Kr and Xe isotopic compositions of Fe-Mn crusts from the western and central Pacific Ocean and implications for their genesis

Kr and Xe nuclide abundance and isotopic ratios of the uppermost layer of Fe-Mn Crusts from the western and central Pacific Ocean have been determined. The results indicate that the Kr and Xe isotopic composi-tions, like that of He, Ne and Ar, can be classified into two types： low3He/4He type and high3He/4He type. The low3He/4He type crusts have low84Kr and132Xe abundance, while the high3He/4He type crusts have high84Kr and132Xe abundance. The82Kr/84Kr ratios of the low3He/4He type crusts are lower than that of the air, while the83Kr/84Kr and86Kr/84Kr ratios are higher than those of the air. The Kr isotopic ratios of the high-er3He/4He type crusts are quite similar to those of the air. The128Xe/132Xe,130Xe/132Xe and131Xe/132Xe ratios of the low3He/4He type sample are distinctly lower than those of the air, whereas the129Xe/132Xe,134Xe/132Xe and136Xe/132Xe ratios are higher than those of the air. The low3He/4He type samples have the diagnostic characteristics of the MORB, with excess129, 131, 132, 134, 136Xe relative to130Xe compared with the solar wind. The128Xe/132Xe,130Xe/132Xe and131Xe/132Xe ratios of the high3He/4He type samples are slightly higher than those of the air, and the129Xe/132Xe,134Xe/132Xe and136Xe/132Xe ratios are qiute similar to those of the air. The noble gases in the Fe-Mn crusts are derived from the lower mantle, and they are a mixture of lower mantle primitive component, radiogenic component and subduction recycled component. The helium isotopic ra-tios of the low mantle reservoir are predominantly controlled by primitive He （3He） and U and Th radiogenic decayed He （4He）, but the isotopic ratios of the heavier noble gases, such as Ar, Kr and Xe, are controlled to different extent by recycling of subduction components. The difference of the noble isotopic compositions of the two type crusts is the result of the difference of the noble isotopic composition of the mantle source reservoir underneath the seamounts the crusts occurred, the noble gases of the high3He/4He type crusts are     

The role of resource recycling

Resource recycling reduces the amount of waste discharged into the global environment. The waste reduction achieved by thorough recycling is substantial. Recycling is thus an inseparable part of global environmental protection.We human beings have used mineral resources since the birth of our species. The quantities and increasingly complex forms in which mineral resources have been used at different times in our prehistory and history serve as indices of civilization's advancement. But on the eve of the 21st century, environmental pollution and global warming stemming from spiraling resource and energy consumption pose serious dilemmas for humanity. The rapidity with which our resource consumption has increased approximates exponential growth.The worsening condition of the earth's environment because of massive resource and energy consumption is the result of activity at many stages of production, from the mining of mineral resources to the manufacture of finished products; the culmination of the process is the disposal of products as waste after their use. As we shall see from examples given in this paper, efforts are being made to solve this problem through recycling; but in many areas the problems remain incompletely solved or unsolved altogether.     

地球化学组成揭示的杜蒙沙地化学风化和沉积再循环特征及其对风尘物质贡献的指示

对杜蒙沙地的河流冲积砂、河漫滩泥质粉砂、沙质古土壤和风成沙等不同类型沉积物进行了采样（27组）,对这些样品的细颗粒组分（<63 μm）进行了常量元素、微量元素、稀土元素（REE）和Sr-Nd同位素比值等地球化学分析,就杜蒙沙地的化学风化、沉积再循环特征及其对风尘物质的贡献等展开了讨论。结果显示,杜蒙沙地的地球化学组成表现出空间的均一性,低的化学蚀变指数CIA（48~56,平均52）及A-CN-K和A-CNK-FM图解均表明了杜蒙沙地仅遭受了低级的化学风化程度。沙地的成分成熟度较低,大部分河流沉积物表现出初次循环沉积特征,系大兴安岭东侧中酸性岩浆母岩风化剥蚀的产物经嫩江搬运堆积形成;古土壤表现出与河流沉积物相同的初次循环特征,表明古土壤的成土母质是河流沉积物,这与野外地层出露情况一致;风成沙表现出再循环沉积特征,系河流沉积物就地起沙搬运堆积形成。不活动元素比值、REE和Sr-Nd同位素比值等物源判别图解,结合植被和地貌状况,一致表明杜蒙沙地与东北平原中东部的风尘物质没有地球化学亲缘关系,其对该地区（甚至下风向更远地区）的大气风尘的贡献很小。     

中国电子废物的地区间流动

电子废物跨境转移近年来开始引起国际经济地理学者关注,其中折射了全球生产网络中污染控制与市场化再生利用之间的治理矛盾和价值冲突。中国在规范电子废物管理的过程中,采纳了生产者责任延伸制度,逐渐形成生产者缴纳政府基金,基金补贴正规处理厂,正规处理厂再通过市场采购方式从非正式的回收渠道收集电子废物的分工格局。这一格局杂合了巴塞尔公约的属地化管理机制和地区贸易的市场化机制,反映了政府在规制复杂产品环境问题中所面临的两难。本文在多年参与式调查的基础上,根据环保部公布的2014年全国109家正规处理厂实际回收废弃家电产品的数量,采用威尔逊空间相互作用模型,估算了全国非正式回收渠道内的废旧家电产品地区间流动格局,并结合处理厂问卷调查对比了实际流向与理论模型的差异。研究结果显示：由于非正式回收渠道的竞争性所导致的废旧家电跨省流动占到全国正规渠道电子废物回收总量的1/3以上,这与电子废物处理设施省级属地化管理,主要满足本省产生的电子废物处理需求的规划初衷有较大出入。为此本文探讨了这种规划目标与市场流动之间发生错位的内在原因,指出当前电子废物管理重点应该从围绕处理设施的管理控制转向逆向物流系统的优化和商业模式创新。     

‘I hate sand … it gets everywhere’—Phanerozoic sedimentary recycling from NW Africa

Over 10,000 published detrital zircon ages have been reprocessed (applying a +10% normal and reverse concordance range) and analysed to understand the evolution of the detrital zircon record of north-west Africa during the Phanerozoic. Using dissimilarity and clustering analysis, shifts in detrital zircon populations allow interpretation of the evolution of source regions and source to sink systems throughout the Phanerozoic within the West Gondwana superfan. Previous thermochronology and field studies conducted across north-west Africa indicate significant and sustained shifts in source regions in Meso-Cenozoic times which are not recorded in the detrital zircon geochronology record. This discrepancy is most notable for Mesozoic to modern source to sink studies focused on the evolution of the Atlasic rift and opening of the Atlantic and Tethyan Oceans to the west and north respectively. Our results indicate a high degree of similarity between samples from Cambrian times onwards due to successive phases of sediment recycling. This highlights the need to integrate detrital zircon analysis with other techniques to provide confident reconstruction of sediment routing systems across Morocco. This systematic review also reveals the ubiquitous occurrence of Mesoproterozoic zircons within Moroccan sediment. No basement of this age is known from north-west Africa—often described as the ‘Mesoproterozoic Gap’, which was thought to be a diagnostic feature of sediment derived from the West African Craton. However, zircons of this age form 7% of all analysed zircons and are present in sediments from at least 700 Ma. The presence of this population is interpreted as strongly diagnostic of provenance from either the Amazonian Craton or the Eastern Gondwana Orogen within Central Africa. Their presence in the Moroccan detrital record from the Neoproterozoic onwards raises questions about the position of the West African Craton in the Proterozoic, and for the spatial extent of Mesoproterozoic orogeny within north Africa.     

Circuits of scrap: closed loop industrial ecosystems and the geography of US international recyclable material flows 1995–2005

The recycling of scrap material has been identified as an important strategy in the larger theory of industrial ecology. Industrial ecology argues that the traditional model of industrial activity needs to be transformed into a 'closed loop' industrial ecosystem where used materials (scrap) and by-products would substitute for virgin materials during production processes. The recycling of scrap material forms part of this larger effort to reduce the overall environmental impact of production and consumption. A key, but as yet, unresolved question in this process is the geographic scale (local, regional, national, global) at which loop closing should take place. This preliminary empirical research examines the export and import geography of the seven largest (by weight) US scrap commodities (iron and steel, paper, plastics, aluminium, copper, nickel and zinc) between 1995 and 2005 to ascertain the extent to which US scrap flows overseas and how that might affect our understanding of how material loops can close. Other than an integrated export and import relationship with Canada, the results suggest that there are two distinct circuits of scrap flows in the USA. The USA exports a substantial portion of the recyclable scrap generated each year to rapidly developing countries, while importing smaller quantities of scrap from the EU. With the major exception of exporting higher value iron and steel scrap to China, the US tends to export lower value scrap and import higher value scrap. In part this reflects imbalances in the supply and demand for scrap between the USA and the developing world, the lack of potentially available scrap and the absence of a robust recycling infrastructure in the developing world. Although such scrap circuits are probably not ideal, the use of US scrap in the developing world is both a realistic and preferable alternative in the short to medium term than virgin production.     

Adaptation, innovation and domestic food production in Jamaica: Some examples of survival strategies of small-scale farmers

Small-scale farmers' experimental innovations have not generally been considered for on-farm research trials as those in the traditional sector have been perceived as recipients, rather than originators, of technical knowledge and sustainable and viable practices. Yet there is abundant evidence throughout the tropics that small-scale farmers are adaptive and experimental problem solvers, and experts at devising innovative survival strategies. While literature on the topic is rich with accounts from Africa, Asia and Latin America, there is a general dearth of examples from the Caribbean. This paper highlights some examples of farm- and village-level problem solving and survival practices among small-scale domestic food producers in the challenging agroecological environment of Jamaica.     

Petrogenetic significance of high Fe/Mn ratios of the Cenozoic basalts from eastern China

The Cenozoic basalts from eastern China show commonly high Fe/Mn ratios (average = 68.6 ± 11.5) coupled with OIB-type trace element signature. The Cenozoic basalts form the northern margin and the southern margin of the North China Craton are studied in detail. Model calculations point out that the coupling feature of high Fe/Mn ratio with OIB-type trace element signature of these basalts cannot be produced by neither pyroxene/olivine crystallization nor remelting of previously melted mantle, but require partial melting of a garnet pyroxenite-rich mantle source. Combining these features of the Cenozoic basalts with the Phanerozoic lithospheric evolution of the eastern China, we suggest that the Cenozoic basalts were derived from a garnet pyroxenite-rich mantle source associated with continental crust delamination or oceanic crust subduction.     

Methane hydrate recycling offshore of Mauritania probably after the last glacial maximum

To what extent methane liberated from marine hydrate will enter the ocean during a warmer world is unknown. Although methane release due to hydrate dissociation has been modelled, it is unclear whether or not methane will reach the seafloor during a warmer world and therefore contribute to oceanic and atmospheric budgets. Here we show, using a new three-dimensional (3-D) seismic dataset, that some hydrate deposits surround the gas chimneys passing through the HSZ. Bottom water warming since the last glacial maximum (LGM) is interpreted to cause hydrate dissociation but critically some of the released methane was not vented to the ocean. The released gas caused seal failure and free gas entered the hydrate stability zone (HSZ) through vertical gas chimneys to where new hydrate accumulations formed. This process is a new evidence for methane recycling and could account in part for the lack of methane in ice core records that cover warming events during the late Quaternary. This research provides new insight into how methane could be recycled rather than vented during a warmer world.     

一个降水再循环模型的建立及分析

陆-气相互作用是当今水文科学界和大气科学界共同瞩目的一个前沿课题。为寻求陆-气相互作用的某些信号,在长江流域的主体区域上建立了一个降水再循环模型,并分析了这一区域降水的不同水汽来源。依据再循环降水率这个反映陆面过程对当地气候影响的定量指标,得出了一些很有实际意义的结论。