聚四氟乙烯平板型气态膜回收淡盐水中氯气

本文以离子膜电解氯化钾制取碳酸钾工艺产生的淡盐水为原料,系统地研究了聚四氟乙烯平板型气态膜回收氯过程中膜性能和次氯酸钠水溶液的制备。初步研究表明,次氯酸钠含量大于100g/L,氢氧化钠有效利用率为90％;聚四氟乙烯膜有传质快、对离子截留性能好、使用寿命长等优点,在工业上有较好的应用前景。     

Wavepath traveltime tomography

The elastic-wave equation is used to construct sensitivity kernels relating perturbations in elastic parameters to traveltime deviations. Computation of the functions requires a correlation of the forward-propagating seismic wavefield with a backward propagation of the residual wavefield. The computation of the wavefields is accomplished using a finite difference algorithm and is efficiently executed on a CM-2 parallel processor. The source and receiver locations have maximum sensitivity to velocity structure. The sensitivity kernels or wavepaths are well suited for transmission traveltime inversion such as cross-borehole tomography and vertical seismic profiling. Conventional ray tomography and wavepath tomography are applied to a set of P -wave arrival times, from a cross-borehole experiment at Kesterson, California. Because the wavepaths have increased sensitivity near the source and receiver there are differences in resolution of the velocity structure. Both techniques recover the same relative variations in velocity where the coverage is adequate. The wavepath solution is more laterally continuous and the dominant variation is vertical, as is expected for the layered sediments in this region.     

Observations of geomagnetic pulsations and variations with a new borehole magnetometer down to depths of 3000 m

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A triaxial magnetometer has been developed for investigating the in situ skin effect of horizontal geomagnetic pulsations and variations in deep boreholes. The observations were carried out in the pilot borehole of the Continental Deep Drilling Program of Germany (KTB) down to depths of 3000 m and up to temperature of 90 C. A weak skin effect, due to the known very low conductivity of the penetrated crystalline rocks, of 90 to 95 per cent in amplitude and -5 to -10 rotation in phase has been observed at periods of 10 s and magnetometer depth of 2400 m.
An essential prerequisite for all calculations is the accurate determination of the orientation of the downhole magnetometer. It is demonstrated how oriented record samples of temporal variations at depth correlate precisely with those from the surface.
Results from surface magnetotelluric (MT) investigations show strong local distortions of the telluric field. The distortion of the MT tensor response has been determined by means of newly introduced skin-effect transfer functions, which are assumed to be undistorted.     

Late Quaternary kinematics of the Pallatanga strike-slip fault (Central Ecuador) from topographic measurements of displaced morphological features

The northeast-trending Pallatanga right-lateral strike-slip fault runs across the Western Cordillera connecting N50E-N70E trending normal faults in the Gulf of Guayaquil with N-S reverse faults in the Interandean Depression. Over most of its length, the fault trace has been partly obscured by erosional processes and can be inferred in the topography only at the large scale. Only the northern fault segment, which follows the upper Rio Pangor valley at elevations above 3600 m, is prominent in the morphology. Valleys and ridges cut and offset by the fault provide an outstanding record of right-lateral cumulative fault displacement. The fault geometry and kinematics of this particular fault segment can be determined from detailed topographic levellings. The fault strikes N30E and dips 75 to the NW. Depending on their size and nature, transverse morphological features such as tributaries of the Rio Pangor and intervening ridges, reveal right-lateral offsets which cluster around 27 ± 11m, 41.5 ± 4 m, 590 ± 65 m and 960 ± 70 m. The slip vector deduced from the short-term offsets shows a slight reverse component with a pitch of about 11.5 SW. The 41.5 ± 4 m displacements are assumed to be coeval with the last glacial termination, yielding a mean Holocene slip-rate of 2.9- 4.6 mm yr⁻¹. Assuming a uniform slip rate on the fault in the long term, the 27 m offset appears to correlate with an identified middle Holocene morphoclimatic event, and the long term offsets of 590 m and 960 m coincide with the glacial terminations at the beginning of the last two interglacial periods.     

Reciprocity theorem to compute the static deformation due to a point dislocation buried in a spherically symmetric earth

Intriguing reciprocity relations exist between the static deformation excited by a point dislocation in a SNREI earth and those generated by external forces, such as tidal force, surface loading and surface shear forces. Coseismic deformations can be rewritten as follows: (1) potential change in terms of the tide deformation field, (2) radial displacement in terms of the load and tidal deformation fields, and (3) tangential displacement in terms of shear and torsional deformation fields. The relations greatly reduce the effort to compute the coseismic crustal deformation in a spherically symmetric earth.     

Inference of core-mantle boundary topography from ISC PcP and PKP traveltimes

We invert ISC PcP and PKP absolute and differential traveltimes in an attempt to infer the long-wavelength topography of the core-mantle boundary (CMB). The data selection and processing methods are described and evaluated. These travel-time data are very noisy and the geographic distribution of the data is highly non-uniform, inhibiting reliable inference of CMB topography. Spatial averaging enhances the coherent component of the residual variance (related to heterogeneity), however, the random component of the variance is much larger than the coherent component. We show that for PcP data the coherent signal due to mantle heterogeneity overshadows that arising from the CMB, and that the effects of mantle heterogeneity are mapped into our inferred CMB solutions. The PcP data are not correlated across the spatial averaging bins and seem to have a strong bias due to small-scale structure and/or noise. The non-uniform geographic sampling of the data plays a role in the mapping of mantle heterogeneity onto the CMB. Spatial patterns of CMB models inferred from different phases do not agree. Amplitudes of seismically inferred CMB undulations vary greatly. The sensitivity of inferred CMB models to the processing, spatial averaging procedure, and inversion techniques are investigated. Topographic amplitudes increase strongly with increasing input residual variance. The power spectrum of inferred topography indicates that there are unmodelled heterogeneities that must be described with spherical harmonics of degree 6 and higher. Based on this work, we conclude that reliable inference of long-wavelength CMB topography is not likely with the current ISC data set or with a spherical harmonic expansion truncated to degree and order 6.