稀土氧化物及黏土负载La2O3除磷性能的实验研究

地表水体富营养化现象与磷的积累有密切关系,去除水体中溶解态磷是降低富营养化风险的技术关键。近十余年来,稀土元素被用于污水除磷剂的开发,并获得了良好的应用成效。本文实验比较了8种结晶态稀土氧化物(Y_2O_3、La_2O_3、CeO_2、Pr6O11、Nd_2O_3、Sm_2O_3、Eu_2O_3和Dy_2O_3)的除磷性能,结果表明La_2O_3的除磷性能最好,Pr6O11、Y_2O_3、Eu_2O_3、Nd_2O_3次之,Sm_2O_3和Dy_2O_3效果微弱,CeO_2完全没有除磷能力;研究表明稀土氧化物表面磷吸附的动力学行为更符合准一级反应模型,吸附等温线符合Langmuir模型。实验表征了除磷后的稀土氧化物和除磷过程中溶液p H值的变化,认为稀土氧化物除磷是一个表面吸附占主导,氧化物溶解出来的离子辅助沉淀的吸附过程。为了避免稀土氧化物颗粒在水体中发生团聚并降低表面吸附能力,将稀土氧化物La_2O_3微纳米颗粒负载在不同黏土矿物上,发现负载于黏土矿物表面的稀土氧化物除磷能力有较好提升,磷吸附量均提高25%左右。负载等量La_2O_3的3种黏土矿物的除磷性能差异不显著,黏土矿物提高稀土氧化物颗粒分散度可能是后者除磷能力提升的主要原因。     

四川省雷波县瓦岗磷矿地质特征及矿床成因分析

四川省雷波县瓦岗磷矿位于川西南磷矿矿集区的南部,矿体赋存于下寒武统麦地坪组第二段,呈层状展布于瓦尼觉背斜两翼,含矿建造为硅质岩-碳酸岩-磷块岩,矿石结构构造为球状、团块状、条带状,文章通过对矿石和围岩地质特征研究,认为矿床形成于海湾潮下低能带的古地理环境,成因主要为富磷生物碎屑沉积聚集而成。     

1992-2011年夏季南海西部离岸流区涡流相互作用特征

本文利用南海海洋再分析产品REDOS（Reanalysis Dataset of the South China Sea）和风场资料CCMP（Cross-Calibrated,Multi-Platform）,从能量学角度探讨了1992-2011年夏季（6-9月）越南离岸流区域涡-流相互作用特征,并通过能量收支方程诊断评估了风应力、压力梯度、正压不稳定以及平流的相对贡献。以越南离岸流的强度作为分类标准,对1992-2011年划分为正异常年、负异常年和正常年。结果表明,在正异常年,涡动能EKE（Eddy Kinetic Energy）和涡势能EPE（Eddy available Potential Energy）极大值主要分布在越南离岸流附近;在负异常年,EKE极大值向南北两侧分散,EPE极大值向北延伸;在正常年,EKE和EPE的极值空间分布介于正负异常之间。斜压不稳定是EPE年际变化的主要因素,越南离岸流影响周围海域的速度和密度分布,是斜压不稳定的主要原因。而影响EKE年际变化的因素较为复杂,压力做功是最主要的影响因素,风应力做功和平流做功次之,正压不稳定最小,其中正压不稳定依赖于流速大小和由风应力旋度扰动引起的上层水平流速剪切。     

基于环境CGE模型的鄱阳湖流域氮磷排放调控方案及影响模拟

本文基于我国2007年投入产出表和引力模型假设条件下的中国多区域社会经济核算矩阵(SAM)数据库,构建了可计算一般均衡理论和数学优化求解思想的环境CGE(ECGE)模型;并以鄱阳湖流域为研究案例区,设计了两种水质目标下的四种氮、磷营养盐排放调控方案,分别探讨并综合比对了其对江西省及全国其他地区经济增长的影响,为寻求实现鄱阳湖流域经济增长与入湖氮、磷营养盐减排达标的双重目标提供了决策参考信息。研究结果表明,以Ⅲ类水质为控制目标,仅对氮、磷营养盐高排放产业实施减排调控的鄱阳湖流域氮、磷营养盐排放调控方案既能满足当地人们生活改善与区域经济增长的基本要求,又能够通过排污外部成本内在化推动科技投入和生产工艺的改进以不断减少氮、磷营养盐的排放,最终实现人与自然的和谐发展。     

太湖流域望虞河西岸地区氮磷污染来源解析及控制对策

本文比较全面地调查了太湖流域望虞河西岸地区氮磷污染来源,结果表明:太湖流域望虞河西岸水体氮磷污染严重,氮磷污染物主要来源于生活污染,其氨氮、总氮、总磷排放量分别占总负荷量的60.2%、52.5%和52.9%.工业污染问题突出,纺织印染是污染物排放最大的工业行业.张家港市和江阴市为氮磷污染的主要贡献地.对区域环境容量进行了预测,并提出了氮磷污染削减目标,氨氮、总氮和总磷污染削减率分别达32.4%,51.8%和51.1%.最后,从加大污染综合治理力度、落实河道及生态修复工程、加强环境管理和监控等方面提出了望虞河西岸地区的氮磷污染控制对策.     

Influence of hydro-sedimentary factors on mollusc death assemblages in a temperate mixed tide-and-wave dominated coastal environment: Implications for the fossil record

Mollusc death assemblages were recovered in 98 subtidal sampling stations on the seafloor of the shallow Pertuis Charentais Sea (Atlantic coast of France). Taxonomic composition and spatial distribution of death assemblages were investigated, as well as their response to sediment grain size (field data), bottom shear stress (coupled tide and wave hydrodynamic modelling), and sediment budget (bathymetric difference map). Results showed that molluscs are likely to be reliable paleoenvironmental indicators since death assemblages were able to acquire ecological changes within years (decadal-scale taphonomic inertia), and live–dead agreement inferred from existing data on living benthic communities was high, except close to river mouths and intertidal mudflats that provide terrestrial and intertidal species to subtidal death assemblages, respectively. Taxonomic composition of these within-habitat death assemblages strongly depended on sediment grain size and bottom shear stress, similarly to living subtidal communities. Post-mortem dispersal of shells, owing to relatively low bottom shear stress in the area, was only of a few 10s to 100s of meters, which shows that death assemblages preserved environmental gradients even at a fine spatial scale. Sediment budget had also a significant influence on death assemblages. Thick-shelled epifaunal species were correlated with erosion areas on one side, and thin-shelled infaunal species with deposition on the other, showing that mollusc fossil assemblages could be used as indicators of paleo-sedimentation rate. This new proxy was successfully tested on a previously published Holocene mollusc fossil record from the same area. It was possible to refine the paleoenvironmental interpretation already proposed, in accordance with existing stratigraphic and sedimentological data.     

Pumping-induced Well Hydraulics and Groundwater Budget in a Leaky Aquifer System with Vertical Heterogeneity in Aquitard Hydraulic Properties

In groundwater hydrology, aquitard heterogeneity is often less considered compared to aquifers, despite its significant impact on groundwater hydraulics and groundwater resources evaluation. A semi-analytical solution is derived for pumping-induced well hydraulics and groundwater budget with consideration of vertical heterogeneity in aquitard hydraulic conductivity (K) and specific storage (Ss). The proposed new solution is innovative in its partitioning of the aquitard into multiple homogeneous sub-layers to enable consideration of various forms of vertically heterogeneous K or Ss. Two scenarios of analytical investigations are explored: one is the presence of aquitard interlayers with distinct K or Ss values, a common field-scale occurrence; another is an exponentially depth-decaying aquitard Ss, a regional-scale phenomenon supported by statistical analysis. Analytical investigations reveal that a low-K interlayer can significantly increase aquifer drawdown and enhance aquifer/aquitard depletion; a high-Ss interlayer can noticeably reduce aquifer drawdown and increase aquitard depletion. Locations of low-K or high-Ss interlayers also significantly impact well hydraulics and groundwater budget. In the context of an exponentially depth-decaying aquitard Ss, a larger decay exponent can enhance aquifer drawdown. When using current models with a vertically homogeneous aquitard, half the sum of the geometric and harmonic means of exponentially depth-decaying aquitard Ss should be used to calculate aquitard depletion and unconfined aquifer leakage.     

From experimental plots to experimental landscapes: topography,erosion and deposition in sub‐humid badlands from Structure‐from‐Motion photogrammetry

In the last decade advances in surveying technology have opened up the possibility of representing topography and monitoring surface changes over experimental plots (<10 m²) in high resolution (~10³ points m^‐1). Yet the representativeness of these small plots is limited. With ‘Structure‐from‐Motion’ (SfM) and ‘Multi‐View Stereo’ (MVS) techniques now becoming part of the geomorphologist's toolkit, there is potential to expand further the scale at which we characterise topography and monitor geomorphic change morphometrically. Moving beyond previous plot‐scale work using Terrestrial Laser Scanning (TLS) surveys, this paper validates robustly a number of SfM‐MVS surveys against total station and extensive TLS data at three nested scales: plots (<30 m²) within a small catchment (4710 m²) within an eroding marl badland landscape (~1 km²). SfM surveys from a number of platforms are evaluated based on: (i) topography; (ii) sub‐grid roughness; and (iii) change‐detection capabilities at an annual scale. Oblique ground‐based images can provide a high‐quality surface equivalent to TLS at the plot scale, but become unreliable over larger areas of complex terrain. Degradation of surface quality with range is observed clearly for SfM models derived from aerial imagery. Recently modelled ‘doming’ effects from the use of vertical imagery are proven empirically as a piloted gyrocopter survey at 50m altitude with convergent off‐nadir imagery provided higher quality data than an Unmanned Aerial Vehicle (UAV) flying at the same height and collecting vertical imagery. For soil erosion monitoring, SfM can provide data comparable with TLS only from small survey ranges (~5 m) and is best limited to survey ranges ~10–20 m. Synthesis of these results with existing validation studies shows a clear degradation of root‐mean squared error (RMSE) with survey range, with a median ratio between RMSE and survey range of 1:639, and highlights the effect of the validation method (e.g. point‐cloud or raster‐based) on the estimated quality. Copyright © 2015 John Wiley & Sons, Ltd.     

德国WBGU碳预算方案解析与中国社会科学院方案比较

在《联合国气候变化框架公约》第15次缔约方会议召开前夕,德国发布了一份旨在通过对未来排放空间进行管理以实现长期减排目标、构建全球低碳经济的国际气候制度设计方案。该方案的研究思路与中国社会科学院学者提出的碳预算方案基本一致,但是两种方案在参数选择、减排路径、历史责任计算等问题上存在较大分歧。虽然德国方案力图平衡南北双方在气候领域的不同利益诉求,但从结果上看,德国方案明显有利于发达国家集团,公平性不足,难以达到其方案设计效果。     

137Cs示踪技术在黑土区农业非点源污染负荷研究中的应用

利用¹³⁷Cs核素示踪和定位监测相结合,研究松嫩平原黑土区3个旱作坡面土壤的流失厚度和流失速率,坡面土壤流失厚度1.20~5.25 mm/a,侵蚀强度1 355.0~7 558.2 t/(km²·a);近40 a来,松嫩平原黑土区年均入河(湖)农业非点源污染负荷分别为TN 1.43 t/(km²·a)、NH₃^-N 15.01 kg/(km²·a)、NO₃^-N 8.51 kg/(km²·a)TP 0.42 t/(km²·a)、PO₄^3--P 1.85 kg/(km²·a);土壤流失氮以有机氮为主;水溶态无机氮占总氮的0.51%,水溶性磷酸盐磷占总磷的0.12%。黑土区农业非点源污染物的输出和水土流失密切相关,深入研究其输移机理及防治措施具有重要的环境意义。