山东平邑县德埠庄石膏矿区北矿段水文地质特征分析

德埠庄石膏矿区北矿段位于平邑凹陷的西部,通过研究区内地质孔简易水文地质编录、水文地质孔分层抽水试验,查明了矿床水文地质条件及石膏矿带含水特征,确定水文地质单元边界条件模型,采用“水文地质比拟法”预测矿床正常涌水量和最大涌水量,在此基础上划定矿床水文地质条件属于中等型。     

Calibration of a hysteretic model for glass fiber reinforced gypsum wall panels

Glass fi ber reinforced gypsum(GFRG) wall panels are prefabricated panels with hollow cores, originally developed in Australia and subsequently adopted by India and China for use in buildings. This paper discusses identifi cation and calibration of a suitable hysteretic model for GFRG wall panels fi lled with reinforced concrete. As considerable pinching was observed in the experimental results, a suitable hysteretic model with pinched hysteretic rule is used to conduct a series of quasi-static as inelastic hysteretic response analyses of GFRG panels with two different widths. The calibration of the pinching model parameters was carried out to approximately match the simulated and experimental responses up to 80% of the peak load in the post peak region. Interestingly, the same values of various parameters(energy dissipation and pinching related parameters) were obtained for all fi ve test specimens.     

新疆乌苏地区新近系石膏脉特征及形成过程

基于野外地质调查及采集样品的微观分析,文中详细研究了新疆乌苏地区新近系发育的石膏脉特征,并从古沉积环 境、成岩作用、风化作用和溶盐水注入期次等方面分析了石膏脉的形成过程。该区石膏脉发育形态特殊,主要是由两横两 纵4条线状主控石膏脉派生出的各种产状石膏脉组成,呈龟壳状。通过分析认为该石膏脉的形成过程共经历过4个阶段,炎 热的古沉积环境为沉积大量的石膏矿物奠定了基础,先成岩后胶结的成岩作用为石膏脉形成提供了必要条件,加上强烈的 风化作用和多期地表溶盐水注入和析出,形成了现今的龟壳状结构石膏脉。该套石膏脉的存在为推测盆地中心可能存在天 然储层裂缝改造区提供线索,并对西北地区新近纪干旱沉积环境具有一定的指示意义。     

Origins of High H_2S-bearing Natural Gas in China

Natural gas containing hydrogen sulphide （H2S） has been found in several petroliferous basins in China, such as the Sichuan Basin, Bohai Bay Basin, Ordos Basin, Tarim Basin, etc. Natural gas with higher HES contents （HES 〉5 % mol.） is mostly distributed in both the gas reservoirs of Dukouhe, Luojiazhai, Puguang and Tieshanpo, which belong to the Triassic Feixianguan Formation in the northeastern Sichuan Basin and those of the Kongdian-Shahejie formations in the northeastern Jinxian Sag of the Jizhong Depression, Bohai Bay Basin. In the Sichuan Basin, the HES contents of natural gas average over 9% and some can be 17 %, while those of the Bohai Bay Basin range from 40 % to 92 %, being then one of the gas reservoirs with the highest H2S contents in the world. Based on detailed observation and sample analysis results of a total 5000 m of core from over 70 wells in the above-mentioned two basins, especially sulfur isotopic analysis of gypsum, brimstone, pyrite and natural gas, also with integrated study of the geochemical characteristics of hydrocarbons, it is thought that the natural gas with high HES contents resulted from thermochemical sulfate reduction （TSR） reactions. Among them, the natural gas in the Feixianguan Formation resulted from TSR reactions participated by hydrocarbon gas, while that in the Zhaolanzhuang of the Jinxian Sag being the product of TSR participated by crude oil. During the consumption process of hydrocarbons due to TSR, the heavy hydrocarbons were apt to react with sulfate, which accordingly resulted in the dry coefficient of natural gas increasing and the carbon isotopes becoming heavier.     

中国北方宁南盆地古近纪晚期咸化湖盆演化及其区域地质意义

本文以宁南盆地北部的贺家口子清水营组剖面为研究目标,对古近纪晚期清水营组的岩性特征、石膏主元素地球化学特征和泥岩有机地球化学特征进行研究,结果表明:清水营组岩性以灰绿-紫红色泥岩、石膏及二者互层为主,可划分为8个二级沉积旋回和3个一级沉积旋回。石膏中CaO含量反映了咸化湖盆中石膏的化学沉积作用,Al_2O_3等为陆源碎屑来源,清水营组下段为盐湖深水环境沉积的纯净石膏;中段石膏沉积的水体较浅。清水营组下段地层泥岩TOC和生烃潜量(S_1+S_2)较高,说明在咸化湖盆演化早期气候较湿润、水体较深;而泥岩降解潜力相对小,反映有机质以高等植物来源为主,陆源输入较多。在此研究基础上,认为宁南盆地清水营组沉积包括:蒸发岩的沉积和碎屑岩的沉积;咸化湖盆演化尚未达到钾盐等盐岩沉淀的高浓缩阶段。咸化湖盆演化主要经历了早期封闭深水盐湖发育阶段、中期封闭浅水盐湖鼎盛阶段和晚期开阔浅水盐湖消亡阶段。宁南盆地古近纪晚期咸化湖盆演化与盆地的持续构造沉降和各次级沉积坳陷最终连为统一的湖泊这一重大区域沉积事件有明显的响应关系。     

石膏ESR测年信号g=2.004峰热稳定性的初步研究

用热活化技术,对甘肃兰州盆地和临夏盆地石膏样品的测年信号稳定性,以及石膏转化为干石膏的脱水情况进行了研究.根据干石膏在不同温度下的等温退火实验,应用双二级动力学和双活化能模式,估算出干石膏中陷阱电子g=2.004峰的平均寿命在20 ℃时为1.78×107a.     

酸碱滴定法测定天然石膏中碳酸盐的不确定度评定

对酸碱滴定法测定天然石膏中碳酸盐的结果进行不确定度评定。测量过程中的不确定度主要来源于样品制备过程引入的不确定度、滴定导致的不确定度、标定NaOH标准滴定溶液和HCl标准溶液引起的不确定度及重复性实验引起的不确定度等。合成各不确定度分量,并乘以扩展因子2得到扩展不确定度。对于CO₂平均含量为8.66%（质量分数）的天然石膏样品,其扩展不确定度为0.17%。     

高速铁路膏溶角砾岩深埋隧道支护荷载确定方法

合理的支护荷载确定方法是膏溶角砾岩深埋隧道设计和施工过程中的关键科学问题。以石太客运专线太行山隧道累计穿越4 410 m膏溶角砾岩地层为依托,通过现场支护荷载量测试验,统计得到初支围岩压力和二衬接触压力。采用泰沙基理论、比尔鲍曼理论、谢家烋理论、铁路隧道设计规范和普氏理论共5种方法分别计算围岩压力,并与现场实测值相比较。结果表明：围岩压力以竖向为主,泰沙基理论值与现场实测统计值最为接近;围岩压力在竖向、水平分布模式不同于传统计算方法,推荐竖向压力采用双峰型或均匀分布,水平压力采用折线型分布;初支和二次衬砌共同承担荷载,二衬分担比例为50.1%。研究成果可为高速铁路膏溶角砾岩以及类似地质条件深埋隧道修建提供参考。     

Modelling ion composition in seepage water from a column experiment with an open cut coal mine sediment

Secondary reactions occurring in pyrite-containing sediments from open cut coal mines are complex and not fully understood. In this study, the changes in seepage water composition in a column experiment with a sediment containing pyrite (5.6 g kg⁻¹) were evaluated using a chemical equilibrium model. A column experiment with artificial irrigation (730 mm water yr⁻¹) was carried out for 2 yr with a sediment from the open pit mine Garzweiler, Germany, at the Institute of Applied Geology. Tracer (LiCl) was added to the sediment. Seepage water composition at 52 cm depth was sampled weekly. Redox potential and the water potential were also recorded weekly. Sulphate and Fe(II) were the dominant ions in the seepage water with concentration maxima of 500 and 350 mmol l⁻¹ after 50 days (0.7 pore volumes (PV)). Minimum pH values were around 0.8 after 100 days (1.4 PV), but increased subsequently and reached 2.4 after 700 days (9.5 PV). Ion activity product calculations indicated the intermediate formation of gypsum (19th–480th day of the experiment). Solutions were undersaturated with respect to alunite, jarosite, jurbanite, schwertmannite, melanterite, gibbsite and goethite during the whole experiment. The model of coupled equilibria which included inorganic complexation, precipitation/dissolution of gypsum and multiple cation exchange was tested. Pyrite oxidation and pH-dependent silicate weathering were considered using simple input functions. Transport was modelled using a field capacity cascade submodel. Model results showed satisfactory agreement with measured values for pH and concentrations of SO₄, Fe, Mg, Ca and Al. Correlation coefficients lay between 0.7 and 0.9 and linear regression coefficients (modelled against measured) were 1.5 (Ca), 1.0 (Fe, SO₄), 0.8 (Mg), 0.7 (pH) and 0.6 (Al). The results showed that the protons produced during pyrite oxidation (94 mmol_c H⁺ kg⁻¹) were mainly released into seepage water (as HSO₄⁻ and H⁺). Cation exchange reactions buffered 20 mmol_c of H⁺ kg⁻¹ sediment, and Al released by silicate weathering accounted for 3.6 mmol_c H⁺ kg⁻¹. Modelling was useful to further understand the significance of different pH buffer reactions.     

Development of Sulfuric Acid Speleogenetic Deposits within Cavernous Middle Eocene Beds: Inference on Hydrocarbon Gas Seepages,Giza Pyramids Plateau,Egypt

Development of sulfuric acid speleogenetic mineral deposits within cavernous middle Eocene beds of the Pyramids plateau is linked to hydrocarbon gas seepages. The work carried out field observations, binocular, polarizing, scanning and transmitted electron microscopy investigation, X-ray diffraction and X-ray fluorescence analyses. The morphological and petrographic features and chemical composition of the studied mineral deposits reveal a hypogene sulfuric acid speleogenesis. A model comprised of the following stages can be used to explain the presence of these features. (1) Ascent of hydrogen sulfide (H2S) gas associated with hydrocarbon seepages from the Cretaceous reservoirs under reducing conditions followed by oxidation to sulfuric acid (H2SO4), (2) descent of carbonic acid (H2CO3)-rich solution generated from surface sources, (3) reaction of H2SO4 and H2CO3 with the calcareous and argillaceous host rocks, (4) formation of H2SO4 speleogenetic by-products represented by natroalunite, aluminium-phosphate-sulfate, hydrated halloysite and Fe/Mn oxides within the replacive gypsum, and (5) subsequent stresses due to the formation of nearby stratiform cavities gave rise to the development of fractures/veinlets filled with displacive fibrous satinspar gypsum. The study sets the paleokarst features of the Giza Pyramids plateau within a hypogene sulfuric acid karst system developed by the action of groundwater containing H2S, H2SO4 and H2CO3.