矿床保存变化研究的热年代学技术方法

成矿后矿床的保存与变化是矿床地质研究的重要组成部分,但研究程度不高,至今仍属于薄弱环节。矿床的保存与其隆升剥露密切相关,深入细致研究恢复矿区矿床的隆升和剥露历史,是揭示矿床保存变化的一种重要途径。本文重点论述研究矿床保存变化的技术方法,通过综合应用裂变径迹、(U-Th)/He、~(40)Ar-~(39)Ar年代学以及La-ICP-MS、锆石U-Pb定年等多种技术手段,研究成矿期次、构造活动期次以及二者间的联系,定量计算不同矿区、不同矿体、不同部位、不同时间的冷却隆升速率、隆升幅度、剥蚀速率和剥蚀量,探讨矿床保存深度与剥蚀量间的关系,总结不同时代、不同矿区矿床保存-变化过程,建立新的矿床地质-保存环境模型,完善矿床预测的综合示踪标志,最终预测不同矿区、不同地段隐伏矿床可能的产出深度,给出矿床可能已经被剥蚀殆尽的区段或地段,为深部找矿和区域成矿潜力评价提供依据。本文可为地质工作者的相关应用提供借鉴和手段。     

北京飞云瀑景点崩塌地质灾害分析及防治方法研究

近15年来,北京飞云瀑景点附近发生过2次大规模崩塌,崩塌堆积岩块体积累计达450 m3,崩塌岩块已滚落覆盖至景区小路。经勘查,确定了1处危岩体及1处危岩带,该危岩体及危岩带对本景点的正常观赏及过往游人构成极大威胁。本文对该景点的崩塌地质灾害地质特征进行了简要介绍;对地质灾害成因、自然发展趋势等进行了初步探讨;对危岩体(带)的稳定性进行了计算、分析及评价;对可能采用的治理方法进行了比选分析。为了最大程度地保护景观资源,最终选择了以避让为主的治理措施,并对选定的治理方案及计算进行了阐述。     

基于FLUENT的内孤立波质量源造波方法

为研究内孤立波质量源数值造波方法,本文采用两个点源形式的质量源,分别放置于两层流体的上下层中作为内孤立波激发源。推导源项表达式,从不可压缩流体的Navier-Stokes方程出发,结合内孤立波Kd V、e Kd V理论,基于商业软件FLUENT发展了一种内孤立波质量源数值造波方法。通过数值模拟,分析了质量源造波过程中内孤立波的生成过程,并将数值模拟结果同理论及实验作对比。结果表明:基于此方法生成的内孤立波波形、波高及波致水平速度与理论及实验吻合度较好,该方法是可行的,并且耗时短、效率高。     

The effects of yawing motion with different frequencies on the hydrodynamic performance of floating vertical-axis tidal current turbines

Under real sea conditions, the hydrodynamic performance of floating vertical-axis tidal current turbines is affected by waves and currents. The wave circular frequency is a significant factor in determining the frequencies of the wave-induced motion responses of turbines. In this study, the ANSYS-CFX software (manufacturer: ANSYS Inc., Pittsburgh, Pennsylvania, United States) is used to analyse the hydrodynamic performance of a vertical-axis turbine for different yawing frequencies and to study how the yawing frequencies affect the main hydrodynamic coefficients of the turbine, including the power coefficient, thrust coefficient, lateral force coefficient, and yawing moment coefficient. The time-varying curves obtained from the CFX software are fitted using the least-squares method; the damping and added mass coefficients are then calculated to analyse the influence of different yawing frequencies. The simulation results demonstrate that when analysing non-yawing turbines rotating under constant inflow, the main hydrodynamic coefficient time-varying curves of yawing turbines exhibit an additional fluctuation. Furthermore, the amplitude is positively correlated with the yawing frequency, and the oscillation amplitudes also increase with increasing yawing frequency; however, the average values of the hydrodynamic coefficients (except the power coefficient) are only weakly influenced by yawing motion. The power coefficient under yawing motion is lower than that under non-yawing motion, which means that yawing motion will cause the annual energy production of a turbine to decrease. The fitting results show that the damping term and the added mass term exert effects of the same level on the loads and moments of vertical-axis turbines under yawing motion. The results of this study can facilitate the study of the motion response of floating vertical-axis tidal current turbine systems in waves.     

2001年秋季风对坦帕湾盐度平衡的影响

利用三维高分辨率有限体积的近海海域模型FVCOM来分析2001年秋季期间风作用对坦帕湾区域盐度平衡的影响。为了区分风的影响,分别设计了两个实验：一个由潮汐和河流作为驱动,另一个由潮汐、河流以及风场共同驱动。结论如下：首先,风作用会使盐度产生变化,能够明显地使坦帕湾内的盐度增加,并导致水平和垂直方向上盐度梯度的减少;随后,本文分析了坦帕湾区域内的盐度平衡,主要的盐度平衡来自于全部（水平和垂直方向上）平流的盐度流量分歧以及除去海峡底部的垂直方向上盐度流量分歧;最后,对由风引起的盐度变化进一步进行分析,结果表明风作用不能改变盐度平衡地位的相对重要性,由风引起的盐度平衡改变高度依靠于特殊的地形,除此之外,全部平流盐度流量分歧和垂直散布盐度通量分歧能够抵消,并且两者都远大于水平散步盐度流量分歧。     

高效液相色谱-离子阱质谱法测定海洋微藻藻粉中的8种脂溶性毒素

建立了利用高效液相色谱-电喷雾离子阱质谱(HPLC-ESI-IT-MS)测定海洋微藻藻粉中8种典型脂溶性毒素的分析方法。藻粉样品经超声细胞破碎后,采用超声波辅助提取法对藻毒素进行提取,用HPLC-ESI-IT-MS多反应离子监测(MRM)模式对各种毒素(包括大田软海绵酸(OA)、鳍藻毒素1(DTX-1)、扇贝毒素2(PTX-2)、虾夷扇贝毒素(YTX)、原多甲藻酸1(AZA1)原多甲藻酸2(AZA2)、罗环内酯毒素(SPX),米氏裸甲藻毒素(GYM))进行测定。8种脂溶性藻毒素均在线性范围内线性关系良好(R2均在0.991以上),检出限均介于0.085～1.315 pg之间,加标回收率在88.5%～111.4%之间,方法重复性相对标准偏差(RSD)在4.82%～10.17%范围。应用该方法对利玛原甲藻干藻粉中的毒素进行了测定,分析结果良好,说明本方法是海洋微藻藻粉中脂溶性藻毒素测定的有效方法。     

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry

Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO₃ results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF₃ precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH₄HF₂ open vessel digestion and (c) NH₄F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF₃ and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH₄HF₂ or NH₄F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO₃, the white precipitates and the semi‐transparent gels present in the NH₄HF₂ and NH₄F digestion methods could be efficiently dissolved by evaporation with HClO₄. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time.     

Hybrid N-order Lagrangian Interpolation Eulerian?Lagrangian Method for Salinity Calculation

The Eulerian?Lagrangian method (ELM) has been used by many ocean models as the solution of the advection equation, but the numerical error caused by interpolation imposes restriction on its accuracy. In the present study, hybrid N-order Lagrangian interpolation ELM (LiELM) is put forward in which the N-order Lagrangian interpolation is used at first, then the lower order Lagrangian interpolation is applied in the points where the interpolation results are abnormally higher or lower. The calculation results of a step-shaped salinity advection model are analyzed, which show that higher order (N=3?8) LiELM can reduce the mean numerical error of salinity calculation, but the numerical oscillation error is still significant. Even number order LiELM makes larger numerical oscillation error than its adjacent odd number order LiELM. Hybrid N-order LiELM can remove numerical oscillation, and it significantly reduces the mean numerical error when N is even and the current is in fixed direction, while it makes less effect on mean numerical error when N is odd or the current direction changes periodically. Hybrid odd number order LiELM makes less mean numerical error than its adjacent even number order LiELM when the current is in the fixed direction, while the mean numerical error decreases as N increases when the current direction changes periodically, so odd number of N may be better for application. Among various types of Hybrid N-order LiELM, the scheme reducing N-order directly to 1st-order may be the optimal for synthetic selection of accuracy and computational efficiency.     

重力方法在祁连山地区构造特征与岩体解释中的应用

依据地质、航磁等资料,结合实测岩石物性资料,以1∶250 000重力资料为基础对祁连山地区(张掖、刚察地区)进行综合研究。研究地质构造与地球物理特征,划分了大地构造单元,探讨了隐伏与半隐伏岩体分布。该区域经多年的重力工作,勘探面积已近3万多km²,根据重力资料研究布格重力场特征并进行分区; 对地质构造单元重新划分,对主要断裂进行探讨; 圈定隐伏与半隐伏岩体,推断其空间展布特征,并对其解释。结果表明: 祁连山地区地壳密度结构横向分区、纵向分层明显,布格重力异常场的分区特征与地质构造分区特征基本一致。结合2.5D重力剖面反演印证了新的推测结果,为综合地质、地球物理找矿提供参考。