西华山脉钨矿床的形成压力及有关花岗岩的侵位深度

文章阐述了西华山黑钨矿-石英脉与普通热液石英脉的不同之处;分析了前人所获压力值较低(30~70MPa)的主要原因;利用黑钨矿-石英脉绿柱石中两相气液包裹体和不混溶硅酸盐熔融包裹体的有关资料及相关相图,求得西华山脉钨矿床的形成压力为200MPa。根据西华山脉钨矿床产出的地质特征以及岩石学、矿物学、稳定同位素和流体包裹体地球化学等证据论证了这一压力的合理性。     

新疆东天山花岗岩类岩石形成的物理化学条件

通过对新疆东天山花岗岩类岩石中的角闪石、斜长石、碱性长石、磷灰石、黑云母成分的系统研究,确定花岗岩类岩石在11—17km深处结晶;无矿化、蚀变的二长花岗岩结晶温度约550℃,花岗闪长岩、石英二长岩的结晶温度为552—650℃,钠长石化的含矿二长花岗岩其二长石平衡温度均低于510℃,蚀变愈强烈,平衡温度愈低。二长花岗岩的起源温度为780—840℃,石英二长岩的起源温度为860—880℃,碱长花岗岩的起源温度最低。推算得到二长花岗岩的极限起源深度为28—32km,石英二长岩的极限起源深度为33—34km。HF,HCI逸度计算表明,它们趋向于岩浆晚阶段富集,但无论是早结晶的磷灰石,还是晚结晶的黑云母,总是钠长石化的含矿花岗岩低于正常无蚀变、无交代现象花岗岩的逸度值,正常花岗岩类岩石由黑云母指示的f_(HC(?)),f_(HF)分别为36.60—51.10kPa,1.20—1.60 kPa。花岗岩类岩石形成的fo_2为1.05×10~(-11)—3.11×10~(-11)Pa,而钠长石化的含矿二长花岗岩具最低的氧逸度,为1.48×10~(-17)—2.45×10~(-15)Pa。     

Conditions of pocket formation in the Oktyabrskaya tourmaline-rich gem pegmatite (the Malkhan field, Central Transbaikalia, Russia)

Coexisting melt (MI), fluid-melt (FMI) and fluid (FI) inclusions in quartz from the Oktaybrskaya pegmatite, central Transbaikalia, have been studied and the thermodynamic modeling of PVTX-properties of aqueous orthoboric-acid fluids has been carried out to define the conditions of pocket formation. At room temperature, FMI in early pocket quartz and in quartz from the coarse-grained quartz–oligoclase host pegmatite contain crystalline aggregates and an orthoboric-acid fluid. The portion of FMI in inclusion assemblages decreases and the volume of fluid in inclusions increases from the early to the late growth zones in the pocket quartz. No FMI have been found in the late growth zones. Significant variations of solid/fluid ratios in the neighboring FMI result from heterogeneous entrapment of coexisting melts and fluids by a host mineral. Raman spectroscopy, SEM EDS and EMPA indicate that the crystalline aggregates in FMI are dominated by mica minerals of the boron-rich muscovite–nanpingite CsAl₂[AlSi₃O₁₀](OH,F)₂ series as well as lepidolite. Topaz, quartz, potassium feldspar and several unidentified minerals occur in much lower amounts. Fluid isolations in FMI and FI have similar total salinity (4–8 wt.% NaCl eq.) and H₃BO₃ contents (12–16 wt.%). The melt inclusions in host-pegmatite quartz homogenize at 570–600 °C. The silicate crystalline aggregates in large inclusions in pocket quartz completely melt at 615 °C. However, even after those inclusions were significantly overheated at 650±10 °C and 2.5 kbar during 24 h they remained non-homogeneous and displayed two types: (i) glass+unmelted crystals and (ii) fluid+glass. The FMI glasses contain 1.94–2.73 wt.% F, 2.51 wt.% B₂O₃, 3.64–5.20 wt.% Cs₂O, 0.54 wt.% Li₂O, 0.57 wt.% Ta₂O₅, 0.10 wt.% Nb₂O₅, 0.12 wt.% BeO. The H₂O content of the glass could exceed 12 wt.%. Such compositions suggest that the residual melts of the latest magmatic stage were strongly enriched in H₂O, B, F, Cs and contained elevated concentrations of Li, Be, Ta, and Nb. FMI microthermometry showed that those melts could have crystallized at 615–550 °C.

Crystallization of quartz–feldspar pegmatite matrix leads to the formation of H₂O-, B- and F-enriched residual melts and associated fluids (prototypes of pockets). Fluids of different compositions and residual melts of different liquidus–solidus P–T-conditions would form pockets with various internal fluid pressures. During crystallization, those melts release more aqueous fluids resulting in a further increase of the fluid pressure in pockets. A significant overpressure and a possible pressure gradient between the neighboring pockets would induce fracturing of pockets and “fluid explosions”. The fracturing commonly results in the crushing of pocket walls, formation of new fractures connecting adjacent pockets, heterogenization and mixing of pocket fluids. Such newly formed fluids would interact with a primary pegmatite matrix along the fractures and cause autometasomatic alteration, recrystallization, leaching and formation of “primary–secondary” pockets.     

辽东早元古代裂谷多金属硫铁矿地质及其成矿规律

辽东早元古代地层内赋存着一系列多金属硫铁矿床。矿床的形成与分布主要受裂谷盆地演化及含矿建造控制。在不同的演化阶段分别形成了含钴黄铁矿 含铜黄铁矿 含硬石膏黄铁矿矿床系列和含硼（镁电气石）磁黄铁矿 含铅锌黄铁矿 重晶石闪锌黄铁矿矿床系列。依据成矿特征可分为海底火山喷气沉积与海底喷气沉积两种成因类型。成矿作用受裂谷、次级盆地、一定含矿层位和特殊容矿岩石相互联系与配套的控矿因素制约。在对成矿规律研究的基础上将该区多金属硫铁矿划分为６个成矿远景区。     

Compressibility and swelling characteristics of Al-Khobar Palygorskite, eastern Saudi Arabia

Expansive soils are found in different locations in eastern Saudi Arabia. The area is arid with high temperatures, highly variable humidity and an excessive rate of evaporation compared to the low precipitation. This resulted in the formation of water sensitive soils. In the present investigation, line valve buildings for a sweet water feeder (1118 mm in diameter) were constructed on a highly expansive material consisting mainly of brown palygorskite and gray palygorskite with thin sheets of gypsum and limestone. Block samples from both palygorskites were brought to the laboratory and cores as well as remolded samples were obtained from the blocks. The two palygorskites were found to be highly plastic and have a very high swelling potential. The liquid limit (LL) and plastic limit (PL) values for the brown palygorskite are 261% and 140%, respectively. The gray palygorskite has a LL of a 285% and a PL of 123%. The oedometer free swell tests for the two palygorskites produced an expansion ranging between 31.8% and 42.5% for the remolded samples. However, the expansion for cores ranges between 8.3% and 19.3%. The constant volume pressure tests produced a stress in excess of 4240 kPa. The swell potential reached a steady state after four days while the swelling pressure reached a steady state in about 3 h. The paper addresses the geology of the area, the characterization of the geomaterial including mineralogical composition using X-ray diffraction and SEM techniques and the swelling characteristics of the material.     

C型采场支承压力分布特征的数值模拟研究

冲击地压的发生与支承压力的分布有重要关系。为研究C型采场支承压力的动态变化规律,采用FLAC3D软件对孤岛工作面推进过程中煤体垂直应力场进行了数值模拟。通过对工作面推进过程中煤体支承压力的平面分布特征、走向支承压力和倾斜支承压力的动态演化特征进行分析,得到以下结论：① 煤体中垂直应力分布呈“C”形;② 孤岛工作面超前支承压力影响距离为正常工作面的3～5倍;③ 双工作面“见方”时,支承压力峰值达到最大值。工程实例验证了结论的可靠性,其结果可为现场冲击地压预测和防治提供依据。     

合肥盆地磨墩水库石墨片岩变形变质分析及构造意义探讨

合肥盆地中南部肥西县磨墩水库南岸防虎山组侏罗系砾岩下发育一套石墨片岩系,两者之间呈断层接触.该石墨片岩不同于钻井揭示的合肥盆地石炭纪一二叠纪沉积岩,亦不同于河南固始县杨山煤系.经分析认为该石墨片岩应属于北淮阳佛子岭群岩系,原岩为炭质泥岩或炭质粉砂岩.石墨为有机成因,石墨化程度较低,但变形强烈,部分已糜棱岩—超糜棱岩,反映出俯冲—碰撞带变形变质特征.通过对白云母、石墨XRD衍射和电子探针测试分析,认为石墨片岩为绿片岩相,估算其变质温度为450～ 500℃,压力0.55 ～0.8GPa.根据显微构造特征和变形—变质条件推断,该石墨片岩为扬子板块北缘的沉积盖层(佛子岭群部分),在扬子板块与华北板块碰撞过程中受到强烈挤压,变形—变质成糜棱岩、石墨构造片岩.该变形带暗示了扬子板块向华北板块缝合带的位置,即石墨片岩出露区及其附近,部分被新生代沉积所覆盖.     

异常压力与油气分布

随着油气勘探活动的不断加深，国内外相继发现了许多异常高压油气田。据不完全统计，全世界已发现超压盆地１８０多个，其中１６０多个为富含油气盆地。异常高压油气田约占全球油气田３０％左右，因此，对异常压力的研究，具有举足轻重的意义。本文介绍了异常地层压力的概念、特征及分类；详细论述了异常压力的成因，即烃类生成作用、欠压实作用、液态烃类的裂解作用、粘土矿物的后生成岩作用、构造作用、温度变化等；系统阐述了世界典型含油气盆地的超压形成机制、超压体系中油气初次运移机理以及超压与油气分布关系；并在此基础上，归纳总结出了五种超压油气藏成藏模式，即：（１）位于超压体系中的低渗超压油气藏；（２）位于超压层系中，以礁灰岩（或浊积砂岩）为储层的高压油气藏；（３）位于超压带上倾方向，以退覆三角洲平原和分流河道砂岩为储层的常压或过渡带超压油气藏；（４）位于超压带上、下部的超压油气藏；（５）位于远离超压体系的泄压区常压油气藏，本文对指导、加深新老油气区勘探具有实际应用价值。     

中国优质碎屑岩深层储层控制因素综述

根据中国深层储层分布广,地质条件差异大的实际情况,认为沉积环境、地温、深埋藏时间、溶解与胶结作用、烃类充注、异常压力、绿泥石环边为深层储层的主要控制因素,并对每一种因素作了具体分析,指出深层储层的分布可以用3种模式来进行预测。     

新疆且日克其菱铁矿床稀土元素地球化学特征

新疆且日克其菱铁矿床赋存于下志留统温泉沟群中低级变质岩系中,由三个矿段组成,总体呈层状、似层状、透镜状.矿石稀土含量较高(∑REE=740.97 ×10-6～820.21×10-6),轻稀土富集(LREE/HREE=13.17～14.74)的特征暗示了矿床形成于弱-中碱性的含矿溶液;明显的Ce正异常(δCe=3.25～...