Seasonal dynamics and exports of elements from a first‐order stream to a large inland lake in Michigan

Headwater streams are critical components of drainage systems, directly connecting terrestrial and downstream aquatic ecosystems. The amount of water in a stream can alter hydrologic connectivity between the stream and surrounding landscape and is ultimately an important driver of what constituents headwater streams transport. There is a shortage of studies that explore concentration–discharge (C‐Q) relationships in headwater systems, especially forested watersheds, where the hydrological and ecological processes that control the processing and export of solutes can be directly investigated. We sought to identify the temporal dynamics and spatial patterns of stream chemistry at three points along a forested headwater stream in Northern Michigan and utilize C‐Q relationships to explore transport dynamics and potential sources of solutes in the stream. Along the stream, surface flow was seasonal in the main stem, and perennial flow was spatially discontinuous for all but the lowest reaches. Spring snowmelt was the dominant hydrological event in the year with peak flows an order of magnitude larger at the mouth and upper reaches than annual mean discharge. All three C‐Q shapes (positive, negative, and flat) were observed at all locations along the stream, with a higher proportion of the analytes showing significant relationships at the mouth than at the mid or upper flumes. At the mouth, positive (flushing) C‐Q shapes were observed for dissolved organic carbon and total suspended solids, whereas negative (dilution) C‐Q shapes were observed for most cations (Na⁺, Mg²⁺, Ca²⁺) and biologically cycled anions (NO₃^?, PO₄^3?, SO₄^2?). Most analytes displayed significant C‐Q relationships at the mouth, indicating that discharge is a significant driving factor controlling stream chemistry. However, the importance of discharge appeared to decrease moving upstream to the headwaters where more localized or temporally dynamic factors may become more important controls on stream solute patterns.     

Effectivity of dissolved SF6 tracer for clarification of rainfall–runoff processes in a forested headwater catchment

Understanding rainfall‐runoff processes is crucial for prevention and prediction of water‐related natural disasters. Sulfur hexafluoride (SF₆) is a potential tracer, but few researches have applied it for rainfall‐runoff process studies. We observed multiple tracers including SF₆ in spring water at 1‐ to 2‐hr intervals during rainstorm events to investigate the effectivity of SF₆ tracer in rainfall–runoff studies through the clarification of rainfall–runoff process. The target spring is a perennial spring in a forested headwater catchment with an area of 0.045 km² in Fukushima, Japan. The relationship between the SF₆ concentration in spring water and the spring discharge volume was negative trend; the SF₆ concentration in spring water becomes low as the spring discharge volume increases especially during rainstorms. The hydrograph separation using SF₆ and chloride ion tracers was applied for determining the contribution of principal sources on rainfall–runoff water. It suggested more than 60% contribution of bedrock groundwater at the rainfall peak and high percentage contribution continued even in the hydrograph recession phase. Based on observed low SF₆ concentration in groundwater after heavy rainfall, the replacement of groundwater near the spring with bedrock groundwater is indicated as a mechanism for water discharge with low SF₆ concentration during rainfall events. Consequently, rainstorm events play an important role as triggers in discharging water stored in the deeper subsurface area. In addition, SF₆ tracer is concluded as one of the strongest tracers for examining rainfall–runoff process studies. And, therefore, this study provided new insights into the dynamics of groundwater and its responses to rainfall in terms of SF₆ concentration variance in water in headwater regions.     

Stream geochemical response to reductions in acid deposition in headwater streams: Chronic versus episodic acidification recovery

In the decades since dramatic reductions in acid emissions and subsequent deposition in North America and Europe, the vast majority of research on aquatic chemical recovery has focused on trends in acid–base concentrations during baseflow conditions. Missing from such assessments is consideration of higher flow periods, when flow paths and chemical concentrations change and episodic acidification may occur. Stream samples collected weekly and bi‐hourly during high‐flow storm events from 1992 to 2015 at three watersheds representing a gradient in response to acid deposition in the south‐eastern United States were used to evaluate temporal trends in acid anions, base cations, acid neutralizing capacity (ANC), and pH for each of five distinct flow exceedance regimes, as well as trends in concentration–discharge (C–Q) relationships. For the most well‐buffered watershed (mean ANC = 220 μeq L^?1), ANC and pH increased at a similar rate for baseflow and storm flow conditions. Decreases in sulfate controlled ANC trends at higher flows, whereas smaller sulfate decreases in combination with base cation increases resulted in similar ANC improvements for low‐flow periods. For the most acid sensitive watershed (mean ANC = 10 μeq L^?1), no trends in ANC or pH were observed for the lowest flows (>90% flow exceedance), whereas reductions in sulfate resulted in significant increases in ANC during higher flow conditions. At all sites, greater rates of sulfate decline during high‐flow, as compared with low‐flow, conditions are likely a result of a reduced capacity of near surface soils to adsorb and retain sulfur in these non‐glaciated watersheds. Overall, consistent increases in pH (~0.01–0.02 pH units year^?1) during higher flow conditions (<10% flow exceedance) in contrast to the variable trends observed during lower flows (>50% flow exceedance) illustrate that episodic acidification is recovering at an equal or greater rate than chronic acidification in these watersheds.     

Weathering and Geochemical Processes Controlling Solute Acquisition in Ganga Headwater–Bhagirathi River, Garhwal Himalaya, India

Water and suspended sediment samples were collected along a longitudinal transect of the Bhagirathi – a headwater stream of the river Ganga, during the premonsoon and postmonsoon seasons, in order to assess the solute acquisition processes and sediment transfer in a high elevation river basin. Study results show that surface waters were dominated by HCO₃ and SO₄ in anionic abundance and Ca in cationic concentrations. A high concentration of sulphate in the source region indicates oxidative weathering of sulphide bearing minerals in the drainage basin. The combination of high concentrations of calcium, bicarbonate and sulphate in river water suggests that coupled reaction involving sulphide oxidation and carbonate dissolution are mainly controlling the solute acquisition processes in the drainage basin. The sediment transfer reveals that glacial weathering and erosion is the major influence on sediment production and transfer. The seasonal and spatial variation in ionic concentration, in general, is related to discharge and lithology. The sediment mineralogy and water mineral equilibrium indicate that water composition is in equilibrium with kaolinite. The river Bhagirathi annually delivers 0.74 M.tons of dissolved and 7.88 M.tons of suspended load to the river Ganga at Devprayag. The chemical and physical denudation rate of the Bhagirathi is 95 and 1010 tons/km²/yr, higher than the Indian and global average.     

Impact of forest degradation on streamflow regime and runoff response to rainfall in the Garhwal Himalaya,Northwest India

Baseflows have declined for decades in the Lesser Himalaya but the causes are still debated. This paper compares variations in streamflow response over three years for two similar headwater catchments in northwest India with largely undisturbed (Arnigad) and highly degraded (Bansigad) oak forest. Hydrograph analysis suggested no catchment leakage, thereby allowing meaningful comparisons. The mean annual runoff coefficient for Arnigad was 54% (range 44–61%) against 62% (53–69%) at Bansigad. Despite greater total runoff Q_t (by 250 mm year^–1), baseflow at Bansigad ceased by March, but was perennial at Arnigad (making up 90% of Q_t vs. 51% at Bansigad). Arnigad storm flows, Q_s, were modest (8–11% of Q_t) and occurred mostly during monsoons (78–98%), while Q_s at Bansigad was 49% of Q_t and occurred also during post-monsoon seasons. Our results underscore the importance of maintaining soil water retention capacity after forest removal to maintain baseflow levels.

EDITOR D. Koutsoyiannis; ASSOCIATE EDITOR D. Gerten     

黄河源区不同主体功能区草地恢复措施效果评价

位于青藏高原的黄河源区的高寒草地生态系统和牧民生计都极为脆弱,中国政府已经实施了一系列工程以恢复该区的退化草地。2014年青海省实施的主体功能区规划,依据资源环境承载能力、现有开发强度和发展潜力将研究区分为重点开发区、限制开发区和禁止开发区。本文旨在识别不同主体功能区采用的草地恢复措施并评估其生态和社会经济影响,以筛选有效的恢复措施。基于195份牧户调查问卷和遥感、统计数据,分析发现3类主体功能区的生态和社会经济特征差异:(1)研究区域应用了5种草地恢复措施;(2)2000-2016年间,重点开发区的草地恢复效果优于限制开发区和禁止开发区;(3)重点开发区的家庭纯收入最高;(4)重点开发区牧民对于草地保护和退化草地治理的认知和意愿比其他区域更为积极,该区牧民更多采用围栏+灭鼠+人工饲草地+暖棚舍饲措施。根据不同的发展目标,评估不同区域草地恢复措施的效果有助于促进草地可持续利用和理解区域生态承载力。     

Nutrient dynamics in an alpine headwater stream: use of continuous water quality sensors to examine responses to wildfire and precipitation events

Stream water quality can change substantively during diurnal cycles, discrete flow events, and seasonal time scales. In this study, we assessed event responses in surface water nutrient concentrations and biogeochemical parameters through the deployment of continuous water quality sensors from March to October 2011 in the East Fork Jemez River, located in northern New Mexico, USA. Events included two pre‐fire non‐monsoonal precipitation events in April, four post‐fire precipitation events in August and September (associated with monsoonal thunderstorms), and two post‐fire non‐monsoonal precipitation events in October. The six post‐fire events occurred after the Las Conchas wildfire burned a significant portion of the contributing watershed (36%) beginning in June 2011. Surface water nitrate (NO₃? N) concentrations increased by an average of 50% after pre‐fire and post‐fire non‐monsoonal precipitation events and were associated with small increases in turbidity (up to 15 NTU). Beginning 1 month after the start of the large regional wildfire, monsoonal precipitation events resulted in large multi‐day increases in dissolved NO₃? N (6 × background levels), dissolved phosphate (100 × background levels), specific conductance (5 × background levels), and turbidity (>100 × background levels). These periods also corresponded with substantial sags in dissolved oxygen (<4 mg l^?1) and pH (<6.5). The short duration and rapid rates of change during many of these flow events, particularly following wildfire, highlight the importance of continuous water quality monitoring to quantify the timing and magnitude of event responses in streams and to examine large water quality excursions linked to catchment disturbance. Copyright © 2015 John Wiley & Sons, Ltd.     

Interaction between runoff – bedrock groundwater in a steep headwater catchment underlain by sedimentary bedrock fractured by gravitational deformation

Recent studies have suggested the importance of the bedrock groundwater (BG) contribution in storm runoff in headwater catchments. However, few such studies have been conducted, and the study of different types of bedrock conditions is still ongoing. The role of BG in storm runoff is still poorly understood, particularly in headwater catchments underlain by relatively deep fractured bedrock. This study aims to clarify this role using hydrometric and hydrochemical observations of BG via boreholes and catchment discharge. The responses of the BG to rainfall are demonstrated to be fast and independent of the sediment cover. The BG exhibits different responses and flow paths that are largely controlled by the bedrock fracture system. The storm runoff in the studied catchment is characterized by rapid discharge response generally followed by a delayed discharge response. The peak of the delayed discharge is much faster than that observed in previous studies, and it is well correlated with the BG levels. A hydrograph separation was performed for two storm events using three end members: rainfall, shallow BG and deep BG. The results demonstrate that the delayed discharge is primarily composed of deep BG. Moreover, a significant contribution of shallow BG is observed during large precipitation events. Although we observed no physical evidence of direct contributions of BG in the catchment, the calculations presented in this study demonstrate that the BG controls the hydrological and hydrogeological response of the catchment to rainfall events. Copyright © 2015 John Wiley & Sons, Ltd.     

Subsurface hydrology of tile-drained headwater catchments: Compatibility of concepts and hydrochemistry

Concepts and terms used in previous multidisciplinary studies of tile-drained aquitard-dominated catchments (TDADC) are inconsistent and confusing. We provide a well-defined, comprehensive conceptual model of the subsurface hydrology of TDADC by selecting seven mutually compatible and consistent concepts. These concepts are: (1) groundwater as the main source of baseflow in headwater streams, (2) dominance of ‘pre-event’ water in stormflow, (3) importance of both macropores and matrix, (4) changes in flowpaths with rate of stream discharge, (5) dominance of shallow, lateral subsurface flow, (6) interactive nature of subsurface water, (7) transpiration of groundwater. This conceptual model was successfully ‘field-tested’ by examining data collected in a TDADC in a rural area of southern Ontario, Canada. The data consist mainly of chemical and isotopes tracers in water samples (headwater streams, groundwater, precipitation, tile water, soil-surface water), supplemented by water levels and meteorological data.     

黄河源区基流量的变化规律及影响因素

选用改进的加里宁方法计算出源区的基流量,利用小波变换、小系数方差等方法分析了1955—1999年基流量周期变化规律,同时利用显著周期振幅的不稳定性,计算同周期基流量与气象要素的小波系数的相关系数,判定了基流量变化趋势及显著周期的气象成因,确定了三次断流的原因。计算结果表明:源区基流量存在一个强趋势项、7~8a与3~4a两个显著周期。强趋势项决定了基流量的总体变化规律。受其影响,20世纪50年代以来,源区基流量呈现枯—丰—枯的变化规律。强趋势项与两个显著周期的叠加是基流丰枯变化的本质,是历史上三次断流的根本原因。计算结果还表明,基流量的强趋势项为气温所致,两个显著周期为降水所致。源区植被覆盖率与基流指数成负相关关系,当植被覆盖率增加20%时,基流指数将减少10%以上。