改性粘土絮凝法对大西洋鲑(Salmo salar)存活及生理生化的影响初探

本文以平均体重为(388.00±41.11)g的大西洋鲑(Salmosalar)为实验对象,探究了改性粘土絮凝过程对养殖水体水质以及大西洋鲑存活、组织形态和氧化应激反应的影响。在本实验条件下,添加改性粘土的实验组水质得到一定程度的改善,其中磷酸盐、铵盐、亚硝酸盐浓度相较于对照组有明显降低的趋势(P0.05)。添加远高于现场可有效去除赤潮生物用量(4—10g/m~2)的改性粘土并没有导致大西洋鲑出现死亡现象,显微观察结果显示,实验组与对照组中大西洋鲑鱼鳃、消化道组织特征无明显差别。对大西洋鲑鳃、肝脏、消化道的丙二醛(MDA)含量、超氧化物歧化酶(SOD)和过氧化氢酶(CAT)活性测定结果表明,改性粘土未对大西洋鲑造成显著的氧化胁迫(P0.05)。本研究结果说明,在远高于现场有效用量条件下,改性粘土未对大西洋鲑产生不良影响,该研究结果将为改性粘土治理有害藻华技术在国内外养殖海域的应用提供科学依据。     

Loading performance of fish and OMNI-Max anchors in crust-over-soft clays

This paper reports the results from three-dimensional dynamic finite element analysis undertaken to provide insight into the behaviour of the fish and OMNI-max dynamically installed anchors during loading in crust-over-soft clay sediments. Particular attention was focused on the situations where the anchor is embedded to a shallow depth during dynamic installation due to the strong crust layer. Large deformation finite element analyses were carried out using the coupled Eulerian-Lagrangian approach, incoporating the anchor chain effect. Parametric analyses were undertaken varying the initial embedment depth, anchor shape, loading angle, strength ratio between the top and bottom layers. The tracked anchor trajectory confirmed that the diving potential of the fish and OMNI-Max anchors were enhanced by the presence of the crust layer as that somewhat restircted the upward movement. This will be beneficial for many hydrocarbon active regions with layered seabed sediments where the anchor embedment depths during dynamic installation are expected to be low.     

关于结构土屈服破坏的探讨

天然沉积土往往均为结构土,结构土的屈服破坏是研究结构土力学性状的关键问题之一。但是,结构土的屈服破坏至今没有合理明确的定义。对两种天然沉积软粘土的高质量不扰动土样进行了固结压缩试验和三轴等向固结不排水剪切试验以探讨结构土的力学性状。基于结构土的强度特性,提出了当外加应力达到固结屈服应力时结构土达到完全屈服破坏的新概念,并且初步探讨了结构土的强度性状与变形特性的本质联系与其耦合问题。     

Degradation of Coking Wastewater under Microwave Irradiation in the Presence of Modified Activated Carbon

In this study, a new material consisting of activated‐carbon‐containing magnetic oxide is prepared for assisted microwave (MW) irradiation treatment of coking wastewater. The optimum condition for degrading coking wastewater is 98.14% chemical oxygen demand (COD), under which 87.57% ammonia nitrogen (NH₃–N) can be removed. The results are verified by GC–MS, showing that most organic pollutants can be adsorbed by modified activated carbon (MAC). The surface morphology and elemental composition of MAC before and after microwave irradiation and adsorption is determined by scanning electron microscopy. After microwave irradiation, many apertures of pores looked relatively large. It can be shown that MAC as a catalyst in the microwave‐assisted treatment process has many advantages, including rapid degradation of COD and NH₃–N. In conclusion, microwave‐irradiation‐assisted MAC treatment of coking wastewater is a novel technology that is economical, efficient, and has broad prospects for development.     

一种手性辅助试剂C_2-对称二亚砜的合成方法研究

采用改良的Ｓｈａｒｐｌｅｓｓ氧化条件,以氢过氧化枯烯为氧化剂,成功地对二硫醚１进行了不对称氧化得到单亚砜６,其光学纯度为１００％,产率为６０％。用臭氧将单亚砜６进一步氧化,以３６％的产率和１００％ｅｅ得到Ｃ２对称二亚砜７,从而建立了合成Ｃ２－对称二亚砜７手性辅助试齐的有效方法。     

Pre-Failure Behavior of Deep-Situated Osaka Clay

Great interest has been aroused on deeply-situated Osaka clay since Kobe Earthquake in1994.In this paper is presented the analysis on the results of a series of lab tests on Osaka clay situatedfrom 100m to 1500m under the ground.The wave velocity method,bender element method,LDT and theformula derived by the authors are used,focus is put on the pre-failure mechanical behavior of the clay.The analysis shows that,(i)pore-pressure coefficient B is less than 1.0,(ii)the relationship between shearmodulus and Poisson＇s ratio is not in agreement with that reported before,(iii)the modulus measured withLDT is still less than that measured with bender element method,and(iv)there are two threshold strains,within which the clay can be considered as elastic,and both of them are larger than that reported before.     

Statistical aspects of Tricomi's function and modified Bessel functions of the second kind

Some of the considerable statistical content of modified Bessel functions of the second kind and of Tricomi's confluent hypergeometric function is illustrated. Moment solutions for the parameters of exponential class distribution functions based on both are derived. Unlike the generalised inverse Gaussian, the Tricomi exponential distribution is little known but it emerges that it is of wide applicability, highly flexible and has the gamma distribution as a special case.     

群桩沉降计算理论分析

基于Geddes应力解,并根据叠加原理计算群桩内任意点处的三向应力,采用基于Duncen-Chang本构模型的修正分层总和法计算群桩内任意点处的沉降量,最后,根据基点法[1]和群桩基础荷载、变形协调关系建立方程,从而,最终获得群桩的沉降计算。该理论较常规弹性理论方法计算群桩沉降有较大地改进,具体体现在以下几个方面：（1）考虑了群桩中地基土的三向应力分布对群桩沉降计算的影响;（2）考虑了土体本构模型（Duncen-Chang弹性非线性本构模型）,因而,能计及土体非线性特性对群桩沉降的影响;（3）采用修正分层总和法理论,能考虑土体成层分布特性以及侧向变形对单桩沉降计算的影响。     

基于有机-无机杂化材料的硝酸还原酶电极的研究

在制备由聚乙烯醇和二氧化硅溶胶凝胶掺杂而成的有机-无机杂化材料的基础上,将硝酸还原酶用此杂化材料包埋固定在金盘电极上,利用甲基紫精为电子媒介体,制得高性能的安培型硝酸还原酶电极。此酶电极可以在-0.68 V（SCE）下对硝酸根进行测定,最适pH值为7.0,载酶量为7.2 mU。在选定的工作条件下,此酶电极的灵敏度和线性范围分别为2.53 nA/(μmol·L^-1)和0.01～0.36 mmol/L ,平均响应时间为12.1 s左右。     

2000年东海黑潮和琉球群岛以东海流的变异Ⅰ.东海黑潮及其附近中尺度涡的变异

基于日本“长风丸”调查船在2000年5个航次水文资料及同时期QuikSCAT风场资料,采用改进逆方法计算了东海黑潮的流速与流量等,获得了这5个航次期间的主要结果:(1)在东海海区风速1~2月比其他月份时大,风海流也最强.只在7月表层风海流为北向,加强了黑潮流速.(2)表层最低盐度值夏季时最小,1~2月时最大.这再次表明,夏季时长江冲淡水向东北方向扩散,冬季时基本上向南,其他季节在上述两者之间.(3)PN断面流速结构及其变化:黑潮流核在1~2,10和11月时有两个,在4和7月皆只有1个.黑潮主流核在1月位于计算点9,在4,7,10与11月都位于计算点8,即向陆架方向移动.(4)黑潮在TK断面出现多流核结构特性.11月主流核出现在TK断面中部,存在于水深大于1 200 m区域,其余月份主流核皆出现在TK断面北部,存在于深度400m以浅水层.(5)通过PN断面的净东北向流量在11月最大,为28.1×106m3/s,7月时其次,10月时最小,为24.6×106m3/s.通过PN断面的净东北向流量年平均值为26.4×106m3/s.(6)1~2,4,7与10月在PN断面以东都出现暖的、反气旋式涡,10月份时,反气旋式涡最强.只在11月时出现弱的、气旋式涡.黑潮以东反气旋涡加强时,黑潮流量似乎减小(例如10月);相反,当黑潮以东反气旋涡减弱(例如7月)或者代之出现气旋涡时(例如11月),黑潮流量似乎增大.10和11月在PN断面附近流态的比较,揭示了环流变化较大,这进一步表明,黑潮和其附近中尺度涡的相互作用是重要的.(7)通过TK断面的净东向流量,11月最大,7月其次,10与1~2月最小.通过TK断面净东向流量年平均值为21.9×106m3/s.(8)通过A断面的北向流量在1~2与4月较大,分别为3.5×106与3.1×106m3/s,7月最小.通过A断面的年平均北向流量约为2.7×106m3/s,这表明,在2000年1~2与4月通过对马暖流的流量最大,7月时最小.