Diffusive mass exchange of non‐reactive substances in dual‐porosity porous systems – column experiments under saturated conditions

Diffusive mass exchange into immobile water regions within heterogeneous porous aquifers influences the fate of solutes. The percentage of immobile water is often unidentified in natural aquifers though. Hence, the mathematical prediction of solute transport in such heterogeneous aquifers remains challenging. The objective of this study was to find a simple analytical model approach that allows quantifying properties of mobile and immobile water regions and the portion of immobile water in a porous system. Therefore, the Single Fissure Dispersion Model (SFDM), which takes into account diffusive mass exchange between mobile and immobile water zones, was applied to model transport in well‐defined saturated dual‐porosity column experiments. Direct and indirect model validation was performed by running experiments at different flow velocities and using conservative tracer with different molecular diffusion coefficients. In another column setup, immobile water regions were randomly distributed to test the model applicability and to determine the portion of immobile water. In all setups, the tracer concentration curves showed differences in normalized maximum peak concentration, tailing and mass recovery according to their diffusion coefficients. These findings were more pronounced at lower flow rates (larger flow times) indicating the dependency of diffusive mass exchange into immobile water regions on tracers' molecular diffusion coefficients. The SFDM simulated all data with high model efficiency. Successful model validation supported the physical meaning of fitted model parameters. This study showed that the SFDM, developed for fissured aquifers, is applicable in porous media and can be used to determine porosity and volume of regions with immobile water. Copyright © 2015 John Wiley & Sons, Ltd.     

Upper-Tropospheric Environment–Tropical Cyclone Interactions over the Western North Pacific: A Statistical Study

Based on 25-year(1987–2011) tropical cyclone(TC) best track data, a statistical study was carried out to investigate the basic features of upper-tropospheric TC–environment interactions over the western North Pacific. Interaction was defined as the absolute value of eddy momentum flux convergence(EFC) exceeding 10 m s~(-1)d~(-1). Based on this definition, it was found that 18% of all six-hourly TC samples experienced interaction. Extreme interaction cases showed that EFC can reach~120 m s~(-1)d~(-1) during the extratropical-cyclone(EC) stage, an order of magnitude larger than reported in previous studies.Composite analysis showed that positive interactions are characterized by a double-jet flow pattern, rather than the traditional trough pattern, because it is the jets that bring in large EFC from the upper-level environment to the TC center. The role of the outflow jet is also enhanced by relatively low inertial stability, as compared to the inflow jet. Among several environmental factors, it was found that extremely large EFC is usually accompanied by high inertial stability, low SST and strong vertical wind shear(VWS). Thus, the positive effect of EFC is cancelled by their negative effects. Only those samples during the EC stage, whose intensities were less dependent on VWS and the underlying SST, could survive in extremely large EFC environments, or even re-intensify. For classical TCs(not in the EC stage), it was found that environments with a moderate EFC value generally below ~25 m s~(-1)d~(-1) are more favorable for a TC's intensification than those with extremely large EFC.     

浙江盛夏一次强对流天气的特征及其成因分析

利用常规气象观测资料、区域自动站加密观测资料、GFS 0.5°×0.5°逐6 h分析场数据,以及多普勒雷达、风廓线、微波辐射计探测资料,对2014年7月26日浙江盛夏一次强对流天气过程的特征及其成因进行了诊断分析,结果表明:此次过程发生在副热带高压边缘,由于高空槽东移过程中带来了弱冷空气的渗透,并有大量不稳定能量积聚,形成了午后"上干冷、下暖湿"这样有利于强对流发生的不稳定层结条件和环境背景场。当低层925 hPa的中尺度辐合线和对流层中层700 hPa的垂直上升运动区相重合时,中尺度辐合线附近在未来6 h内产生了强对流,这对强对流的发生发展具有一定的预报指示意义。宁波中尺度辐合线是由偏南风和东北风辐合而成,同时受沿海和喇叭口地形影响,该辐合线早已存在,之后触发了宁波地区的强对流天气。杭州中尺度辐合线是由于宁波雷暴的地面出流增强了偏东风气流,从而加强了偏东风与环境东北风的辐合,导致了杭州中尺度辐合线的形成,随后在辐合线附近出现了剧烈的对流天气。     

Computer-aided design of bus route maps

The bus route map is a diagram that aims to convey necessary information for map readers to find an appropriate way of moving from an origin to a destination. Design of bus route map is a complicated and time-consuming task that requires careful consideration of readability and aesthetics. This paper proposes a new computational method for designing bus route maps. The method helps us to reduce six types of undesirable elements in bus route maps, i.e., gap, shift, crossing, overlap, misalignment, and acute bend. The method consists of two phases: line layout phase determines the relative order of bus routes on each road segment and map layout phase calculates the actual position of bus routes drawn on a map. This paper applies the method to the design of bus route maps of Chiba City, Japan. The result supports the effectiveness of the method as well as reveals open topics for future research.     

西藏“一江三河”地区地下水环境背景值初步研究

在分析对比国内外研究方法的基础上,选择数理统计方法,通过最广泛的数理统计法的应用原则、数据检验、背景值取值等问题的论述,对西藏"一江三河"地区地下水水质指标TDS,Ca²+,Mg²⁺,Na⁺环境背景值进行研究,并初步探讨了它们的空间分布规律及控制因素.结果表明,地形地貌、区域水动力条件等因素对研究区地下水指标的空间分布起主要控制作用.该结果为评价西藏"一江三河"地区地下水污染状况提供科学的依据.     

Electrical analogy for modelling thermal regime and moisture distribution in sandy soils

The soil mass is subjected to temperature variation due to several human activities (viz. tanks storing heated fluids, buried cables and pipelines, air-conditioning ducts, disposal of nuclear and thermal power plant wastes etc.), which result in heat-induced migration of the moisture in it. Though several studies have been conducted in the past to investigate the mechanism of heat migration through the soil mass, a methodology for ‘real-time measurement of the variations in temperature, flux and moving moisture front, in tandem, with respect to space' has rarely been attempted. In this context, extensive laboratory investigations were conducted to measure real-time flux and temperature variations in the sandy soils, and the validation of results has been done by employing an equivalent electrical circuit programme, LTspice. Subsequently, a mathematical model PHITMDS (i.e. Prediction of Heat-Induced Temperature and Moisture Distribution in Soil) has been developed and its utility and efficacy, for predicting the depth-wise temperature and heat-induced moisture migration, due to evaporation, in terms of position of moving moisture front in the sandy soil has been critically discussed and demonstrated.     

Kinetic energy budget and moisture flux convergence analysis during interaction between two cyclonic systems: Case study

An analysis of the kinetic energy budget during a case of interaction between middle latitude and extratropical cyclones has been made in this work. Horizontal flux convergence constitutes a major energy sink. Generation of kinetic energy via cross-contour flow is a persistent source throughout the growth and decay periods. Dissipation of kinetic energy from subgrid to grid scales is an important source during the pre-storm period; it acts as a sink during the growth and decay periods. The major contribution to kinetic energy comes from a persistent upper tropospheric jet stream activity throughout the period of the cyclone development. The characteristics of moisture-flux components (divergent and rotational) along with precipitable water content for different tropospheric layers throughout the life cycle of our cyclone are also studied in this work. It is found that most of required humidity for our cyclone are initiated from Arabian Sea and then to some extent are reinforced over Gulf of Aden and east of central Africa and then by passing over Red sea enter to the south and south east of Mediterranean Sea. The rotational component of the moisture transport brings moisture from two regions; the first which is considered the main region is the Indian Ocean, Arabian Sea, Gulf of Aden and north east of Sudan. The second source region is the Atlantic and Mediterranean Sea. In the middle troposphere, the primary moisture source is found over central Africa, which in turn is traced to the Atlantic Ocean, the Indian Ocean, and the Arabian Sea. The upper-level moisture fluxes are weak and play a minor role over the area of interaction between two cyclones.     

水库现代沉积过程沉积磷的早期成岩作用模型研究

在沉积磷形态分析、孔隙水化学、核素计年以及吸附解吸实验等的基础上,运用一维“反应-平流-扩散”模型,研究了红枫湖现代沉积过程中磷的沉积改造。结果表明:红枫湖现代沉积过程中,有机态磷的矿化分解和铁结合态磷的络合/溶解,是控制沉积物磷迁移转化动力学的主要机制。沉积物-水界面附近有机磷的快速降解,可能克服沉积界面上铁氧化物对溶解磷的吸附缓冲,而形成向水体的磷酸盐迁移通量;自生磷灰石的沉积改造相对不明显,沉积磷向稳定形态含磷矿物(钙氟磷灰石)的转化过程同样不能影响红枫湖现代沉积过程中磷转化的质量平衡。     

谈地下水数学模型在南干渠灌区中的预测与应用

地下水数学模型是用数学方法表述,经过概化地下水系统,在系统分析地下水补、径、排的基础上,对地下水预测分析的一种有效方法.随着南干渠灌区建成后水量的变化,本文通过选用适宜的数学模型,对灌区地下水资源量进行模拟计算,根据模拟计算结果对灌区地下水升幅进行预测,对灌区生态环境的变化做出评价.     

运用模糊数学法评价项城地下水水质

以频率统计法选择Hg、COD等评价因子,从隶属度、权重的计算以及模糊模型的选择等方面,详细介绍模糊数学法运用于项城市浅层地下水水质现状评价的过程,并结合综合指数评价结果对其进行简析.