currently available. Therefore, the GPt1-7 series of PGE geochemical CRMs, prepared by the IGGE, represent an important addition and comprise a range of matrix types, including a soil, stream sediment, Mg-rich ultramafic rock, Fe-rich ultramafic rock, platinoid ore depleted in Cu, Ni and Fe, and a chromitite. The concentration of PGE in these samples ranges over 4-5 orders of magnitude and the samples were shown to have good homogeneity as assessed by a variance test. Analytical methods based on different principles were used in sample certification, including several fire assay and wet chemical procedures used for decomposition and preconcentration. Certified values for the elements Pt, Pd, Os, Ru, Ir, Rh and Au were determined by AAS, catalytic colourimetry (COL), catalytic polarography (POL), atomic emission spectrometry (AES), ICP-MS and NAA. Recently, the GPt1-7 samples were approved as national primary CRMs by the State Bureau of Technical Supervision of China.     

黑龙江省“九五”与“十五”测震台网理论最小监测能力的对比

对黑龙江省地震局“九五”和“十五”地震台网的理论最小监测能力进行计算和对比,为地震台网的布局提出了一些合理化的建议,为以后的地震台网建设提供了很好的参考。     

Inversion of two-dimensional tidal open boundary conditions of M<Subscript>2</Subscript> constituent in the Bohai and Yellow Seas

Two-dimensional tidal open boundary conditions of the M2 constituent in the Bohai and Yellow Seas(BYS) have been estimated by assimilating T/P altimeter data.During inversion,independent point(IP) strategy was used,in which several IPs on the open boundary is assumed,values at these IPs can be optimized with an adjoint method,and those at other grid points are determined by linearly interpolating the values at IPs.The reasonability and feasibility of the model are tested by ideal twin experiments.In the practical experiment(PE) after assimilation,the cost function may reach 1% or less of its initial value.Mean absolute errors in amplitude and phase can be less than 5 cm and 5°,respectively,and the obtained co-chart can show the character of the M2 constituent in the BYS.The results of the PE indicate that using only two IPs on the open boundary can yield better simulated results.     

利用烈度数据点估算中强历史地震震级与震中的方法研究

本文基于地震烈度数据点,用椭圆参数方程对烈度点空间分布进行最小二乘拟合,得到各烈度区椭圆烈度估计线,然后对烈度估计线进行统计回归,得到一组适用于青、甘、川、滇4省中强地震的椭圆烈度分布模型I=f（M,R）.基于所建烈度分布模型,联立考虑中心点和方向性的椭圆数学方程,代入全部烈度数据点估算地震震级和宏观震中.本文的试算震例表明了此方法的可行性,并进行了不确定性分析.利用该方法对明清时期4次烈度点较少的中强历史地震参数进行了估算,所得结果表明了此方法对历史地震有效.     

考虑LS+AR模型基础数据量的极移预报研究

针对目前极移最小二乘(Least Square, LS)+自回归(AutoRegressive, AR)预报模型的单一数据选取方案, 提出分别考虑LS模型数据量和AR残差数据量的组合数据模式, 并对极移预报时单一数据和组合数据预报结果精度进行分析, 探讨模型输入数据量对极移预报精度的影响. 结果表明, 模型输入数据量的变化对极移预报结果影响较大. 采用组合数据预报的方式相比较于单一数据量预报方式精度更高, 特别是针对30--360 d跨度内的中长期预报, 组合数据量的极移预报精度可比单一数据量预报精度有较大改善. 结论证明组合数据在极移预报时具有一定的优势, 可为以后极移预报数据量选取提供一定的借鉴参考意义.     

Site Effects Study in the Serravalle Village (NE Italy) by Means of Spectral Ratios Analyses Relatively to Multiple Reference Sites

The area of Serravalle, sited in the northern part of the town of Vittorio Veneto (TV), NE Italy, has been the target of a seismic microzonation campaign. 10 seismic stations have been deployed for a 7 months period to record in continuous mode. Three stations were installed on bedrock outcrops and seven on sedimentary sites with variable cover thickness. Spectral analyses have been performed on the collected data-set using the Generalized Inversion Technique (GIT, e.g. Andrews, 1986). In particular, spectral ratios have been calculated for each station relatively to the average of the three reference, bedrock sites. The spectral ratios provide quantitative estimates of the seismic motion amplifications which occur in each of the monitored sites. Two sites show high values of amplification, 5 times larger than signal amplitude at the reference sites, in correspondence of well discernible peak frequencies of 5 Hz. Results for the other stations show smaller amounts of site amplification spreading over a broad range of frequencies. Sites where the highest amplifications were recorded all lie on the left bank of the Meschio River and in areas farther away from its outlet into the plain correlating with the presence of thick layers of Quaternary deposits.     

Gold and Platinum-Group Element Analysis of Geochemical and Platinum Reference Materials Using Fluoroxidation Decomposition

A novel method is described for the rapid dissolution of various geological, geochemical and related reference samples for the determination of Au and the platinum-group elements. The decomposition procedure is based on reaction with the fluoroxidants, liquid bromine trifluoride or molten potassium tetrafluorobromate. Results by this novel procedure are compared with data obtained by traditional methods of sample decomposition, including fire assay, autoclave techniques and an aqua regia leach. The oxidative fluorination procedure with the subsequent conversion of fluorocomplexes into the chloride form was found to be an effective and rapid method for the quantification of all the precious metals in a range of sample types.     

多金属结核中二氧化锰的测定

用过量的含有Ｈ２ＳＯ４的（ＮＨ４）２Ｆｅ（ＳＯ４）２溶液分解多金属结核的同时,还原了试样中的ＭｎＯ２,然后以Ｋ２Ｃｒ２Ｏ７标准溶液滴定测定了多金属结核中的ＭｎＯ２。就样品分解过程中的加热温度和时间对测定结果的影响及标准溶液的标定等问题进行了讨论,经多次测定,方法重现性好。应用此方法为新研制的多金属结核标准物质提供了ＭｎＯ２的定值数据,其结果与初定值相符,无剔除值,精密度（ＲＳＤ,ｎ＝８）小于０６％。     

关于在地震预报中遇到的几个问题的探讨

地震台站工作人员 ,在进行观测资料分析、地震预报研究过程中 ,往往会遇到的几个问题 :1、手段单一 ,对于前兆现象无法全面表述。 2、如何识别异常与地震之间的关系。 3、如何兼顾点和面的关系。