11 Å tobermorite from cement bypass dust and waste container glass: A feasibility study

A novel one-step hydrothermal synthesis of 11 Å tobermorite, a cation exchanger, from a unique combination of waste materials is reported. 11 Å tobermorite was prepared from stoicheiometric quantities of cement bypass dust and waste container glass at 100 °C in water. The product also comprised 10 wt.% calcite and trace quartz as residual parent phases from the cement bypass dust. In a batch sorption study at 20 °C the uptakes of Cd²⁺ and Pb²⁺ by the waste-derived tobermorite product were found to be 171 mg g^− 1 and 467 mg g^− 1, respectively, and in both cases the removal process could be described using a simple pseudo-second-order rate model (k₂ = 2.30 × 10^− 5 g mg^− 1 min^− 1 and 5.09 × 10^− 5 g mg^− 1 min^− 1, respectively). The sorption characteristics of the 11 Å tobermorite are compared with those of other waste-derived sorbents and potential applications are discussed.     

青藏高原那曲地区夏季一次对流云降水过程的云微物理及区域水分收支特征

第三次青藏高原科学试验针对高原夏季云和降水物理过程开展了大量观测研究,为进一步揭示高原云微物理结构、云中水分转化和区域水分收支特征,本文采用中尺度数值预报模式（WRF）并结合高原试验期间的各种观测资料,对那曲观测试验区2014年7月5~6日的一次较为典型的夏季对流云降水过程进行了数值模拟研究。结果表明WRF模式能够基本再现高原夏季对流云的发展演变过程以及降水的日变化特征。模拟结果显示高原夏季对流云中具有较高的过冷云水和霰粒子含量,冰相过程在高原云和降水的形成和发展中具有十分重要的作用,地面降水主要由霰粒子融化产生。暖雨过程对降水的直接贡献很小,但在霰胚形成中具有十分重要的作用。霰粒子胚胎的形成主要来源于冰晶与过冷雨滴的撞冻过程,雪粒子和过冷雨水的碰冻转化及过冷雨滴的均质冻结贡献相对较小。霰粒子的增长过程在12 km（-40℃）以上层主要依靠对冰晶、雪粒子的聚并收集过程,而在其下层的增长过程主要依赖对过冷云水的凇附增长,对雪粒子的聚并收集和凝华增长过程较小。高原那曲地区净水汽收支为正,日平均降水转化率可达20.75%,接近长江下游地区,高于华北、西北地区。该地区日降水再循环率为10.92%,说明局地蒸发的水汽对高原降水的水汽来源具有一定的贡献,但高原降水的90%仍然由外界输入的水汽转化形成。     

European policies on ship recycling: A stakeholder survey

After almost a decade of intensive regulatory activities focused on ship-recycling around the world, special reference is made to combating the problems of ship dismantling practices on the shores of Southern Asian countries. “The Hong Kong International Convention” was adopted in 2009, to provide a uniform shipbreaking management approach. However, in globalised maritime transport, with the majority of shipowners using Open Registries, the European Union has prepared a common approach considering the implementation of a new legal framework. Regulation 1257/2013 implemented by the EU on ship-recycling should be more rigorous than those in the rest of the world. In this article, stakeholder perceptions of this Regulation are presented, based on an online survey. The results show significantly different perceptions in the ship-recycling industry regarding the developing ship-recycling measures within the EU.     

Recycling of Coastal Dredged Sediments from the Northern Nile Delta,Egypt, for Heavy Minerals Exploitation

Mineralogical and textural analyses of 45 undisturbed short cores and 80 grab sediment samples, collected from five frequently dredged navigational areas within harbors and water pathways of the Nile delta littoral system, were utilized for evaluation of these sediments as potential source of economic heavy minerals (EHMs). Results of mineralogical characterization indicate that the average total heavy mineral (HM) concentrations are as follows: Abu Qir Bay (1.7%), Rosetta estuary (3.1%), Burullus fishing port (4.5%), Damietta Harbor (2.9%), and El Gamil lagoon inlet (1.9%). Assessment of HM grades indicates predominance of magnetite, ilmenite, hematite, leucoxene, garnet, zircon, and rutile. Results of the feasibility analysis indicate that dredged sediments at these study areas are considered as a potential source of EHMs and economically promising to be mined for HMs. The present study suggests a practical operative plan of two successive phases for HMs recycling: (1) in-situ initial separation of HMs on the dredger deck using wet-gravity spirals, then (2) transportation of the recovered HM concentrates to an onshore processing plant to selectively separate individual HMs via wet and dry magnetic and electrostatic separators. Alternatively, dredged sediments can be directly pumped to a nearby onshore area as stockpile to be recycled afterward in inland processing plant.     

地壳再循环与大陆碱性玄武岩的成因：以山东新生代碱性玄武岩为例

      大陆碱性玄武岩在地球化学特征上与洋岛玄武岩高度相似,被看做是板内玄武岩在大陆上的典型代表。本文以山东 新生代碱性玄武岩为例,探讨大陆碱性玄武岩的成因。山东新生代碱性玄武岩按时空分布特征可以分为两类：早期定向分 布、相互平行的三个火山群（包括鲁西的潍坊火山群、沂水火山群和胶东的蓬莱火山群）和晚期杂乱分布的孤立小火山。 早期火山群碱性较弱,以碱性橄榄玄武岩和碧玄岩为主,微量元素特征和同位素组成变化大;晚期孤立小火山碱性强,以 碧玄岩和霞石岩为主,微量元素特征和同位素组成较均一。因此,从岩性组成和时空分布特征看,山东的火山群相当于洋 岛/海山的造盾期玄武岩,而孤立小火山接近于洋岛/海山上的复苏期玄武岩。潍坊火山群和沂水火山群在Sr-Nd,Nd-Hf同位 素相关图上都存在从亏损到富集的两端元混合排列趋势,但两者的排列趋势有一点区别。其中同位素富集的端元相对于原 始地幔具有偏低的Ce/Pb比和偏高的Ba/Th比,指示其为大陆下地壳物质。同时,这种富集端元的Th/La比值明显低于大陆下 地壳的平均值,其放射成因Hf相对于放射成因Nd过剩（即Nd-Hf同位素解耦）,说明这种富集端元不是岩浆上升过程中混染 的下地壳物质,而是经历过早期熔融的再循环大陆下地壳（榴辉岩或者石榴辉石岩）。鲁西两个平行火山群在同位素排列上 的区别类似于夏威夷玄武岩中的KEA链和LOA链,因此,山东的平行火山群的深部动力学背景可能是地幔柱,再循环大陆 下地壳物质可能是这种地幔柱的重要组成物质。晚期的孤立小火山在地球化学特征上与火成碳酸岩非常相似,如在原始地 幔标准化图上都具有K,Pb,Zr,Hf,Ti的负异常等特征,因此我们认为其地幔源区为碳酸盐化的橄榄岩。孤立小火山中等亏损 的Sr,Nd,Hf同位素特征支持碳酸岩熔体来自年轻的（中生代？）再循环洋壳。     

Quantifying the Spatial Characteristics of the Moisture Transport Affecting Precipitation Seasonality and Recycling Variability in Central Asia

Moisture contribution and transport pathways for Central Asia(CA)are quantitatively examined using the Lagrangian water cycle model based on reanalysis and observational data to explain the precipitation seasonality and the moisture transport variation during 1979-2015.Westerly-related(northwesterly and westerly)transport explains 42%of CA precipitation and dominates in southwest CA,where precipitation is greatest in the cold season.Southeast CA,including part of Northwest China,experiences its maximum precipitation in the warm season and is solely dominated by southerly transport,which explains about 48%of CA precipitation.The remaining 10%of CA precipitation is explained by northerly transport,which steadily impacts north CA and causes a maximum in precipitation in the warm season.Most CA areas are exposed to seasonally varying moisture transport,except for southeast and north CA,which are impacted by southerly and northerly transport year-round.In general,the midlatitude westerlies-driven transport and the Indian monsoon-driven southerly-related transport explain most of the spatial differences in precipitation seasonality over CA.Moreover,the contribution ratio of local evaporation in CA to precipitation exhibits significant interdecadal variability and a meridionally oriented tripole of moisture transport anomalies.Since the early 2000s,CA has experienced a decade of anomalously low local moisture contribution,which seems jointly determined by the weakened moisture contribution from midlatitudes(the Atlantic,Europe,and CA itself)and the enhanced contribution from high latitudes(West Siberia and the Arctic)and tropical areas(South Asia and the Indian Ocean).     

Zircon recycling and crystallization during formation of chromite- and Ni-arsenide ores in the subcontinental lithospheric mantle (Serranía de Ronda,Spain)

The ultramafic massifs of the Serranía de Ronda (namely Ronda, Ojén and Carratraca) are portions of Proterozoic (∼1.2–1.8 Ga) subcontinental lithospheric mantle (SCLM) affected by partial melting and infiltration of melts. The latter of these events was broadly coeval with the tectonic emplacement of the peridotites into the continental crust in the Early Miocene. This resulted in the formation of chromite and Ni-arsenide ores (Cr-Ni) associated with orthopyroxenites and cordieritites. Six zircons recovered from a massive chromitite sample from the Ronda massif yield both concordant and discordant ages between 2309 ± 37 Ma and 109 ± 15 Ma, and δ¹⁸O between 8.3‰ and 9.4‰. Two Proterozoic ages obtained for zircons of this population (1815 ± 9 Ma and 1794 ± 17 Ma) are identical, within error, to those of zircons reported previously in the garnet pyroxenites of Ronda (1783 ± 37 Ma). Similarly, concordant Early Jurassic (192 ± 13 Ma) and Cretaceous ages (109 ± 15 Ma) obtained from the core and rim, respectively, of a single zircon from the chromitite are also consistent with the ages (180 ± 5 Ma, 178 ± 6 Ma, and 131 ± 3 Ma) already reported for magmatic zircons from corunudum-bearing garnet pyroxenites in the Ronda massif. The observation that chromitites and garnet-pyroxenites contain similar populations of zircons suggests that the parental melts of chromitites inherited zircons from their protolithic garnet pyroxenites, representing relics of oceanic/arc crust recycled in the mantle. Eleven zircons recovered from a massive cordieritite associated with chromitite in the Ronda massif yield scattered concordant and discordant ages between 568 Ma and 21 Ma, with correspondingly variable δ¹⁸O (4.8–13.5‰) and unradiogenic Hf-isotope ratios (ε_Hf(t) from −12.36 to −4.43). The youngest age is concordant at 21.18 ± 0.4 Ma and matches the ages of zircons from the chromitite (weighted average age of 20.4 ± 0.87 Ma, n = 4) and a plagioclasite dyke (scattering between 20.1 ± 0.2 Ma and 17.9 ± 0.1 Ma; n = 11) associated with the Cr-Ni mineralization in the Ojén massif. These zircons show similar unradiogenic Hf-(ε_Hf(t) between −14.5 and −7.6) and heavy O-isotope compositions (δ¹⁸O = 11.3–12.4‰). A sample of the massive cordieritite hosting the chromitites contains abundant zircons that yield scattered concordant, sub-concordant and discordant U-Pb ages varying from 33.8 ± 1 Ma to 781 ± 10 Ma; these zircons (n = 21) have variable U-contents (105–13900 ppm) and Th/U ratios (0.003–0.8). On the basis of O- and Hf-isotope compositions, these zircons define three populations independently of their ages: (1) grains with consistent high δ¹⁸O (6.1–12.7‰) and negative ε_Hf(t) (from −14.42 to −6.88); (2) grains with high δ¹⁸O (7.6–11.1‰) and positive ε_Hf(t) (3.10–4.84); and (3) grains with δ¹⁸O < 5.5‰ typical of mantle values. We suggest that zircons from this cordieritite with U-Pb ages older than Miocene are inherited, and were incorporated physically into the SCLM by fluids or melts produced during dehydration-melting of the crustal rocks wrapping the peridotite massifs. The population of Early Miocene zircons found in the chromitites and associated cordieritites and the plagioclasite dyke in the mineralization of the Ojén massif date the crustal emplacement of the peridotites and, therefore, the formation of the Cr-Ni ores. We propose a model in which the unique Cr-Ni mineralizations found in the ultramafic rocks of the Serranía de Ronda were formed as a result of contamination of the SCLM with crustal components.     

Mg-Sr isotopes of low-δ26Mg basalts tracing recycled carbonate species: Implication for the initial melting depth of the carbonated mantle in Eastern China

ABSTRACT

Recent studies show that crustal carbonates recycled into the mantle can be traced using Mg isotopes of basalts. However, the species of recycled carbonates are poorly constrained. Carbonates have lower δ²⁶Mg values and higher ⁸⁷Sr/⁸⁶Sr ratios relative to the mantle, but different carbonate species display different mixing curves with the mantle in the Mg-Sr isotopic diagram because of differences in their Sr and Mg contents. Thus a combined study of Mg-Sr isotopes can constrain the species of deeply recycled carbonates. Here, we present newly determined ⁸⁷Sr/⁸⁶Sr ratios of the <110 Ma basalts from Eastern China, and together with published Mg isotopic data we evaluate the species of recycled carbonates in the mantle and discuss their implication. The <110 Ma basalts display low δ²⁶Mg values of ?0.60 to ?0.30‰ and relatively low initial ⁸⁷Sr/⁸⁶Sr ratios of 0.70328 to 0.70537, suggesting that their mantle source was hybridized by recycled carbonates with a light Mg isotopic composition which had more significant effects on Mg than Sr isotope ratios. Mg-Sr isotopic data indicate that the recycled carbonates consist of magnesite and aragonite, but the possibility of calcite and dolomite cannot be eliminated. Based on the carbonated peridotite solidus, the equilibrium line between dolomite and magnesite + aragonite, as well as the mantle adiabat, the initial melting depth of the carbonated mantle, the source region of the studied basalts, was constrained at ~300–360 km. Thus, the subducted depth of the west Pacific slab underlying the carbonated mantle and supplying recycled carbonates should be greater than ~300–360 km, consistent with the seismic tomography result that the west Pacific slab now stagnates in the mantle transition zone.     

西安市再生水回用浅析

西安市水资源概况,针对西安市水资源问题提出了西安市再生水回用的必要性及可行性,通过对西安市再生水回用途径的分析,提出了解决西安市再生水回用问题的建议措施,肯定了发展再生水回用事业在缓解西安市水环境日益恶化和水资源短缺等问题中的重要地位.