大洋多金属结核中铁锰质矿物拉曼光谱特征初探

拉曼光谱是一种快速无损的分析手段,它既可观察样品的显微结构构造,也可分析样品的成分和结构。为了丰富多金属结核的岩石矿物学特征,文章对西太平洋某海山区的多金属结核样品进行了X射线粉末衍射分析和拉曼光谱分析。X射线分析结果显示该区域样品主要含有水羟锰矿、钡镁锰矿、斜长石、钙十字沸石和石英,显微构造主要有纹层状构造、柱状构造、树枝状构造、充填构造等。通过分析对比潮湿样品和烘干样品铁锰质矿物的拉曼特征谱峰,得出结核中水羟锰矿的特征谱峰位于490 cm~(-1)、570 cm~(-1)和626 cm~(-1)附近,钡镁锰矿的特征谱峰则位于640 cm~(-1)附近,与陆地上对应矿物的特征拉曼谱峰不同。结核中的钡镁锰矿结构不稳定,经过风干或者抛磨后部分产生相变,不同显微结构中,相变情况不同。经与RRUFF数据库比对,识别出钙十字沸石、斜长石等自形晶,多分布于结核最内层,往结核外层总体减少。矿物微晶多见铁锰质矿物微晶和钙十字沸石微晶,铁锰质矿物绕其向外生长。     

越南中部Kontum地块前寒武纪地壳组成和构造演化

越南中部的Kontum 地块是印支地块中前寒武纪变质岩最重要的出露地区之一。该地块由不同时代不同变质程度的岩石组成。该研究通过对该地区主要变质岩的岩石学、地球化学和锆石U-Pb 年代学分析,探讨了Kontum 地块的物质组成以及其形成的构造背景。岩相学和化学成分分析结果表明,这些基底变质岩主要由变质沉积岩和少量的变质火成岩组成。变质沉积岩的原岩主要是硬砂岩和页岩。锆石U-Pb 定年结果显示,这些沉积岩形成于古元古代晚期到新元古代晚期,并大致可以划分为五期沉积盆地的形成和演化,分别对应岛弧环境、被动大陆边缘环境、活动大陆边缘或大陆弧环境、活动大陆边缘-被动大陆边缘过渡环境和活动大陆边缘的构造背景。二个变质火成岩的原岩分别是拉斑玄武岩和S 型花岗岩,它们分别形成于1424 Ma 和1485 Ma。拉斑玄武岩显示富集Rb、Ba、Sr 等大离子亲石元素,亏损Nb、Ta、Zr、Ti 等高场强元素,符合典型岛弧玄武质岩石的地球化学特征。其锆石的εHf(t)值主要为正值（-1.68~+14.2）, 表明其岩浆起源于亏损的岩石圈地幔。地球化学特征表明其形成于岛弧环境,与第三期沉积沉积作用环境相符。S 型花岗岩具有较高的SiO2、ALK和A/CNK（>1.1）,以及中等的稀土含量和中等的Eu 负异常。其原岩岩浆锆石的εHf (t)值变化于+5.97~+12.1,表明源区沉积岩的碎屑主要来自新生地壳。对比显示Kontum 地块与海南岛在中元古代时期很可能曾经相连,在Columbia 超大陆裂解时期处于超大陆的边缘。     

汶川地震震前龙门山以西地壳垂直隆升机理分析

结合流动GPS观测速度场及层析成像结果,构建跨龙门山断裂剖面的二维有限元分层模型,分两种情况讨论汶川地震前龙门山前缘地壳垂直隆升的物理机制,以及中、下地壳软物质垂向和横向的不均匀性对地壳隆升作用的影响。分析认为：川西高原相对四川盆地的差异抬升和龙门山以西地壳缩短的共同作用是汶川地震震前龙门山前缘地壳垂直隆升的可能原因。     

Nishinoshima volcano in the Ogasawara Arc: New continent from the ocean?

Nishinoshima, a submarine volcano in the Ogasawara Arc, approximately 1 000 km south of Tokyo, Japan, suddenly erupted in November 2013, after 40 years of dormancy. Olivine‐bearing phenocryst‐poor andesites found in older submarine lavas from the flanks of the volcano have been used to develop a model for the genesis of andesitic lavas from Nishinoshima. In this model, primary andesite magmas originate directly from the mantle as a result of shallow and hydrous melting of plagioclase peridotites. Thus, it only operates beneath Nishinoshima and submarine volcanoes in the Ogasawara Arc and other oceanic arcs, where the crust is thin. The primary magma compositions have changed from basalt, produced at considerable depth, to andesite, produced beneath the existing thinner crust at this location in the arc. This reflects the thermal and mechanical evolution of the mantle wedge and the overlying lithosphere. It is suggested that continental crust‐like andesitic magma builds up beneath submarine volcanoes on thin arc lithosphere today, and has built up beneath such volcanoes in the past. Andesites produced by this shallow and hydrous melting of the mantle could accumulate through collisions of plates to generate continental crust.     

利用远震研究四川盆地及其周缘瑞利面波相速度和方位各向异性

基于四川盆地及周边的245个宽频带台站2010年9月—2014年9月期间的远震记录,提取双台路径瑞利面波相速度频散资料,反演得到四川盆地20～120s的高分辨率瑞利面波相速度及各向异性空间分布.在丰富区域地球物理基础数据的同时,结合已有研究成果对地壳上地幔变形耦合进行探讨,结果表明短周期(20～30s)的相速度分布与四川盆地的地质构造特征相吻合,作为川滇地块、松潘—甘孜地块和四川盆地之间的边界——龙门山断裂带和鲜水河断裂带对上述三个地块上地壳的速度结构具有明显的控制作用;松潘—甘孜地块,特别是川滇地块中下地壳普遍表现为明显的低速异常,表明中下地壳相对软弱;而四川盆地的中下地壳整体呈现相对高速,表明四川盆地具有相对坚硬的中下地壳.研究区域东南角接近北扬子地块与南扬子地块的缝合部位,呈现高速异常.四川盆地南部和东南邻区不同周期均具有较强的各向异性,且快波方向较为一致,反映这些地区不同深度变形耦合较好.四川盆地西部、北部及东北部邻区,不同周期的各向异性快波方向变化较大,不同深度变形耦合较差.这些特征与绕喜马拉雅东构造结的物质流动被扬子地块的高速地壳阻挡的宏观认识基本一致.     

藏北北羌塘盆地晚三叠世古风化壳地质地球化学特征及其意义

对最近在藏北羌塘盆地菊花山、肖茶卡、石水河等地区新发现的肖茶卡组顶部的粘土质角砾岩的地质、地球化学特征研究表明:其岩石矿物成分、结构构造、角砾层产状及剖面演化序列等与古风化壳的形成及其特征较为一致;相对于基岩,古风化壳的主量元素表现为CaO、CO2的淋失和SiO2、Al2O3、Fe2O3、K2O、Na2O、MnO、P2O5等不同程度的相对富集;古风化壳中的粘土质风化残积层的稀土元素具有明显的富集,表现为LREE含量远大于HREE的特征,存在明显的Ce的正异常以及Eu的负异常;微量元素除Mo、Sn和U外,粘土质风化残积层的其余元素含量均有明显的增加。这些特征从另一角度证实了北羌塘盆地晚三叠世存在明显的沉积间断。晚三叠世肖茶卡组顶部古风化壳的发现,为了解区域地壳发展史、古气候、古地理演化、层序地层的划分与对比、羌塘含油气盆地分析等提供了重要的依据。     

Differential water distribution over dune slopes as affected by slope position and microbiotic crust,Negev Desert,Israel

Runoff is one of the main water sources responsible for water redistribution within a given ecosystem. Water redistribution is especially important in arid regions, and may be of great importance on sandy dunes, where the likelihood of runoff is low owing to the high infiltration rates of sand. Redistribution of water may significantly affect plant and animal distribution, and may explain vegetation patterns within an ecosystem. Runoff yield over sandy dune slopes in the western Negev Desert was measured under natural conditions during 1990–1994. The magnitude of runoff yield on different slope sections and on north and south exposures was established. The results demonstrate that while slope position controlled the microbiotic crust cover, crust cover and crust biomass controlled the amounts of runoff obtained. Whereas no runoff was measured on the upper dune sections devoid of crust, only meagre quantities were measured on the midslope sections, characterized by discontinuous crust cover. Substantially larger amounts were, however, obtained at the bottoms of the slopes, characterized by continuous crust cover. North‐facing slopes, usually characterized by a chlorophyll a content of 29–41 mg m⁻², yielded on average 3·2 times more runoff than south‐facing footslopes, characterized by a 17 mg m⁻² chlorophyll a content. Whereas microbiotic crust was found to be responsible for runoff generation, additional water supply owing to runoff may also explain the occurrence of a high biomass crust and the dense vegetation belt at the dune–interdune interface of the northern exposure, where runoff tends to collect. Thus, whereas crust may reduce infiltration in certain habitats, runoff generated by crust may also be responsible for the promotion of crust growth in other habitats. Runoff may also be used to promote vegetation growth at the dune footslopes. The possibility of using runoff to facilitate agroforestry is discussed. Copyright © 1999 John Wiley & Sons, Ltd.     

太平洋海山地形与钴结壳资源分布的分形研究

通过海山地形与钴结壳资源量的分形研究表明,海山地形与钴结壳资源量间呈多重分形分布。海山坡度与资源量分形呈三段式,引起海山坡度与资源量分段分形的原因是不同类型结壳分布叠加的结果。水深—资源量分形呈三到四段式,引起水深—资源量复杂分形的原因可能与海山基底洋壳有关,海山基底洋壳年龄老于165 M a的海山呈四段式分布,而小于165 M a的海山呈三段式分布。同一区域或不同区域内海山地形与资源分布各不相同。      

Microbial activity promotes the enrichment of cobalt over nickel on hydrogenetic ferromanganese crusts

The different mineral phases of the ferromanganese (Fe–Mn) crusts stem from the interaction of biotic and abiotic components. It is therefore vital to study the activity of these components to decipher their contribution to the enrichment/depletion of metals in the crust. Thus, the present study examined sorption and release of Co and Ni by Fe-Mn crusts with associated microbial communities in the presence and absence of the metabolic poison sodium azide (15?mM). The study was conducted in the presence (G⁺) and absence (G^?) of added glucose (0.1%) at temperatures of 4?±?1°C and 28?±?2°C. Results showed that the microbial community had maximal sorption of Co of 66.12?µg?g^?1 at 4?±?1°C in the absence of added glucose and 479.75?µg?g^?1 at 28?±?2°C in the presence of added glucose. Maximum sorption of Ni in the absence of added glucose was 1.89?µg?g^?1 at 4?±?1°C and release of Ni was 51.28?µg?g^?1 in the presence of added glucose. Under abiotic conditions with 15?mM sodium azide as a metabolic inhibitor, significant amounts of Co and Ni were released in the G⁺ medium. Total cell counts on the Fe-Mn crust in the presence of added glucose increased by an order of magnitude from 10⁶ to 10⁷ cells g^?1 and in the absence of added glucose remained within the order of 10⁶ cells?g^?1 irrespective of temperature of incubation. Microscopic observation of the samples from biotic incubations showed numerous bacterial cells, exopolysaccharides, and structures resembling secondary minerals formed by bacteria. The results indicate that bacteria promote the enrichment of Co and Ni on the hydrogenetic Fe-Mn crusts by sorption processes and release of Ni by reductive dissolution of the oxides. The higher enrichment of Co than Ni is attributed to the way in which microbes interact with the metals.     

桂北地区丹洲群碎屑锆石LA-ICP-MS U-Pb年龄和Hf同位素特征及其地质意义

桂北丹洲群顶部拱洞组粉砂岩的碎屑锆石的阴极发光图像和Th/U(0.2~2.4)值显示,它们均为岩浆成因的锆石。锆石~(206)Pb/~(238)Pb年龄分布在730~769Ma和771~850Ma之间,这些锆石的Hf同位素成分范围较大,ε_(Hf)(t)值和二阶段Hf模式年龄(T_(DM2))分别为-18.4~11.4和1020~2812Ma。此外,样品中还有一些年龄较老的锆石颗粒,~(207)Pb/~(206)Pb年龄为1910~3140Ma,ε_(Hf)(t)值和二阶段Hf模式年龄(T_(DM2))分别为-13.6~3.4和2740~3635Ma。结合前人的研究推测,桂北丹洲群拱洞组沉积年龄小于等于706±10Ma,物源主要由扬子板块新元古代岩浆岩组成,也有少量太古宙岩浆岩的加入。推测中国华南地区存在对应于Rodinia超大陆聚合相关的格林威尔运动的响应。根据已测锆石的ε_(Hf)(t)值和Hf二阶段模式年龄推断,研究区地壳生长主要经历3个阶段:(1)3.64~3.25Ga,初生地壳出现在3.64Ga;(2)2.98~2.37Ga;(3)2.19~1.28Ga,地壳生长的主要时期。