基于支持向量机的喀斯特山区土壤环境质量评价——以贵州北部一茶叶园区为例

以贵州北部一茶叶园区80个表层土壤样品为研究对象,对其Hg、As、Cd、Pb、Cr和Cu含量进行测定,在MATLAB中应用支持向量机构建土壤环境质量评价模型,并与模糊综合评价法和内梅罗综合污染指数法的评价结果对比分析,探究支持向量机模型在喀斯特山区土壤环境质量评价中的适用性,其结果表明:研究区土壤质量Ⅰ类与Ⅱ类样品比例为33∶7,土壤环境质量大多数为I类;支持向量机方法的评价结果与模糊综合评价法和内梅罗综合污染指数法结果的相同率分别达到82.5%和80.0%,并分析结果有差异的样品,发现支持向量机评价结果更符合实际情况,这说明该模型适用于土壤环境质量的评价。      

江西省山地风场风速订正方法研究

利用气象站、探空及NASA再分析资料,对江西省4县山地风场的12座测风塔风速进行订正研究。研究结果表明:测风塔与气象站风速数据相关性较低,相关系数一般远小于0.45;测风塔与探空资料的风速相关系数可达到0.6以上,最高可达到0.8;NASA再分析资料可以作为江西山地风场风速订正参证数据,其与测风塔风速数据相关性较高,相关系数可达到0.54～0.77,大多数测风塔相关系数可达0.7左右。海拔高度小于1000 m的测风塔与NASA 50 m风速的相关系数明显高于其与NASA 850 hPa风速的相关系数,高度为1000—1200 m的测风塔与NASA 50 m风速和与NASA 850 hPa风速的相关系数相差不明显,高度大于1200 m的测风塔与NASA 850 hPa风速的相关系数明显大于其与NASA 50 m风速的相关系数。比值法订正效果略好于线性回归法的,订正后的风功率密度总体偏大。     

京津冀地区低层局地大气环流的气候特征研究

本文采用2007-2016年的中尺度数值模拟结果和15个地面气象站观测资料,定义了局地风场表征风速,研究京津冀平原地区局地大气环流日变化的气候特征,并对区域大气污染及其输送的影响进行分析。此外,对2016年12月30日至2017年1月7日北京地区跨年大气重污染过程进行了个例分析。得到结论:京津冀平原地区低空风场变化是天气系统与局地大气环流共同作用的结果,山谷风环流致使太行山和燕山沿线平原地区大气边界层内的长年主导风向为偏北和偏南;太行山和燕山沿线地区山谷风环流本身呈顺时针旋转的日变化特征,夜间至早晨谷风转向山风,午后至夜间山风转向谷风;在午后谷风向山风转向期间,容易形成沿太行山东麓和燕山南麓、自南向东北的"弓形"气流输送通道,此气流输送通道在1月于21时左右形成,持续时间大约3 h,在7月于18时左右形成,持续时间可达9 h;冬季午后至晚间盛行谷风时,受山体的阻挡,污染物容易在山前累积,导致污染浓度增高;夏季同样的情况会发生在后半夜。     

四川地形扰动对降水分布影响

引入一维加权平均的谱分析方法定量研究四川地形强迫对该区域降水分布的影响。结果表明:纬向地形和冬季降水谱峰锁相于同一波长（475.8 km）,呈共振关系,地形与其他季节降水呈漂移关系,这与经向和纬向上环流变动有关,即冬季纬向环流占主导,纬向地形触发的大气波动对冬季降水策动作用大;夏季降水是各种不同尺度系统相互作用的结果,地形是重要因素之一。经向和纬向地形特征尺度分别为296.8 km和475.8 km,反映了地形强迫的中尺度特征,且纬向地形谱峰比经向大1个数量级,纬向强迫更明显。夏季降水谱峰比冬季大2个数量级,降水系统纬向特征尺度比冬季小约150 km,说明夏季在纬向地形强迫下,降水系统尺度减小的同时其强度大大增加,这在一定程度上可以解释中尺度对流性降水在夏季偏多。四川夏季最大降水位于雅安地区,其地形扰动比四川整体扰动更明显,故产生的降水也更大。夏季降水和经向地形锁相于同一波长（37.1 km）,经向地形对雅安夏季强降水起关键作用。     

La3+ 离子掺杂钨酸铅单晶的微结构缺陷

钨酸铅晶体是一种非化学计量化合物,缺陷丰富,蕴含着利用掺杂产生新效应和开发新功能的广泛可能性。探讨了不同浓度La3 掺杂对于钨酸铅晶体发光性能的影响,如热释光、X射线激发发光、光致发光等。La3 掺杂有效地抑制了陷阱中心,使发光受到强烈的抑制,在高浓度掺杂的钨酸铅中,激发机制有所改变,通过XPS测试的结果分析了不同浓度La3 掺杂机制。低浓度掺杂中,La3 取代Pb2 ,形成缺陷复合体[2(La3Pb ).-(VPb)″];高浓度掺杂晶体中,La3 离子不但占据Pb2 位置,而且也会占据W6 位置(La3W ),产生La3 的自补偿机制,形成La3 的自补偿对[(La3W )-(La3Pb ).]-(VO)..或缺陷聚集体[3(LaP3b ).-(La3W )]。     

大黄鱼病原副溶血弧菌拮抗菌的筛选

用点种法从大黄鱼肠道优势菌群中筛选出104株病原性副溶血弧菌的拮抗菌,进一步研究拮抗效果最好的11株拮抗菌的抗菌谱和生长曲线,其中NAC平板上筛选的4株拮抗菌的抗菌范围较广,锰营养琼脂培养基上筛选的3株拮抗菌具有生长优势。用BIOLOG板测定了抗菌谱较广、有一定生长优势3株拮抗菌(R22,Y58和J312)的碳源利用情况,结果表明,3株拮抗菌的碳源谱都比较广,都能利用糖类、有机酸和氨基酸等,而且与鱼类营养的竞争较小。16S rRNA基因同源性分析的结果显示与R22,Y58,J312同源性达99%以上的菌株分别来自弧菌属、芽孢杆菌属和假单胞菌属。进一步对R22,J312和Y58三株拮抗菌进行生化鉴定,结果显示R22为溶藻弧菌,J312为荧光假单胞菌,但Y58的种属未能得到确认。所得到的3株拮抗菌R22,Y58,J312在拮抗病原菌、抗菌谱、生长特性和营养利用等方面都初步满足益生菌的筛选条件,有待进一步检测其安全性和实用效果以便能够成为能实用的益生菌。     

Large-scale dune erosion tests to study the influence of wave periods

Large-scale physical model tests were performed to quantify the effects of the wave period on dune erosion. Attention was focussed on 2D cross-shore effects in a situation with sandy dunes and extreme water levels and wave conditions. Besides profile measurements, detailed measurements in time and space of water pressure, flow velocities and sediment concentrations were performed in the near near-shore area. It was concluded that a longer wave period leads to a larger dune erosion volume and to a larger landward retreat of the dune face. Tests with double-peaked wave spectra showed that the influence of the spectral shape on dune erosion was best represented by the T_m − 1,0 spectral mean wave period, better than the peak wave period, T_p. The effect of the wave period on dune erosion was implemented in a dune erosion prediction method that estimates erosion volumes during normative storm conditions for the Dutch coast. More details of the measurements and additional analyses of physical processes are described in an accompanying paper by Van Thiel de Vries et al. [Van Thiel de Vries, J.S.M., van Gent, M.R.A., Reniers, A.J.H.M. and Walstra, D.J.R., submitted for publication. Analysis of dune erosion processes in large scale flume experiments, In this volume of Coastal Engineering.].     

DFT对Rb+水合团簇及其相关性质的分析

运用密度泛函理论(DFT)在ωB97XD/gen (O、H元素Aug-cc-PVDZ; Rb元素Lanl2DZ)基组水平上研究了[Rb(H_2O)_n]~+(n=1～12)水合团簇的结构和光谱学性质。研究结果表明,通过分析气相和液相中的稳定能以及水合团簇可知,稳定构型出现在8配位的团簇中。第一配位层水分子数为8时形成Rb~+第一近似饱和水合层。此外,拉曼光谱显示[Rb(H_2O)_n]~+(n=1～12)水合团簇中O-H伸缩振动峰随着水分子数增加发生移动和加宽,Rb~+发生水合时,O-H对称和非对称伸缩振动发生红移,随着水合数的增多,频率蓝移。此外,文中对拉曼光谱中O-H振动的频率位置结合团簇结构进行了说明。     

山东蒙山与四川海螺沟冰川擦痕特征对比及成因分析

冰川擦痕在冰川遗迹的判断中具有极为重要的意义,其中以槽谷岩壁擦痕与冰碛砾石擦痕最为明显。槽谷岩壁擦痕具有细长密集、近似平行的特征;冰碛砾石擦痕具有短粗稀疏、方向杂乱的特征。除此之外,还有弧形擦痕、逆冲擦痕、新月形凿口、新月形裂纹、新月形裂口、颤痕等刻蚀遗迹的配套产出。经对比分析,蒙山发育的擦痕与四川海螺沟现代冰川谷内的擦痕具有完全的一致性,因此进一步确定了蒙山擦痕的冰川成因。     

Access routes to high mountain huts facing climate-induced environmental changes and adaptive strategies in the Western Alps since the 1990s

ABSTRACT

In the European Alps, high mountain environments are subject to major impacts resulting from climate change, which strongly affect human activities such as mountaineering. The purpose of the study was to examine changes in access routes to 30 high mountain huts in the Western Alps since the 1990s. Data were derived from the use of two different methods, geo-historical studies and a questionnaire, and were used to identify both the climate-related processes affecting the climbing routes and the strategies implemented by public entities, Alpine clubs, guide companies, and hut keepers to maintain acceptable safety and technical conditions. The case studies revealed issues affecting three access routes and the results from the questionnaire showed that the main processes affecting access routes were loss of ice thickness and retreat from the front of the glaciated areas. Commonly, in situ equipment was installed to facilitate access for mountaineers and/or a part of a route was relocated to a safer area. The authors conclude that in most cases, the measures were effective but they were limited by financial, ethical and legal issues, especially in protected or classified areas that could jeopardise their durability and effectiveness.