Iron speciation and biogeochemistry in different nearshore waters

Different environmental conditions in various nearshore waters dynamically determine the speciation of iron, its solubility, removal and hence bioavailability to phytoplankton. The iron speciation, the impact of phytoplankton blooms and the effects of organic matter on iron speciation and transformation were studied in four different coastal systems: the Trondheim Fjord, Norway, which is a coastal system that is open to a vast riverine impact; Hopevågen, Norway, a pristine coastal basin, which has negligible river and anthropogenic impact; zmir Bay, Turkey, a Mediterranean embayment with heavily polluted eutrophic inner–middle section, and the oligotrophic outer section. In this paper, we compare iron speciation in these different coastal systems. While colloidal iron (ColFe) was the predominant species especially in the Trondheim Fjord and to some degree also in Hopavågen, Chelex labile iron (ClxLFe) and hydrophobic organic-iron complex (HpOFe) were predominate species in both the inner–middle and the outer section of zmir Bay. The impact of phytoplankton blooms on the ClxLFe was significant especially in the Trondheim Fjord, in the inner–middle section of zmir Bay and in Hopevågen.     

连云港南部近岸带冲淤变化分析

选取连云港南部近岸带南北不同岸滩 4个典型断面的样品点进行主成分分析 ,得出研究区控制泥沙交换和冲淤变化的主要动力因素为潮流作用和潮流波浪混合作用。据此 ,尝试建立冲淤变化的协方差数学模型 ,经过对计算结果显著性分析和实证检验得出研究区域的冲淤趋势为“整体冲淤平衡 ,局部略有冲刷” ,从北到南 ,依次出现淤积平衡、冲淤平衡、冲刷平衡三种较为稳定的自然冲淤环境。     

Mercury methylation,demethylation and reduction rates in coastal and marine surface waters of the Mediterranean Sea

In situ experiments using isotopically labeled mercury species (¹⁹⁹Hg(II) and Me²⁰¹Hg) are used to investigate mercury transformation mechanisms, such as methylation, demethylation and reduction, in coastal and marine surface waters of the Mediterranean Sea. The aim of this work is to assess the relative contribution of photochemical versus biological processes to Hg transformation mechanisms. For this purpose, potential transformation rates measured under diurnal and dark incubation conditions are compared with major biogeochemical parameters (i.e. hydrological and biological data) in order to obtain the relative contribution of various biotic and abiotic mechanisms in both surface (high light) and bottom (low light) waters of the euphotic zone. The results demonstrate that coastal and marine euphotic zones are significant reactors for all Hg transformations investigated (i.e. methylation, demethylation, reduction). A major outcome demonstrates that Hg methylation is taking place in oxic surface seawater (0.3–6.3% day^− 1) and is mainly influenced by pelagic microorganism abundance and activities (phyto- and bacterioplankton). This evidences a new potential MeHg source in the marine water column, especially in oligotrophic deep-sea basins in which biogeochemistry is mostly governed by heterotrophic activity. For coastal and marine surface waters, although MeHg is mainly photochemically degraded (6.4–24.5% day^− 1), demethylation yields observed under dark condition may be attributed to microbial or chemical pathways (2.8–10.9% day^− 1). Photoreduction and photochemical reactions are the major mechanisms involved in DGM production for surface waters (3.2–16.9% day^− 1) but bacterial or phytoplanktonic reduction of Hg(II) cannot be excluded deeper in the euphotic zone (2.2–12.3% day^− 1). At the bottom of the euphotic zone, photochemical processes are thus avoided due to the attenuation of UV-visible sunlight radiation allowing biotic processes to be the most significant. These results suggest a new potential route for Hg species cycling in surface seawater and especially at the maximum biomass depth located at the bottom of the euphotic zone (i.e. maximum chlorophyll fluorescence). In this environment, DGM production and demethylation mechanisms are thus probably reduced whereas Hg methylation is enhanced by autotrophic and heterotrophic processes. Experimental results on mercury species uptake during these investigations further evidenced the strong affinity of MeHg for biogenic particles (i.e. microorganisms) that correspond to the first trophic level of the pelagic food web.     

Sources of environmental sulfur in the groundwater system,southern New Zealand

Sulfide minerals commonly occur in sediments and basement rocks in southern New Zealand, as authigenic precipitates from groundwater below the oxygenated surface zone. There are two principal potential sources for sulfur in the groundwater system: weathering of sulfide minerals in the metamorphic basement and rainwater-derived marine aerosols. We present data for these two key sulfur sources: metamorphic sulfide and associated hydrothermal Au-bearing veins within the Otago Schist (average δ³⁴S = −1.8 ± 2.4‰), and an inland saline lake (S derived entirely from rainwater, δ³⁴S = 21.4 ± 0.8‰). We use these two end member δ³⁴S values to estimate the contributions of these sources of sulfur in authigenic groundwater sulfide minerals and in waters derived from oxidation of these sulfide minerals, across a range of environments. We show that authigenic groundwater pyrite along joints in the Otago schist is derived primarily from metamorphic basement sulfur. In contrast, authigenic groundwater pyrite cementing Miocene-Recent aquifers shows a substantial marine aerosol component, and represents a distinct hydrogeological system. We suggest that marine aerosols represent a significant flux to the terrestrial sulfur cycle that has been present through the groundwater system in Otago over the past 20 million years.     

Diurnal and vertical variability of pH, [O2], and Eh in the Novosibirsk water reservoir

In situ data on the daily dynamics of pH, [O₂], and E_h values at five water layer depths were obtained. Some regularities have been established: All these parameters are characterized by significant diurnal fluctuations and their daily cyclic recurrence; the diurnal cycles of pH and [O₂] nearly coincide (they show close extreme points on the time scale); the E_h cycles are less distinct and antisymbatic to the pH and [O₂] cycles, but typical E_h extremes sometimes lag by 2–3 h. These data were analyzed using the principle of equilibrium locality and partiality. The main flows of O₂ and CO₂ in the system have been revealed with regard to the water layer–atmosphere gas exchange, absorption of CO₂ by phytoplankton in the photic layer, breathing of phyto- and zooplankton, birth and die-off of biota, settling of mortomass, and redistribution of detailed components within the water layer as well as between it and the bottom sediments. On the basis of the results obtained, the known technique for estimating the content of primary photosynthesis products (Bruevich's method) was corrected. The used generalized algorithm of chemical thermodynamic analysis of the substance state in aqueous systems can be applied to waters of different classes as well as any surficial waters if E_h, pH, and [O₂] are taken into account.     

The Equation of State for Caspian Sea Waters

The density ρ of Caspian Sea waters was measured as a function of temperature (273.15–343.15) K at conductivity salinities of 7.8 and 11.3 using the Anton-Paar Densitometer. Measurements were also made on one of the samples (S = 11.38) diluted with water as a function of temperature (T = 273.15–338.15 K) and salinity (2.5–11.3). These latter results have been used to develop an equation of state for the Caspian Sea (σ = ±0.007 kg m⁻³)

Geochemistry of the thermal waters of Sikhote Alin

This paper reports new geochemical data on the low temperature nitric thermal waters of Sikhote Alin. The studied alkaline waters belong to the HCO₃-Na type with significant trace element variations. The waters demonstrate an increase in temperature and TDS from the south northward of Sikhote Alin. The oxygen and hydrogen isotopic data suggest their infiltration origin. The chemical composition of these waters was formed by water-rock interaction.     

厦门近岸海域大型底栖动物摄食功能群及其与环境因子的关系

根据2013年5月和11月在厦门周边海域60个取样站获得的大型底栖动物数据,运用功能群方法分析该海域大型底栖动物功能群的时空格局及其与环境因子的关系。共鉴定大型底栖动物9门160科411种,其中肉食者152种,浮游生物食者102种,碎屑食者103种,杂食者48种和植食者6种,菲律宾蛤仔（Ruditapes philippinarum）和丝鳃稚齿虫（Prionospio malmgreni）分别是该海域春、秋季的主要优势种。总体而言,浮游生物食者和肉食者为该海域的主要优势功能群,但各区域的优势功能群存在一定差异,围头湾的主导功能群为肉食者和碎屑食者,大嶝海域以肉食者和浮游生物食者为主,而九龙江口和同安湾则以碎屑食者和浮游生物食者占优势。典范对应分析结果表明,水深和底温是影响该海域大型底栖动物功能群时空格局的主要因素,活性磷酸盐、底盐、有机质和叶绿素a等对其分布也有一定的影响。     

An ecological classification of rocky shores at a regional scale: a predictive tool for management of conservation values

The ecological classification of coastal waters has become an important issue in ecosystem water quality assessment. Previous studies have suggested that abiotic variables seem to be a suitable alternative to biological data for classifying coastal areas at different scales. The study presented here proposes a downscaling methodology for the classification of coastal waters at a regional scale within the NE Atlantic based on standardized data and objective decision rules. Physical variables (temperature, wave exposure, tidal range and radiation) were selected because of their ecological role, availability and statistical decision rules. This information was based on satellite data and mathematical modelling of natural coastal processes. The N and NW Spanish coastline was subdivided into 41 20‐km segments that were classified according to physical variables using the self‐organizing map and k‐means algorithms. To validate the classification with biological data, 21 sites representing the entire range of physical typologies in the study area were simultaneously and consistently sampled. Intertidal macroalgae were identified in each of 10 quadrats of 50 × 50 cm for two to three transects per site, according to a stratified sampling procedure. The coverage of macroalgae was obtained by photographic analysis. The physical classification shows four typologies: Lower Rias, Upper Rias, West Cantabric and East Cantabric. Statistical analyses confirmed the ecological significance of these typologies at the tidal levels where seaweeds were the major structural element (lower and middle intertidal). According to the biological data, the greatest differences were found between the Upper Rias and the rest of the N and NW Iberian Peninsula coast. Thus, the classification methodology has potential application as a management tool.     

A new model of angular momentum transfer from the rotating central body of a two‐body system to the orbital motion of the system

In a previous paper we treated within the framework of our Projective Unified Field Theory (Schmutzer 2004, 2005a) the 2‐body system (e.g. Earth‐Moon system) with a rotating central body in a rather abstract manner. Here a concrete model of the transfer of angular momentum from the rotating central body to the orbital motion of the whole 2‐body system is presented, where particularly the transfer is caused by the inhomogeneous gravitational force of the Moon acting on the oceanic waters of the Earth, being modeled by a spherical shell around the solid Earth. The theory is numerically tested. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)