Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.     

Ultra-rapid landscape response and sediment yield following glacier retreat, Icy Bay, southern Alaska

The páramo is a neotropical alpine ecosystem that covers more than 75,000 km² of the northern Andes of Colombia, Ecuador, Venezuela, and Peru. It provides important environmental services: more than 10 million people in the Andean highlands benefit from the water supply and regulation function, which is attributed to the volcanic soils that underlie the ecosystem. The soils are also major carbon sinks of global significance. Severe land use changes and soil degradation threaten both the hydrology and carbon sink function. Nevertheless, soil genesis and properties in the páramo is rather poorly understood, nor are their ecological functions well documented. The impact of the geomorphology of the páramo on soil genesis was studied in the rio Paute basin, south Ecuador. Two toposequences were described and analysed. In each toposequence, four pedons were selected representing summit, backslope, undrained plain situation, and valley bottom positions in the landscape. The soils are classified as Hydric Andosols in the World Reference Base for Soil Resources and Epiaquands or Hydrudands in Soil Taxonomy. They are very acidic and have a high organic matter content, high P deficiency, and Al toxicity. Their water content ranges from 2.64 g g^− 1 at saturation, down to 1.24 g g^− 1 at wilting point, resulting in a large water storage capacity. Two major soil forming processes are identified: (1) volcanic ash deposition and (2) accumulation of organic carbon. Volcanic ash deposits may vary in depth as a result of regional geomorphological factors such as parent material, orientation, slope, and altitude. Organic carbon accumulation is an interaction of both waterlogging, which depends on the position in the landscape, and the formation of organometallic complexes with Al and Fe released during volcanic ash breakdown. Despite the high variability in parent material and topography, the soil is characterised by a notable homogeneity in physico-chemical properties. Statistical analysis reveals that only topographic location has a slight but significant influence on soil pH as well as the organic matter content, saturated conductivity and water retention at high pressure. Finally, the exceptional properties of these soils provide useful insights to improve classification of the Andosols reference group of the FAO World reference Base for Soil Resources.     

现今绝对板块运动

根据热点假设,热点对于中间层是固定的.相对热点的板块运动叫做绝对板块运动.绝对板块运动模型可以通过反演火山链传播的速率和走向数据以确定相对板块运动在角速度空间的原点来得到.利用一组近来(0～7.8 Ma)全球分布的热点的迁移速率和走向数据,结合板块运动模型NNR-NUVEL1A,已研制出一个叫做APM2的现今绝对板块运动模型.按照该模型,太平洋板块围绕60.063°S、102.210°E处的极以(0.833 0°±0.013 3°)/Ma的速率运动,非洲板块围绕46.849°N、44.372°W的极以(0.101 5°±0.013 4°)/Ma的速率运动,南极板块的运动则以46.871°N、146.942°E为极,速率为(0.084 6°±0.017 7°)/Ma,欧亚板块的运动更慢,极为27.291°N、171.925°W,速率为(0.065 5°±0.020 6°)/Ma.这一模型表明,岩石圈相对深部地幔有一个以49.423°S、90.625°E为极,速率为(0.198 3°±0.013 5°)/Ma的净旋转.表明太平洋热点同印度-大西洋热点不一致,显示太平洋热点的运动也不一致.为了分析和比较,还给出了仅用全球分布的热点的走向数据和仅用印度-大西洋热点的走向数据得到的板块绝对运动的角速度.     

我院教师文献信息需求调查与分析

作者对该院教师的文献信息使用及需求情况进行了９个方面的调查分析，其结果对学校教学科研的改革和深化具有现实的参考意义。     

浙江省地质遗迹保护工作现状与面临的任务

本文以浙江省地质遗迹的展布特点 ,根据目前地质遗迹保护工作现状和存在的主要问题 ,提出了我省地质遗迹保护工作的任务与拟建地质遗迹保护区参考名录     

农业资源信息标准参考模型研究

为满足全社会对农业资源信息共享的迫切需求,使农业资源信息标准化的工作在统一的框架下进行,借鉴国际地理信息标准制定的思路,初步提出了农业资源信息标准化的技术框架--农业资源信息标准参考模型。该标准参考模型是由指导标准、通用标准、专用标准和领域标准等三个部分组成。本文重点阐述了5个指导标准、4类通用标准的标准组成和要点,提出依据基础标准制定专用标准作为农业资源信息较低层次标准制定的重要原则与方法。农业资源信息标准参考模型对于以信息的积累与服务为主的行业信息标准化具有普遍的指导意义。     

Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).     

大范围网络RTK基准站间整周模糊度实时快速解算

网络RTK是目前实现高精度实时动态定位的重要手段之一,而网络RTK高精度定位的关键问题是基准站间整周模糊度的实时快速准确固定。对于大范围网络RTK,由于基准站间距离的增加,电离层延迟误差、对流层延迟误差和卫星轨道误差相关性降低,导致基准站间整周模糊度不能快速准确地固定,因此本文提出了一种大范围网络RTK基准站间整周模糊度固定算法。该算法首先利用L1、L2载波相位观测值和P1、P2伪距观测值解算基准站间的双差宽巷模糊度;然后采用Saastamoinen模型和Chao映射函数模型相结合解算双差对流层延迟误差,并将双差宽巷模糊度作为L1、L2双差载波相位整周模糊度的约束关系来确定L1、L2双差载波相位整周模糊度;最后采用CORS站的实测数据进行试验,并将本文的试验结果同GAMIT软件的解算结果进行比对,结果表明该算法可以快速准确地实现单历元双差载波相位整周模糊度的固定。     

用于生成DTM的改进的最小二乘匹配(LSM)算法

本文提供了一种用于生成DTM的LSM算法的数学模型。其特点是,引入了辐射线条件和共面条件的几何约束,以及辐射偏差和几何变形参数的虚拟观测方程。试验表明.改善了LSM算法的收敛性、稳定性和可靠性,因而提高了图像配准的质量。     

图像获取条件对SPOT景像的影响

图像获取条件对ＳＰＯＴ景像的构成有极大影响，也直接影响对ＳＰＯＴ图像的处理方法。ＳＰＯＴ图像的辅助数据在解析或数字处理中有重要应用。本文对ＳＰＯＴ卫星与视点间的地心角、节距角ω卫星与视点的纬度差异、景像方位角Ｔ、景像尺寸和ＳＰＯＴ图像格网参考系统ＧＲＳ中（Ｋ，Ｊ）与（λ， Ｂ）换算公式进行了推证和分析，并以ＳＰＯＴ辅助数据验证了（Ｋ，Ｊ）与（λ，Ｂ）换算的精度。