中原油田高压注水诱发的油水井套管损坏原因分析

中原油田高压注水开发35年,套管损坏严重,严重的影响了油田的开发效果。据研究,油田水井套管损坏主要有错断、变形及破漏等三类,平面上主要分布在断层发育区、高地层水矿化度区、泥岩层和盐膏层发育区,剖面上主要分布在盐膏层段和主力生产井段。提出断层活动、地应力非均质演化、盐岩蠕变、油田开发历程和开采方式及油气流场、化学场演化是中原油田套损的主要控制因素,建立油田油藏油井多参数动态模式,优选与油藏模式匹配的开采方式及增产措施,改造套管动力学环境和化学环境将能防治套损地质灾害的发生。     

沂源县田庄水库农业面源氮素淋滤行为研究

受农业面源影响,典型山区水库-田庄水库氮素超标,通过模拟土壤在不同降雨强度与不同降雨类型下的淋滤行为,探讨氮素淋溶释放规律,并对田庄水库农业面源氮素入库量进行了计算。结果表明,降雨类型和降雨强度只影响土壤中氨氮峰值浓度出现的时间,对其数值影响不大,由于土壤中硝氮含量较高,使降雨强度和类型对其淋出液中的硝氮峰值浓度产生的时间和数值都有所影响;农业面源氮污染通过田庄水库四条入库河流年均排入水库中的硝氮总量高达604．49t,氨氮为23．85t。     

我国地下水污染调查评价中的水质分析技术

在介绍我国地下水污染调查与评价工作的基础上,结合地质矿产实验室的实际情况,总结并探讨了其水质分析的技术体系和最新成果,对开展地下水污染样品的检测和质量管理具有一定的实用价值和指导意义。     

松辽盆地十屋油田营城组油气分布

应用试油与压裂测试分析法、流体组成成份分析法、生产动态分析法和物质平衡分析法对十屋油田营城组营Ⅰ、营Ⅱ、营Ⅲ和营Ⅴ油层组的油气分布进行了精细研究。结果表明, 气层发育在十屋逆断层的北部地区, 分布在八屋断裂的两侧; 营Ⅰ和营Ⅱ油层发育在十屋逆断层北部D3和B7井区; 营Ⅲ和营Ⅴ油层发育于十屋油田东部, 十屋逆断层两侧的A24、A25、A16及A11井区; 油气同层只在南部和北部的少数井区分布。     

气体、泡沫等欠平衡钻井条件下感应测井应用分析

对气体、泡沫等欠平衡钻井条件下测井方式进行阐述,通过不同钻井液电阻率下对感应测井进行数字模拟,发现气体、泡沫等介质对感应测井影响较小。天然气介质和原油介质条件下感应测井现场实验的资料分析说明,感应测井在气体、泡沫等欠平衡钻井条件下可行。     

油页岩灰渣提取氧化铝制备铝酸盐发光材料

利用干馏后的油页岩灰渣,湿法提取氧化铝作为发光材料基质,经采用高温固相法合成 CaAl2O4 : Eu3 + ,R + ( R = Li,Na,K,Rb) 荧光粉。最佳合成条件为: 烧结温度1 200 ℃,烧结时间3 h,助熔剂加入量3 wt%,激活离子配比3 mol%; 实验发现辅助激活离子为Li + 时,CaAl2O4 : Eu3 + , Li + 的发光强度最强。样品荧光光谱分析结果表明,发射光谱在615 nm 处出现强谱峰,归属为Eu3 + 的5D0→7F2 跃迁辐射。     

强烈气洗作用导致原油成分变化的定量计算:以库车坳陷天然气藏为例

库车坳陷以产天然气为主,同时产出少量原油和凝析油,油气充注不同步,普遍具有"油早气晚"的特点,晚期大量天然气的侵入,必然对早期聚集的油藏发生改造作用。对气藏中原油成分变化的定量计算和讨论,可为天然气的注入强度定量评价提供直接证据。未遭受气洗的原油,正构烷烃摩尔浓度的对数与相应的碳数呈线性关系,而气洗作用可使轻组分的正构烷烃最先溶解于干气中,并随着天然气继续向前运移,原始油藏中的轻组分正构烷烃大大减少。以此为理论基础,建立了正构烷烃损失的定量计算模型。结果表明克拉2构造原油正构烷烃损失程度最高,平均可达70%左右,大北构造带原油正构烷烃损失程度差异较大,与该地区断块发育有关。气洗作用导致原油正构烷烃减少,而金刚烷、多环芳烃等在天然气中溶解度较低的化合物得以浓缩富集,相对含量大大增加。轻芳烃含量也会随之而增加,原油芳香度增加,石蜡度降低。在模拟实验基础上对气洗程度进行了定量评价,初步估算表明,克拉2构造原油遭受的气洗作用最强,是其他构造带的2～5倍。     

A geochemical survey of trace elements in agricultural and non-agricultural topsoil in Dexing area,China

In China, soil pollution is very serious, which has jeopardized the ecology, food safety, the people's health, and even the sustainable development of agriculture. In order to investigate the soil pollution situation, a total of 874 agricultural and non-agricultural topsoil samples were collected from Dexing area, northeast of Jiangxi Province, China. The total elemental concentrations of 17 elements (As, Hg, Mo, Cd, Cr, Zn, Cu, Mn, Ti, Pb, Fe, Ca, K, Si, Al, Mg, and Na) were determined. The geochemical background and threshold was predicted with the method of the median ± median absolute deviation (MAD). The agricultural soil median concentration of trace elements was similar to that of the non-agricultural soil. In contrast to Jiangxi soil background of trace elements, the geochemical background of the study area was obviously higher. The maps of the pollution indices for As, Cd, Cr, Cu, Hg, Mn, Mo, Pb, Ti and Zn of non-agricultural soil and agricultural soils in the study area, showed that the highest level of pollution is distributed near and along the Lean River, especially in the neighboring and surrounding Dexing and Leping mining area.     

Selenium content in soils from Murcia Region (SE,Spain)

The objective of this study was to determine the selenium content in soils from the Region of Murcia (SE, Spain) and to study the possible relationship between mineralogical composition, soil properties and selenium content. In addition, generic reference level (GRL) for selenium was determined according to Spanish legislation. For this study, 490 samples were selected in areas subjected to agricultural activity or abandoned agricultural soils with natural vegetation. Five different zones were established in order to study selenium variability. Four different mineralogical groups were established, based on significant relationship with the mineralogical composition, and each sample was included in one mineralogical group. The results showed that the concentration of selenium is correlated with the electrical conductivity, sulphate content and with the mineralogical composition, particularly positively with quartz and in a negative way with calcite percentage. In addition, selenium level was positively correlated with the phyllosilicate content. Established GRL for selenium varies with the mineralogical group, having a great transcendence from the legal and economic points of view.     

松辽盆地北部中浅层含油饱和度和孔隙度的关系与油气侵位对成岩作用的抑制

为了研究油气侵位对松辽盆地中浅层成岩作用和孔隙度衰减的抑制作用,本文系统的统计和分析了该盆地大量的孔隙度和含油饱和度岩芯分析数据。结果表明,所有探井储层的孔隙度与含油饱和度之间均呈正相关关系,储层含油饱和度越高,孔隙度越大,而且中部含油组合中萨尔图油层、葡萄花油层和高台子油层二者的相关性好于下部含油组合中扶余油层和杨大城子油层的相关性。由此可见,油气注入储层之后,可以有效地抑制储层的成岩作用,保护孔隙,而且油气注入越早,越有利于孔隙的保护。