柴达木盆地北缘侏罗系不同沉积环境烃源岩生物标志物特征及其应用

柴达木盆地北缘地区侏罗系(中下侏罗统)的优质烃源岩主要发育于湖相与三角洲相环境。研究了不同时代、不同沉积环境中烃源岩的生物标志物组成特征,结果发现,有3类化合物的分布与组成差异显著,包括三环萜烷(C19、C20、C21)的分布型式、重排藿烷的丰度以及规则甾烷的相对组成。其中,不同时代的差异主要体现在规则甾烷组成上;而不同沉积环境的差异主要体现为三环萜烷(C19、C20、C21)的分布型式及重排藿烷的丰度。分析认为,这些差异与烃源岩的沉积环境及其生源组成有密切关系。据此,初步将这些参数应用于两方面研究,一是为划分地层沉积环境提供“生物标志物相标志”,二是研究油源对比,取得良好效果。因此,本文研究结果具有重要实用价值与参考意义。     

Potential for localized groundwater contamination in a porous pavement parking lot setting in Rhode Island

The control of polluted surface runoff and the assessment of possible impacts on groundwater is a concern at the local and regional scale. On this background, a study investigates possible impacts of organic and inorganic pollutants (including bacteria) originating from a permeable asphalt parking lot on the water quality immediately beneath it. The functioning of the permeable pavement, including clogging and restricted vertical percolation, was also evaluated. Four nested sample ports (shallow and deep) were installed below low- and high-traffic areas, including one port outside the parking lot. At least initially there was a good hydraulic connection between the parking surface and the shallow sample ports. The presence of a geotextile layer at the base of the parking lot structure, however, was identified in lab tests as one factor restricting vertical percolation to the deeper ports. Clogging of the permeable surface was most pronounced in heavy traffic areas and below snow pile storage areas. Corroborated by high electric conductivity and chloride measurements, sand brought in by cars during winter was the principal cause for clogging. No bacteria or BOD were found in percolating water. Polycyclic aromatic hydrocarbons (PAH) were present at concentrations near minimum detection limit. Nutrients (nitrate and phosphate) were being leached into the ground via the permeable parking lot surface at annual flux rates of 0.45–0.84 g/m²/year. A multi-species tracer test demonstrated a retention capacity of the permeable parking lot structure of >90% for metals and 27% for nutrients, respectively.     

Biaxial test simulations using a packing of polygonal particles

The mechanical response of cohesionless granular materials under monotonic loading is studied by performing molecular dynamic simulations. The diversity of shapes of soil grains is modelled by using randomly generated convex polygons as granular particles. Results of the biaxial test obtained for dense and loose media show that samples achieve the same void ratio at large strains independent of their initial density state. This limit state resembles the so‐called critical state of soil mechanics, except for some stress fluctuations, which remain for large deformations. These fluctuations are studied at the micro‐mechanical level, by following the evolution of the co‐ordination number, force chains and the fraction of the sliding contacts of the sample. Copyright © 2007 John Wiley & Sons, Ltd.     

柴达木盆地北缘侏罗系两类不同有机质丰度泥岩的 生物标志物特征对比研究

在柴达木盆地北缘地区,分别选取有机碳含量很低和较高的侏罗系泥岩样品,对比分析了它们在生物标志物组成上的差异。结果发现,高有机质丰度泥岩的生标组成与我国西北地区侏罗纪煤系有机质的特征差异不大,相比而言,低有机质丰度泥岩的正烷烃以前主峰为特征,Pr/Ph比值在1.0左右,三环萜烷和伽马蜡烷丰度较高,并在部分样品中检出了25 降藿烷系列。结合泥岩的有机岩石学特征,认为这些差异可能反映了泥岩沉积环境和生烃母质的不同:高有机质丰度泥岩的有机显微组分以相对弱还原条件下的形态有机质为主,包括藻类体、孢子体和角质体等,而低有机质丰度泥岩的有机显微组分以相对强还原条件下的矿物沥青基质为主,其母质可能来源于低等显微菌藻类。进一步通过对比不同有机质丰度泥岩,以及区内原油生标组成之间的相互关系,讨论了研究区的油源问题。     

近190ka BP以来菲律宾海黑潮源区的碳酸盐旋回及其控制因素

对取自西菲律宾海黑潮源区的Ph05-5和WF3岩芯进行了CaCO3和钙质超微化石研究.在利用氧同位素曲线对比和AMS14C数据进行地层划分的基础上,结合钙质超微化石的碳酸盐溶解指数和初级生产力指标,分析了晚第四纪黑潮源区碳酸盐旋回特征及其控制因素.约190ka BP以来CaCO3含量整体上都表现为冰期高、间冰期低的"太平洋型"旋回特征,但菲律宾以东海区在末次冰期(MIS 4到MIS 2期)内部又显示出间冰段含量高、冰段含量低的"大西洋型"旋回特征.碳酸盐旋回的控制因素在黑潮源区内部也有明显的差异,菲律宾以东海区以碳酸盐溶解作用为主,初级生产力起次要作用;而台湾东南部海区的主要因素则是初级生产力变化引起的钙质生物输入量的波动.菲律宾以东海区末次冰期内部表现出的"大西洋型"旋回特征则是溶解作用和初级生产力共同影响的结果.     

空间刚架结构极限强度分析

本文用理想结构单元法对空间刚架结构进行了极限强度分析，理想结构单元法在于将结构分成最大可能的单元。以简单的形式归并几何非线性与材料非线性。按增量形式加载，直到达到极限强度。本文根据Ｒａｓｈｅｄ理论导出了对称的切向方程组，节省了存贮单元、改善了破坏准则的描述。算例结果与非线性有限单元法结果十分吻合。     

中太平洋铁锰结壳铅同位素研究

已有研究表明大洋中溶解的铅(Pb)来源于陆源物质，但是，对Pb进入大洋的途径争议很大。为此分析了取自中太平洋两块铁锰结壳样品的Pb同位素组成，获得了整个新生代的中太平洋Pb同位素演化历史。结果表明这两块结壳的Pb同位素随时间的演化曲线与中北太平洋沉积物岩心LL44-GPC3中风成碎屑的Pb同位素演化曲线相似。证实该区深水中的天然溶解铅主要来自风成粉尘，并且50Ma之前中太平洋中溶解Pb同位素组成主要取决于源自美洲的风成粉尘的输入，40Ma之后主要取决于源自亚洲的风成粉尘的输入。     

Organic matter origin and distribution in suspended particulate materials and surficial sediments from the western Adriatic Sea (Italy)

In this study, organic carbon (OC), total nitrogen (TN), stable carbon isotopic (δ¹³C_OC) and CuO reaction product compositions were used to identify the sources of organic matter (OM) and to quantify the relative importance of allochthonous and autochthonous contributions to the western Adriatic Sea, Italy. Suspended particulate material (195 samples) and surficial sediments (0–1 cm, 70 samples) from shallow cross-shelf transects were collected in February and May 2003, respectively. Vertical water column profiles were acquired along the same transects. Data include depth, potential temperature, salinity, density and chlorophyll fluorimetry.Along the western Adriatic shelf in the near-shore region, the phytoplankton growth was influenced by dynamics of the buoyant plumes from the Po and Appennine rivers. A small amount of very fine terrigenous material remained suspended within the coastal current and was exported southward along the shelf to the slope. High variability in the bulk composition was detected in the Po prodelta surficial sediments, whereas the western Adriatic shelf, although a larger area, exhibited a narrower range of values.A significant decoupling was observed between suspended particles in the water column and surficial deposits. The organic material collected in the water column was compositionally heterogeneous, with contributions from marine phytoplankton, riverine–estuarine phytoplankton and soil-derived OM. Frequent physical reworking of surficial sediments likely leads to the efficient oxidation of marine OC, resulting in the observed accumulation and preservation of refractory soil-derived OC delivered by the Po and Appennine rivers.     

标志沉积层磁组构特征及其古环境意义研究

通过对长江三角洲及其邻近区域埋藏古土壤、潮坪、长江下游河道浸滩、舟山滨岸风成沙丘、南京黄土古土壤序列沉积体的磁组构测量统计分析，取得了各自的标志特征。该２特征揭示出，舟山滨岸风成沙丘与南京黄土吉土壤序列沉积的搬运介质能量位相基本一致，其物源来向却显示出巨大差异；上述两类沉积体与上述现今潮坪、河道漫滩沉积体地搬运介质能量位相及物源来向均显示出绝然不同的标志特征。然而浸滩物源来民南京黄土的物尖兵为向却     

海水中砷标准物质的研制

本文介绍了海水中砷标准物质的研制过程，其中包括溶液的配制、均匀性和稳定性检验，标样的分析方法。并对标准物质的定值数据进行统计处理，两种浓度的定值结果分别为：１．００μｇ／ｃｍ３±０．０４μｇ／ｃｍ３和５１．０μｇ／ｄｍ３±２．６μｇ／ｄｍ３。两种浓度砷标准物质的稳定期均为一年