直流弧光放电等离子体CVD金刚石薄膜中的晶体类型与特征

采用自主研制的直流弧光放电等离子体CVD设备,以甲烷和氢气为气源,在YG6硬质合金基体上制备出主显晶面为（100）、（111）以及纳米晶粒的金刚石薄膜涂层。SEM观测其晶体类型主要为立方体、八面体、立方八面体,其中以立方八面体为主。随着碳源气体浓度的增加,金刚石晶体的形态会呈现从八面体一立方八面体一立方体顺序转变的趋势;而薄膜的表面形貌呈现从主显（111）晶面-（111）与（100）晶面混杂-主显（100）晶面顺序转变的特征。此外,CVD金刚石薄膜中还存在有许多类似接触孪晶、贯穿孪晶、复合孪晶,以及球形或聚晶晶粒形态的晶体,并且多数孪晶属于类似（111）复合孪晶结构。     

Characteristics of magnetic and non-magnetic lag in the Cobar area, NSW

Geochemical patterns from two lag anomalies in the Cobar region of central New South Wales are described. The region is semi-arid, deeply weathered and some areas are covered by variable thicknesses of aeolian and alluvial transported overburden.Lag morphology and mineralogy are related to landform. In erosional landforms the surface is covered by lag, which is composed of coarse fragments derived locally from bedrock and displays varying degrees of ferruginization, together with a range of secondary pisoids. In depositional landforms the lag is less abundant and contains more pisoids. Deflation by sheetwash may lead to lag being partially buried by alluvium. In a large proportion of pisoid lag, hematite and goethite have been converted to maghemite, allowing ready separation into magnetic and non-magnetic fractions. The non-magnetic fraction is dominated by the lithic lag whereas the magnetic fraction is dominated by pisoid lag.The magnetic and non-magnetic components of the 2–11 mm lag fraction, milled to < 75 μm and subjected to HF-HNO₃-HClO₄ attack, give rise to distinct geochemical patterns at targets related to a variant of the Cobar style of Pb-Zn mineralization with variable silicification and to Zn mineralization in a swarm of quartz and carbonate veinlets. The patterns are influenced by metal source, lag type, surface chemical conditions and landtbrm. Differences in the correlation between metal contents in the magnetic and non-magnetic lag components, and between trace elements and Fe. indicate variable loss of Cu and Zn from the magnetic lag at some targets but retention of Pb. The presence of a readily cxtractable base metal component in the lag has implications for detecting anomalies in transported cover in the region.     

Evaluating river morphology change with a geomorphic form variation approach

Geomorphic river design strives for natural resilience by encouraging geomorphic form complexity and morphological processes linked to greater habitat diversity. Increasing availability of high-resolution topographic data and spatial feature mapping methods provide advantages for morphological analysis and river restoration planning. We propose and evaluate an approach to quantifying topographic variability of geomorphic form and pixel-level surface roughness resulting from channel planform geometry differences using spatially continuous variety computation applied to component metrics including flow direction, aspect and planform curvature. We define this as the geomorphic form variation (GFV) approach and found it scalable, repeatable and a multi-stage analytical metric for quantifying physical aspects of river-bed topographic variability. GFV may complement process-based morphological feature mapping applications, hydraulic assessment indices and spatial habitat heterogeneity metrics commonly used for ecological quality evaluation and river restoration. The GFV was tested on controlled synthetic channels derived from River Builder software and quasi-controlled sinuous planform flume experiment channels. Component variety metrics respond independently to specific geometric surface changes and are sensitive to multi-scaled morphology change, including coarser-grained sediment distributions of pixel-level surface roughness. GFV showed systematic patterns of change related to the effects of channel geometry, vertical bed feature (pool-bar) frequency and amplitude, and bar size, shape and orientation. Hotspot analysis found that bar margins were major components of topographic complexity, whereas grain-scale variety class maps further supported the multi-stage analytical capability and scalability of the GFV approach. The GFV can provide an overall variety value that may support river restoration decision-making and planning, particularly when geomorphic complexity enhancement is a design objective. Analysing metric variety values with statistically significant hotspot cluster maps and complementary process-based software and mapping applications allows variety correspondence to systematic feature changes to be assessed, providing an analytical approach for river morphology change comparison, channel design and geomorphic process restoration.     

Morphometry and distribution of isolated caves as a guide for phreatic and confined paleohydrological conditions

Isolated caves are a special cave type common in most karst terrains, formed by prolonged slow water flow where aggressivity is locally boosted. The morphometry and distribution of isolated caves are used here to reconstruct the paleohydrology of a karstic mountain range. Within a homogenous karstic rock sequence, two main types of isolated caves are distinguished, and each is associated with a special hydrogeologic setting: maze caves form by rising water in the confined zone of the aquifer, under the Mt. Scopus Group (Israel) confinement, while chamber caves are formed in phreatic conditions, apparently by lateral flow mixing with a vadose input from above.     

砂土颗粒三维形态的定量表征方法

颗粒形态是影响砂土力学特性的重要因素,特别是影响砂土在低应力状态下的抗剪强度、剪胀效应和临界状态行为,以及高应力状态下的颗粒破碎行为。因此,准确地重构砂粒的三维形态,并量化计算其形态表征参数是研究砂粒形态效应的前提工作。借助于高精度的CT扫描技术和图像处理技术,获得近海石英砂和风化花岗岩残积砂这两类砂土颗粒的三维形态信息。采用球谐函数序列实现两种砂颗粒三维形态的准确重构,并通过球谐函数分析计算砂土颗粒的体积来验证该方法的有效性。基于球谐重构的三维砂粒表面,提出了实用性的方法来计算砂粒的表面积、表面曲率和三维尺寸等,进而计算砂粒的三维球度、圆度和伸长率等形态表征参数。结果表明,当球谐函数阶达到15时,其重构的砂粒基本形状和表面纹理均与真实砂粒非常接近;近海石英砂在水流搬运和磨蚀的作用下颗粒形态较为规则和圆滑,球度和圆度较大,而风化花岗岩残积砂则在物理风化和剥蚀作用下颗粒形态较为复杂和粗糙,球度和圆度较小;而这两种地质作用对砂土颗粒的伸长率则没有明显的影响。     

The influence of increased iron concentration on survival and growth of seedlings and young plants of eelgrass Zostera marina

Iron (Fe) is an essential nutrient for plants but toxic at high concentrations. We subjected seedlings and young plants of eelgrass Zostera marina to different seawater iron concentrations (500, 600, 700, 800, 1,000 and 1,500 μg/L) for 30 days under controlled laboratory conditions. Natural seawater without added iron (500 μg/L) was used as reference seawater. No sediments were provided to avoid iron scavenging by particle surfaces in the sediment. We measured plant response in terms of survivorship, morphology, growth rate and productivity. Survival analysis combined with morphological, dynamic and productive assessment suggested that the optimum seawater iron concentration for the establishment of Z. marina seedlings and young plants is 700 μg/L. The no observed effect concentration, lowest observed effect concentration, lethal concentration that caused an increase in mortality to 10% of that of the control, and the effect concentration that caused a decrease in growth to 10% of that of the control values of young plants were significantly lower than those of seedlings, implying an increased sensitivity to high Fe concentrations (>1,000 μg/L). This study further develops our understanding of the physiological ecology of the early life stages of Z. marina and provides data that could prove helpful in the development of successful eelgrass restoration and conservation.     

基于小波变换和数学形态学的潮沟提取方法研究

潮沟是潮滩的主要地貌类型之一,潮沟信息的检测对湿地生态环境的监测和保护有着重要意义。本文以长江口九段沙下沙北部发育比较复杂的潮沟为研究对象,使用2016年1月26日Landsat8全色波段数据,采用了一种融合小波变换、最大类间方差法和数学形态学的方法对潮沟边缘信息进行了检测。小波变换中通过减小高层小波系数,达到弱化潮滩灰度变化的目的;通过增大低层小波系数,达到增强潮沟信息的目的;利用数学形态学和图像之间的几何(加减乘)运算,完成潮沟的提取;最后,分别在原始数据和检测结果相应的位置取样进行精度验证,样方潮沟面积一致性精度平均为92.1%。     

江南丘陵区农村居民点地域分异特征及类型划分——以长沙市为例

以长沙市2013年Landsat TM遥感影像图和长沙市的行政区划矢量图为基础,借助于ERDAS、MapGIS、ArcGIS、Fragtats、SPSS软件,运用探索性空间数据分析、景观形状指数模型及聚类分析法,从空间、规模与形态等方面探讨长沙市农村居民点地域分异特征、地域类型及调控路径。研究表明：长沙市农村居民点地域分异特征明显,在空间分布上呈现出由长沙市中部向东西两侧呈阶梯状稀疏化分布;而规模普遍偏小,规模分布自西向东呈现“波浪状”结构;在形态格局上,则表现为布局分散且形态复杂、不规则。通过采用聚类分析方法,将长沙市农村居民点划分为低密度散点型、低密度团簇型、中密度团簇型、高密度团簇型、中密度团块型、中密度条带型、高密度条带型7种,并从人口集聚、产业发展、基础设施与公共服务设施提升等方面提出了各地域类型优化调控的路径。     

基于凸壳原理的杭州城市扩展形态演化分析

在城市化快速推进的背景下,探索凸壳原理在城市扩展形态识别中的应用价值,并借此分析杭州市主城区1985~2010年间城市扩展形态演化规律及其机理,以期为控制城市扩展形态,指导未来城市土地开发活动提供借鉴。研究发现,凸壳原理在城市扩展形态识别上简单而明确,通过确定已有城市建设用地的凸壳,将城市所有可开发用地明确区分为凸壳内用地和凸壳外用地2类,为采取差别化的空间管理政策提供依据。构建了基于凸壳原理的城市扩展形态计算机识别方法,有利于在城市扩展模拟中实现城市扩展形态影响因素的定量化表达。1996年之前,杭州市建设用地和凸壳面积增长缓慢,城市形态相对紧凑;1996年之后,建设用地快速增长,城市不均衡扩展加剧,凸壳面积陡增,城市形态紧凑程度下降。总体来看杭州市城市扩展类型属于外延型,随着凸壳面积的增加,城市填充潜力随之增强,为促进杭州市城市紧凑化发展,应该严格控制凸壳外的城市土地开发。沿主干道的城市开发是城市形态外延式发展的主要因素,已有建设用地周边以及城市内部次要道路沿线的城市开发,以及城市中心的集聚作用和规划对城市开发的控制是城市形态填充式发展的主要因素,而郊区化发展和“东扩西进”等城市空间发展政策促使特定时期城市外延式发展。     

乌鲁木齐霾天气PM10单颗粒物理化学特征

为了解乌鲁木齐冬季污染天气形成过程中大气颗粒物化学组分的变化,探讨霾天气快速形成的主要原因,应用扫描电镜/X射线能谱仪(SEM/EDX)对2013年2月乌鲁木齐东南郊一次典型霾天和正常天气所采集的大气颗粒物(PM₁₀)样品进行了微观形貌和化学组成的对比分析。结果表明:伴随着霾形成过程细粒子浓度呈现急剧上升趋势,PM_1.0/PM₁₀比值高达0.77。SEM/EDX观测显示,霾天形成前后,PM₁₀的形态结构和元素组成存在较明显的差异,霾天规则的石膏颗粒占规则颗粒的71.1%,明显高于正常天气,表明大气颗粒物的硫化现象比较普遍,大量硅铝酸盐飞灰说明采样点周边有较明显的燃煤源输送;二次无机颗粒组成主要为硫酸盐颗粒,由正常天气的16.1%增加到24.6%,高浓度硫酸盐与乌鲁木齐东南郊此次霾形成有密切的联系。