原子荧光光谱分析环境样品中砷锑铋汞易出现的问题及解决方法

针对原子荧光光谱法测试砷锑铋汞中易出现的仪器空白不稳定、样品制备及仪器污染等问题，总结出相应的解决方法。     

Assessment of regional karstification degree and groundwater sensitivity to pollution using hydrograph analysis in the Velka Fatra Mountains, Slovakia

Hydrograph analyses of groundwater depletion process in the spring were used for estimation of karstification degree and groundwater sensitivity to pollution in the whole catchment area. Differences of individual depletion hydrographs enable assessment of the anticipated extent of absorption, attenuation and self-purification processes during the groundwater penetration through the rock environment between its infiltration and its outflow in the spring. The method was applied in the SW part of the Velka Fatra Mountains (Slovakia) “Tlsta” hydrogeological structure. In total, 209 individual recession curves from 20 gauged springs were analyzed. Depending on characteristic groundwater depletion hydrographs with independent sub-regimes, categories of groundwater sensitivity to pollution were defined. Finally, resulting sensitivities to pollution were linked to lithostratigraphical units in the area.     

Study of galvanic interactions between pyrite and chalcopyrite in a flowing system: implications for the environment

When galvanic interactions between pyrite and chalcopyrite occur in solution, pyrite, with the higher rest potential, acts as a cathode and is protected whereas chalcopyrite, with the lower rest potential, acts as an anode and its oxidation is increased. In this work a three-electrode system was used to investigate the corrosion current density and mixed potential of a galvanic cell comprising a pyrite cathode and a chalcopyrite anode in a flowing system. The results showed that with increasing concentration of ferric ion in the solution, with increasing acidity, and with increasing flow rate of the solution, the corrosion current density increased and the mixed potential of the galvanic cell became more positive. These experimental results are of direct significance to the control of environmental pollution in mining activity. By using the galvanic model, mixed potential theory, and the Butler–Volmer equation, the experimental results were explained theoretically.     

Simultaneous identification of a single pollution point-source location and contamination time under known flow field conditions

A theoretical framework is presented that allows direct identification of a single point-source pollution location and time in heterogeneous multidimensional systems under known flow field conditions. Based on the concept of the transfer function theory, it is shown that an observed pollution plume contains all the necessary information to predict the concentration at the unknown pollution source when a reversed flow field transport simulation is performed. This target concentration C₀ is obtained from a quadratic integral of the observed pollution plume itself. Backwards simulation of the pollution plume leads to shrinkage of the C₀-contour due to dispersion. When the C₀-contour reduces to a singular point, i.e. becomes a concentration maximum, the position of the pollution source is identified and the backward simulation time indicates the time elapsed since the contaminant release. The theoretical basis of the method is first developed for the ideal case that the pollution plume is entirely known and is illustrated using a synthetic heterogeneous 2D example where all the hydro-dispersive parameters are known. The same example is then used to illustrate the procedure for a more realistic case, i.e. where only few observation points exist.     

节水灌溉与农业面源污染控制研究--以新疆焉耆盆地为例

针对我国北方农业面源污染面积大、分布广、控制难的问题，通过分析新疆焉耆盆地水资源利用现状、潜水位动态、农田排水特征，认为大水漫灌不仅浪费水资源，造成肥料流失，降低产量，而且污染水体，导致土壤次生盐渍化；提出了推广节水灌溉、合理开发利用水资源、控制农业面源污染、综合治理环境的有效途径。     

用离子色谱法测定金矿区水样中常规无机离子

利用DX－120离子色谱仪进行阴阳离子的精密度和准确度测定，100mg/L时相对标准偏差范围为1．00％－3．80％，回收经95．83％－105．00％；5mg／L时相对标准偏差范围为1．18％－4．57％，回收率92．40％－103．20％，完全达到实际要求。用该离子色谱仪测定甘肃阳山金矿山水样中常规无机离子，数据表明该区域水质较好，所测离子浓度都未超过饮用水标准。     

水资源中氯代烃污染物的去除方法

随着工业化的发展。氯代有机溶剂使用越来越广泛。并且难于去除。在20世纪90年代初期，人们就已认识到用Fe^0恢复污染的地下水的潜力。国外正在研究帮使用扔几种还原挥发性氯代烃的还原反应介质，尤其要提高的是双金属反应系统，反应速度快，而且脱Cl中国难解产物少，目前国也只停留在实验室研究阶段，个别做了地上反应器的验证实验，它的脱Cl机理、介质钝化和完全脱Cl问题还有待于进一步研究。     

攀枝花地区不同工业区表层土壤中重金属分布的特征

作者在本文中研究了攀枝花地区不同工业区表层土壤中重金属的污染特征及元素组合。结果表明，煤矿区以Cd,Ni,Cu,Zn污染为主，攀钢工业区以Ni,Cu,Cd, Cr污染为主，其它工业区以Cd,Ni污染为主。不同工业区的重金属元素组合特征基本一致，即分为As-Cd-Cu-Ni-Pb和Cr-Zn两组。     

油水层快速识别改进的CP网络方法初探

CP网络具有分类快速、准确等优点。文中详细介绍了CP网络的算法,并对其进行了部分改进,增加了误差检验和网络测试功能;使用VisualBasic6.0开发了相应仿真软件,并将其用于某油田的油、水层快速识别。实际应用表明:改进的CP网络训练周期短、识别准确率高,完全可以用于油、水层等的快速识别,具有广阔的应用前景。     

BP神经网络识别塔北低阻油气层

简要介绍了塔北低阻油气层岩性剖面、低阻油气层地球物理测井曲线特征,分析了塔北地区低阻油气储层成因,重点论述BP人工神经网络识别油气层、油水同层、水层和干层的方法原理。识别实例表明,BP人工神经网络识别低阻油(气)、水层的结果与实际相符,明显地提高了测井的解释精度。