Seasonal variations of atmospheric sulfur dioxide and dimethylsulfide concentrations at Amsterdam Island in the southern Indian Ocean

Daily measurements of atmospheric sulfur dioxide (SO₂) concentrations were performed from March 1989 to January 1991 at Amsterdam Island (37°50 S–77°30 E), a remote site located in the southern Indian Ocean. Long-range transport of continental air masses was studied using Radon (²²²Rn) as continental tracer. Average monthly SO₂ concentrations range from less than 0.2 to 3.9 nmol m^-3 (annual average = 0.7 nmol m^-3) and present a seasonal cycle with a minimum in winter and a maximum in summer, similar to that described for atmospheric DMS concentrations measured during the same period. Clear diel correlation between atmospheric DMS and SO₂ concentrations is also observed during summer. A photochemical box model using measured atmospheric DMS concentrations as input data reproduces the seasonal variations in the measured atmospheric SO₂ concentrations within ±30%. Comparing between computed and measured SO₂ concentrations allowed us to estimate a yield of SO₂ from DMS oxidation of about 70%.     

Measurements of peroxyacetylnitrate in the marine boundary layer over the Atlantic

The atmospheric concentration of peroxyacetylnitrate (PAN) was measured during a cruise of the R.S. Polarstern from Bremerhaven (Germany) to Rio Grande do Sul (Brazil) in September/ October 1988. The measurements were made in-situ by a combination of electron capture gaschromatography with a cryogenic preconcentration step. The theoretical lower limit of detection (3) was 0.4 ppt. The mixing ratios of PAN varied by more than three orders of magnitude from 2000 ppt in the English Channel to less than 0.4 ppt south of the Azores (38° N). South of 35° N, PAN levels were below the detection limit, except at 30–31° S off the eastern coast of South America. Here, PAN mixing ratios of 10 to 100 ppt were detected in continentally influenced air masses. Detectable levels of PAN were mostly observed in air masses of continental or high northern origin. Changes in the wind directions were usually associated with substantial changes in the PAN mixing ratios.     

Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.     

Seasonal variation of atmospheric dimethylsulfide at Amsterdam Island in the southern Indian Ocean

Daily measurements of atmospheric concentrations of dimethylsulfide (DMS) were carried out for two years in a marine site at remote area: the Amsterdam Island (37°50S–77°31E) located in the southern Indian Ocean. DMS concentrations were also measured in seawater. A seasonal variation is observed for both DMS in the atmosphere and in the sea-surface. The monthly averages of DMS concentrations in the surface coastal seawater and in the atmosphere ranged, respectively, from 0.3 to 2.0 nmol l^-1 and from 1.4 to 11.3 nmol m^-3 (34 to 274 pptv), with the highest values in summer. The monthly variation of sea-to-air flux of DMS from the southern Indian Ocean ranges from 0.7 to 4.4 mol m^-2 d^-1. A factor of 2.3 is observed between summer and winter with mean DMS fluxes of 3.0 and 1.3 mol m^-2 d^-1, respectively.     

Stratigraphy and optically stimulated luminescence (OSL) dating of a Quaternary sequence along the Dong Nai River, southern Vietnam

The pre-Holocene Cenozoic sequence outcrops in the terrestrial part of the eastern margin of the Mekong Basin. However, the stratigraphy of the sequence is still unclear. Its detailed stratigraphy and chronology were therefore studied along the Dong Nai River, southern Vietnam, and the lithofacies and the relations among the formations were investigated from the outcrops. The ages of the deposits were determined by using optically stimulated luminescence (OSL) dating.The Ba Mieu Formation was deposited about 176±52 ka during marine isotope stage (MIS) 7–6. The Thu Duc Formation was deposited about 97±27 ka during MIS 5. Both the Ba Mieu and Thu Duc formations are composed of fluvial and tidally influenced coastal deposits. The newly proposed Nhon Trach Formation was originally an eolian (blanket) deposit, but it has been partly reworked by fluvial processes. The Nhon Trach Formation was deposited about 10.9±4.7 ka, in the last part of the Pleistocene to the beginning of the Holocene. The OSL ages for the Ba Mieu, Thu Duc, and Nhon Trach formations are younger than the ages previously assigned to these formations.     

Ophiomorpha irregulaire, rare trace fossil in shallow marine sandstones, Cretaceous Atane Formation, West Greenland

Ophiomorpha irregulaire is a large and extremely rare trace fossil. The type section is in the Book Cliffs, Utah, USA. A second on-shore locality is reported here, in the Nuussuaq Basin of West Greenland. Both occurrences date from the Late Cretaceous. Other reports of O. irregulaire are restricted to two-dimensional sections in well cores and are mostly Jurassic in age. The West Greenland occurrence is in the Atane Formation in shallow marine clean sandstone. The two on-shore localities lie in the same biogeographical region, in connection with the Cretaceous Western Interior Seaway of North America. O. irregulaire is characterized by a sinuous, branched meander maze lying mostly within a single horizontal plane, probably not far beneath the seafloor. The burrow lining has remarkably elongate pellets that probably were emplaced by the burrower. In some cases, diagenetic compression may have deformed the lining pellets to produce their elongated shape. The muddy sediment comprising the lining is almost unrepresented in the clean sands of the substrate, and it was probably trapped from suspension during suspension-feeding activity.     

The sequence of sediment behaviour during wave-induced liquefaction

This paper presents the results of an experimental investigation of the complete sequence of sediment behaviour beneath progressive waves. The sediment was silty with d ₅₀ = 0.060 mm. Two kinds of measurements were carried out: pore-water pressure measurements (across the sediment depth), and water-surface elevation measurements. The process of liquefaction/compaction was videotaped from the side simultaneously with the pressure and water-surface elevation measurements. The video records were then analysed to measure: (i) the time development of the mudline, (ii) the time development of liquefaction and compaction fronts in the sediment and (iii) the characteristics of the orbital motion of the liquefied sediment including the motion of the interface between the water body and the sediment. The ranges of the various quantities in the tests were: wave height, H  = 9–17 cm, wave period, T  = 1.6 sec, water depth = 42 cm, and the Shields parameter = 0.34–0.59. The experiments reveal that, with the introduction of waves, excess pore pressure builds up, which is followed by liquefaction during which internal waves are experienced at the interface of the water body and the liquefied sediment, the sequence of processes known from a previous investigation. This sequence of processes is followed by dissipation of the accumulated excess pore pressure and compaction of the sediment which is followed by the formation of bed ripples. The present results regarding the dissipation and compaction appear to be in agreement with recent centrifuge wave-tank experiments. As for the final stage of the sequence of processes (formation of ripples), the ripple steepness (normalized with the angle of repose) for sediment with liquefaction history is found to be the same as that in sediment with no liquefaction history.     

Characterization of microbial communities associated with African desert dust and their implications for human and ecosystem health

Desert winds aerosolize several billion tons of soil-derived dust each year, including concentrated seasonal pulses from Africa and Asia. Huge dust events create an atmospheric bridge over continents and oceans, and eject a large pulse of soil-associated microorganisms into the atmosphere. These dust events might therefore have a role in expanding the biogeographical range of some microorganisms by facilitating rare long-distance dispersal events. The goal of this study is to characterize the microbes associated with African dust events and determine if they pose a risk to humans or downwind ecosystems. Air samples were collected by vacuum filtration in a source region （Mali, West Africa） during dust events and plated on R2A media to culture microorganisms. These organisms were compared to those in similar samples collected in the Caribbean during Saharan/Sahelian dust events. A high-volume liquid impinger is currently being tested in Barbados, collecting aerosol samples during African dust events. Over 100 bacteria and fungi （19 genera of bacteria and three genera of fungi） have been characterized from source region dust events.     

与全球变化有关的几个北极海洋地质问题

极地区域是全球变化研究的重点区域 ,在北极地区与全球变化有关的地质问题主要是北极地区的海陆变化对全球变化的影响 ,以及全球变化在地层中的记录。这涉及到北极形态变化及与其它大洋沟通的水道开闭情况 ,地形起伏对大气、大洋环流的影响 ,地壳升降与海平面变化对河流流量和海岸稳定性的影响 ,气体水合物及有机碳等变化对全球碳循环的影响 ,以及这些影响与气候变化信息在极地沉积物中的记录。文章在对上述影响及海洋地质研究状况进行探讨后 ,又简要介绍了中国的首次北极考察海洋地质研究状况     

四阶△－∑过抽样电路原理及其在微弱地学信号检测中的应用

传统的测量电路无法解决诸如海底大地电磁场这样微弱地学信号的检测问题。近几年诞生了一种称之为△-∑的电路理论以及相应的硬件芯片，给微伏级的弱信号检测开辟一条新的技术路径。文章介绍与地学探测有关的一种△-∑电路类型，该类型以低频段微弱信号为检测对象。采用系统理论和电路分析方法对△-∑原理作了较深入的讨论，阐明这种电路技术对提高微弱信号观测的分辨率是有效的。结合海底大地电磁探测中的信号采集问题，介绍了在仪器中把多路的被测模拟量变为数字量的技术过程。经对实际采集的海底信息的频谱曲线进行分析，证实所采用的△-∑技术以及多路信号采集的电路方案是合理的。