鄂尔多斯盆地中生代晚期以来大地热流的变化及其对生态环境格局和演变的影响

鄂尔多斯盆地的西北部、东北部和南部三个区域现今大地热流平均值分别为56．3、67．3和65．3mW／m^2，对应的生态环境格局也有明显的差异。研究表明，大地热流每增加4～5mW／m^2可使年均地表温度升高约l℃，使最低月均地表温度升高2。C以上。鄂尔多斯盆地东北部的平均大地热流比西北部高出11mW／m^2，东北部年均地表温度可能比西北部高出2～3℃，其最低月均地表温度可能比西北部高出4～6℃。西北部的大地热流平均值已经低于维持地表生态系统延续所需大地热流的临界值(57mW／m^2)，其自然生态系统整体上已经处于脆弱境地；东北部和南部的大地热流均大于57mW／m^2，自然生态系统均尚较稳健。东北部的沙漠化可能是风沙侵入的结果，其生态应该是可以恢复的。整个西北部作为一个整体看，72万年以前大地热流就已衰减到临界值以下，区域生态系统渐趋脆弱，开始整体上向荒漠化演变。     

The structural role of Ti in aluminosilicate liquids in the glass transition range: insights from heat capacity and shear viscosity measurements

The shear viscosities and 1 bar heat capacities of glasses and melts along the 67mol% silica isopleth in the system SiO₂-Al₂O₃-Na₂O-TiO₂ have been determined in the temperature ranges 780-1140 K and 305-1090 K respectively. Anomalous behaviour of both these properties is observed for compositions rich in TiO₂ and/or Al₂O₃, an observation attributed to liquid-liquid phase separation followed by anatase crystallization. For samples which do not show anomalous behaviour, it is found that the partial molar heat capacity of the TiO₂ component previously determined in Al-free compositions reproduces our heat capacities to within 1.3%. Viscosity data show that addition of TiO₂ tends to increase viscosity and melt fragility at constant temperature. Furthermore, heat capacity and viscosity data may be combined within the framework of the Adam-Gibbs theory to extract values of the configurational entropy of the liquids and qualitative estimates of the variation of the average energy barrier to viscous flow. Configurational entropy at 900K is inferred to decrease upon addition of TiO₂, in contrast to previous results from Al-free systems. The compositional limit separating normal from anomalous behaviour, as well as the data for homogenous melts have been used to constrain the structural role of Ti in these samples. Our data are consistent with a majority of Ti in five-fold coordination associated with a titanyl bond, in agreement with previous spectroscopic studies. Furthermore, we find no evidence for a Ti-Al interaction in our samples, and we are led to the conclusion that Al and Ti are incompletely mixed, a hypothesis consistent with the observed reduction of configurational entropy upon addition of TiO₂, suggesting an important role of medium range order in controlling the variations in thermodynamic properties.     

Changes in the spatial scale of Beijing UHI and urban development

The seasonal and interannual variations of Beijing urban heat island (UHI) are investigated in this paper using the temperature data from 1960 to 2000 at 20 meteorological stations in the Beijing region, and then the relationship between the intensity and spatial scale of UHI and Beijing urbanization indices is analyzed and discussed. Main conclusions are the followings. First, Beijing UHI shows obvious seasonal variations, and it is strongest in winter, next in spring and autumn, and least in summer. The seasonal variation of the UHI mainly occurs in the urban area. The UHI intensity at the center of Beijing is more than 0.8℃ in winter, and only 0.5℃ in summer. Second, the intensity of Beijing HUI exhibits a clear interannual warming trend with its mean growth rate (MGR) being 0.3088℃/10 a. The MGR of HUI is largest in winter, next in spring and autumn, and least in summer, and the urban temperature increase makes a major contribution to the growth of HUI intensity. Third, since the Reform and Opening, the urbanization indices have grown several ten times or even one hundred times, the intensity of HUI has increased dramatically, and its spatial scale also expanded distinctively along with the expansion of urban architectural complexes. Fourth, the interannual variation of urbanization indices is very similar with that of HUI intensity, and their linear correlation coefficients are significant at a more than 0.001 confidence level.     

The diurnal and seasonal characteristics of urban heat island variation in Beijing city and surrounding areas and impact factors based on remote sensing satellite data

Based on the land surface temperature (LST), the land cover classification map,vegetation coverage, and surface evapotranspiration derived from EOS-MODIS satellite data, and by the use of GIS spatial analytic technique and multivariate statistical analysis method, the urban heat island (UHI) spatial distribution of the diurnal and seasonal variabilities and its driving forces are studied in Beijing city and surrounding areas in 2001. The relationships among UHI distribution and landcover categories, topographic factor, vegetation greenness, and surface evapotranspiration are analyzed. The results indicate that: (i) The significant UHI occur in Beijing city areas in the four seasons due to high heat capacity and multi-reflection of compression building, as well as with special topographic features of its three sides surrounded by mountains,especially in the summer. The UHI spatial distribution is corresponding with the urban geometry structure profile. The LST difference is approximately 4-6℃ between Beijing city and suburb areas, comparatively is 8- 10℃ between Beijing city area and outer suburb area in northwestern regions. (ii) The UHI distribution and intensity in daytime are different from nighttime in Beijing city area, the nighttime UHI is obvious. However, in the daytime, the significant UHI mainly appears in the summer, the autumn takes second place, and the UHI in the winter and the spring seem not obvious. The surface evapotranspiration in suburb areas is larger than that in urban areas in the summer, and high latent heat exchange is evident, which leads to LST difference between city area and suburb area. (iii) The reflection of surface landcover categories is sensitive to the UHI, the correlation between vegetation greenness and UHI shows obviously negative.The scatterplot shows that there is the negative correlation between NDVI and LST (R2 = 0.6481).The results demonstrate that the vegetation greenness is an important factor for reducing the UHI,and large-scale construction of greenbelts can considerably reduce the UHI effect.     

基于门限回归的气温对光伏发电量的影响分析

光伏发电与气象要素密切相关,正确认识气象因子对于光伏发电量及其发电效率的影响是进行发电量预测和维持光伏电站稳定运行的重要基础。采用江苏省淮安市某小型光伏电站2018—2020年发电量数据、淮安市太阳辐射观测站数据及光伏电站附近气象站观测数据,分析气温、太阳总辐射等气象因子对光伏发电量的影响。相关性分析结果表明,光伏发电量与太阳总辐射呈极强的正相关,基本随太阳总辐射的变化而变化;与气温、降水分别呈弱的正相关和弱的负相关;与风速几乎无相关。然而,灰色关联度分析显示,光伏发电量还与气温呈现出较高的灰色关联度。进一步分析表明,光伏发电量随太阳总辐射的变化受到气温的明显调制,不同气温下光伏发电效率不同。门限回归分析显示,当气温达到一定阈值时光伏发电效率会出现下降,具体表现为：当气温达到12.1 ℃,光伏发电效率下降26.7%;当气温超过22.8 ℃,光伏发电效率下降43.7%。使用这两个温度阈值建立的TR（Threshold Regression）模型的准确率要比线性回归模型提高约10%。     

用X射线荧光光谱法测定Cl、S等31个元素

采用硼酸镶边垫底的粉末样品压片制样,用ARL ADVANT′XP＋型X射线荧光光谱仪对土壤和水系沉积物样品中Na、Mg、Al、Si、P、S、Cl等31个组分进行测定。重点研究了Cl和S等元素的测定条件、痕量元素的背景选择和谱线重叠校正问题。使用经验系数法和康普敦散射作内标校正基体效应。经标准物质校验,结果与标准值吻合。方法的检出限、精密度和准确度能满足多目标地球化学调查样品的分析要求。     

含铁闪锌矿热容的实验测定与分析

利用美国ＤｕＰｏｎｔ公司的９９００型差示扫描量热仪对３个含铁闪锌矿样品的热容进行了实验测定,并讨论了定压摩尔热容实验值与实验温度的关系。实验结果表明,在实验条件下,含铁闪锌矿的定压摩尔热容与纯闪锌矿的定压摩尔热容存在显著差异,Ｆｅ置换Ｚｎ是造成这种差异的主要原因。     

世界核电发展及铀供需态势展望

以权威机构发布的最新资料数据为基础,介绍了世界核电近期至中长期的发展态势,归纳了当前世界铀生产的主要特点,初步分析了至2030年铀的供需关系。认为从世界层面看,铀资源对于近期和中长期的世界铀生产和核电铀需求是有充分保障的,世界铀生产可以满足近期的核电铀需求,但至2015年以后核电的快速发展时期又会出现较大的供需缺口。如果世界新铀矿山的投产和老铀矿山的扩产计划都能如期悉数实现,铀生产满足长期核电铀需求是完全可能的。     

水汽和潜热释放对背风波影响的数值试验

利用中尺度数值模式ARPS进行了理想场的数值模拟,分析研究了水汽和潜热释放对大气层结稳定度的影响以及其在背风波的发展和演变过程中的作用,研究发现,潜热释放对大气层结分布的影响要远大于水汽对大气层结分布的直接影响,如果没有潜热的释放,水汽对背风波的发展和演变的作用非常小,而潜热释放可以使湿层结稳定度急剧下降,迅速破坏原有的层结分布,使这个区域出现非拦截的强烈的垂直运动,波动的崩溃更加迅速和明显。但需要说明的是在试验中,将数值模式里控制潜热释放的参数设为:0、1/2、2的假定情况,则在实际的大气运动过程中是不可能存在的。     

重庆雾的特点及其变化分析

利用重庆市沙坪坝195l一2001年的资料，对重庆市区雾的生消时间、持续时间、能见度等主要特征变量及其相对湿度，温度差等相关气象要素做了较为全面的分析，认为城市热岛效应可能是造成重庆主城区雾日数减少的重要原因之一。