YSZ-50型声频振动钻机的研制

声频振动钻进技术是近年来发展较快的新型钻探技术,主要利用声频振动头产生的高频振动力,引起钻柱系统的共振,并带来土体的局部液化,实现快速钻进和高质量地质取样。主要介绍了YSZ-50型声频振动钻机的结构设计、主要技术参数和特点以及取样试验。     

粒度不均匀铬矿石取样代表性的研究

以一批进口土耳其铬矿石为例,对所取的40个样品进行0～ 10 mm、10 ～ 50 mm、50 ～ 150 mm、150～ 250 mm及大于250 mm五个区间的粒度筛分,分析粒度不均匀的铬矿石在各粒度区间内组分含量和所占质量百分比的差异情况.根据分析结果对40个样品在50 ～ 150 mm区间内的质量百分比与样品总组分含量进行相关性分析,结果表明:两者的相关系数为0.466,相关系数的显著性概率为0.002,小于0.01,说明在50～150 mm粒度区间内矿石的质量百分比与样品的总含量的相关性是高度显著的,提出为了提高粒度不均匀的铬矿石取样代表性,应首先保证在所含矿石质量百分比与总组分含量相关性最大的粒度区间内(50 ～ 150 mm),所取矿石样品与实际货物中矿石的质量百分比相一致.     

Sampling epifauna, a necessity for a better assessment of benthic ecosystem functioning: an example of the epibenthic aggregated species Ophiothrix fragilis from the Bay of Seine

Sampling the sea bottom surface remains difficult because of the surface hydraulic shock due to water flowing through the gear (i.e., the bow wave effect) and the loss of epifauna organisms due to the gear’s closing mechanism. Slow-moving mobile epifauna, such as the ophiuroid Ophiothrix fragilis, form high-density patches in the English Channel, not only on pebbles like in the Dover Strait or offshore Brittany but also on gravel in the Bay of Seine (>5000 ind m⁻²). Such populations form high biomasses and control the water transfer from the water column to the sediment. Estimating their real density and biomass is essential for the assessment of benthic ecosystem functioning using trophic web modelling. In this paper, we present and discuss the patch patterns and sampling efficiency of the different methods for collecting in the dense beds of O. fragilis in the Bay of Seine. The large Hamon grab (0.25 m⁻²) highly under-estimated the ophiuroid density, while the Smith McIntyre appeared adequate among the tested sampling grabs. Nowadays, diving sampling, underwater photography and videos with remote operated vehicle appear to be the recommended alternatives to estimate the real density of such dense slow-moving mobile epifauna.     

顶空进样-固相微萃取测定饮用水源水中吡啶

用75μm CarboxenTM-Polydimethylsiloxane(CAR-PDMS)固相微萃取头顶空萃取15 mL水样中的吡啶,萃取物用气相色谱-质谱法进行分离和检测,采用内标法和质谱的选择离子监测模式进行定量分析。优化了顶空进样-固相微萃取条件,获得较佳的萃取温度(58.0℃)和萃取时间(40 min)。在优化的条件下,方法检出限为1.5μg/L,标准曲线的线性相关系数为0.9994,线性范围为2.5～50.0μg/L;饮用水源水和纯水加标平均回收率为75.6%～81.3%,相对标准偏差(RSD,n=6)为9.60%～12.21%。使用顶空萃取方式可避免样品基体的复杂性,有利于保护萃取头涂层,同时无需使用有机萃取溶剂;使用质谱检测器可减小假阳性带来的影响。顶空进样-固相微萃取操作简单、环保、灵敏度高,适合用于饮用水源水中吡啶的监测分析。     

长江入海口浅层沉积物中典型有机氯农药分布特征

对长江入海口包括江苏启东,上海崇明岛、长兴岛、横沙岛等地区的浅层沉积物中典型有机氯农药(OCPs)的分布情况进行了研究。采用气相色谱-电子捕获检测器进行检测,方法检出限为0.10 ng/g,回收率为62.4%～116.7%,精密度(RSD)为2.7%～8.3%。调查分析结果显示,长江入海口沿岸均存在轻度和中度的OCPs污染,主要检出物总滴滴涕(DDTs)浓度范围为1.22～626.43 ng/g。深度(0～80 cm)采样检测结果表明,研究区表层及深度样品中DDTs均有不同程度检出,浅层沉积物中DDTs在0～20 cm区域占检出总量的58.1%;其次是20～40 cm区域,DDTs占总量的30.8%;40～60 cm区域DDTs占总量的8.2%;60～80 cm区域DDTs占总量的2.9%,即浅层沉积物中DDTs主要集中在0～40 cm区域,部分点位40～80 cm能够检出少量DDTs。本研究提供的数据为该地区OCPs垂直分布提供参考。     

污染调查中的水、土样品采集技术

地下水污染日益严重。钻探是地下水污染勘察方法中最直接、最准确的技术方法,是地下水污染调查的重要手段之一。通过取心、取样,可以获得地下污染信息。取心、取样质量的好坏对取得的地下水污染调查资料真实性至关重要。在地下水污染调查中,要根据调查场地的条件和调查目的选择合适的采样方法,并严格按照操作规程进行采样,以取得真实、有代表性的样品。     

q祁连山永久冻土带天然气水合物钻探工艺与应用

大量的研究和钻探取样证明,不仅海洋深处存在着天然气水合物,陆地永久冻土带也存在天然气水合物。从目前的地质探测技术发展现状看,确定冻土层水合物的储藏深度、含量等物理化学特性还必须靠取样钻探技术。论述了全球陆地永久冻土带天然气水合物的钻探现状,介绍了陆地永久冻土带天然气水合物取心钻具的结构设计、试制过程和在海拔4200m的青海祁连山地区进行永久冻土带天然气水合物钻探技术研究过程中取得的成果。     

基于OLHS随机模拟的地下水源地保护区划分

为解决确定性模型可能为地下水源地划分带来的保护不足或过保护问题,探索采用基于正交拉丁超立方抽样法的地下水模型研究,并结合粒子反向追踪技术,进行地下水流随机模拟和对应保护区的概率统计分析,最终得到具有分布概率的保护区范围。为验证该方法的实用性与可靠性,选取北京市平谷区王都庄应急水源地进行实例应用研究。在考虑渗透系数和降雨补给量随机抽样组合基础上进行地下水流动随机模拟,并完成对应保护区划分和加权统计。与确定性模拟划分结果相对比:一级保护区中,确定性模拟划分结果仅相当于随机模拟结果中统计概率70%以上的范围;对于二级保护区,确定法对应保护面积相当于随机模拟结果中50%概率以上的范围。实例研究表明,基于正交拉丁超立方抽样的随机模拟法可完成多个不确定性输入变量条件下的随机模拟,且在小样本数的基础上获得理想结果,适用于复杂水文地质条件下的地下水源地保护区划分研究。     

An Exploration of the Interplay between the Measurement Uncertainty and the Number of Samples in Contaminated Land Investigations

In the assessment of potentially contaminated land, the number of samples and the uncertainty of the measurements (including that from sampling) are both important factors in the planning and implementation of an investigation. Both parameters also effect the interpretation of the measurements produced, and the process of making decisions based upon those measurements. However, despite their importance, previously there has been no method for assessing if an investigation is fit‐for‐purpose with respect to both of these parameters. The Whole Site Optimised Contaminated Land Investigation (WSOCLI) method has been developed to address this issue, and to allow the optimisation of an investigation with respect to both the number of samples and the measurement uncertainty, using an economic loss function. This function was developed to calculate an ‘expectation of (financial) loss’, incorporating costs of the investigation itself, subsequent land remediation, and potential consequential costs. To allow the evaluation of the WSOCLI method a computer program ‘OCLISIM’ has been developed to produce sample data from simulated contaminated land investigations. One advantage of such an approach is that as the ‘true’ contaminant concentrations are created by the program, these values are known, which is not the case in a real contaminated land investigation. This enables direct comparisons between functions of the ‘true’ concentrations and functions of the simulated measurements. A second advantage of simulation for this purpose is that the WSOCLI method can be tested on many different patterns and intensities of contamination. The WSOCLI method performed particularly well at high sampling densities producing expectations of financial loss that approximated to the true costs, which were also calculated by the program. WSOCLI was shown to produce notable trends in the relationship between the overall cost (i.e., expectation of loss) and both the number of samples and the measurement uncertainty, which are: (a) low measurement uncertainty was optimal when the decision threshold was between the mean background and the mean hot spot concentrations. (b) When the hot spot mean concentration is equal to or near the decision threshold, then mid‐range measurement uncertainties were optimal. (c) When the decision threshold exceeds the mean of the hot spot, mid‐range measurement uncertainties were optimal. The trends indicate that the uncertainty may continue to rise if the difference between hot spot mean and the decision threshold increases further. (d) In any of the above scenarios, the optimal measurement uncertainty was lower if there is a large geochemical variance (i.e., heterogeneity) within the hot spot. (e) The optimal number of samples for each scenario was indicated by the WSOCLI method, and was between 50 and 100 for the scenarios considered generally; although there was significant noise in the predictions, which needs to be addressed in future work to allow such conclusions to be clearer.     

煤矿三维地震勘探技术发展趋势

我国煤田三维地震勘探经过20余年的发展,已成为当前煤田地质勘探的主流技术,随着煤矿采掘现代化及安全保障系统对勘探精度要求的提高,三维地震勘探技术也须与之相适应,不断地探索与发展。参考近年来相关研究成果与勘探实例,对可在煤田地质勘探中大面积推广应用的三维地震勘探技术进行了介绍,其中包括：高密度空间采样、数字检波器、高精度静校正技术、叠前时间（深度）偏移技术、分频解释技术、波阻抗反演技术、相干体技术,同时也简要介绍了在煤田勘探方面有发展前景的多分量及各向异性技术。