DEM空间分辨率对毒气扩散模型模拟结果的影响分析

突发性毒气泄漏事故的频繁发生对市民的安全造成了极大威胁,有必要对常见毒气泄漏事故发生后的成灾模型进行探讨,以便从理论上指导应急部门实施应急救援行动。本文在研究和分析典型毒气泄漏扩散模型的基础之上,引入地形因子对原有毒气泄漏扩散模型进行改进,使之适应三维地形下的危化品气体扩散模拟,并将模型与GIS集成可视化,分析比较了模型修正前后气体扩散浓度的分布情况。在此基础上,进一步分析了DEM空间分辨率对毒气扩散浓度的分布影响,发现DEM空间分辨率对毒气浓度分布区域有一定影响,并分析了其影响原因。结果表明,加入地形因子的高斯烟羽模型比之前没有考虑地形因子的高斯模型计算要更加精确,更贴近现实状况;同时,DEM分辨率对改进后的高斯烟羽模型的模拟影响较大,选择适当分辨率的DEM能帮助应急部门在短时间内模拟出真实可靠的浓度分布区域,对毒气泄漏事故的应急有一定的实际参考价值和指导意义。     

中国新能源发电生命周期温室气体减排潜力比较和分析

从生命周期的角度分析,各类新能源发电技术的开发、建设、运行过程,也会带来一定的温室气体排放,这引发了人们对于新能源发电技术“低碳”属性的担忧。遵循生命周期评价方法,在对国内外大量资料文献进行收集整理的基础上,对中国传统火电和主要新能源发电技术的温室气体排放系数进行了对比分析;并根据国家发展规划目标,对新能源发电替代火电的温室气体减排潜力进行了估算。分析结果表明,即使考虑生命周期内的排放,新能源发电技术的温室气体排放系数仍远远低于火电,新能源发电技术替代火电的温室气体减排潜力巨大。     

岩石物理模版在储层定量解释中的应用

岩石物理模板采用测井解释的各类岩性矿物骨架点值,选取适合该地区的岩石物理模型,模拟在不同储层组合、不同孔隙及不同饱和度情况下,储层岩石物理参数变化引起的储层测井参数及地球物理响应特征的变化,定量地建立起储层参数同地球物理弹性参数间的解释关系模版.本文根据新场JS42气藏储层参数分析结果,尝试性地将岩石物理解释模板应用于储层定量解释中,对储层高产气区、含水区域进行定量解释,并预测了该气藏的气水界面,该预测结果与实钻井测试情况吻合,证实了该方法的科学性.     

Biodegradation Studies on Acid Violet 19, a Triphenylmethane Dye,by Pseudomonas aeruginosa BCH

Acid violet 19 (AV) belongs to the triphenylmethane (TPM) class of dyes which are potentially mutagenic or carcinogenic. However, very little studies on biodegradation of AV were reported as compared to other TPM dyes such as malachite green and crystal violet. In this study, AV was decolorized up to 98% within 30 min by Pseudomonas aeruginosa BCH. The decolorization depends on the initial dye concentration, pH, and temperature. However, the dye was decolorized under wide pH and temperature ranges with an optimum of pH 7 and 30°C. Up to 250 mg L^?1 of dye was found to be tolerated and decolorized by this strain. It showed decolorization ability for seven repeated dye addition cycles. The effect of additional carbon sources on dye decolorization was studied in which mannitol containing medium showed decolorization in 15 min. Induction in the enzyme activities of laccase, NADH‐DCIP reductase, and veratryl alcohol oxidase (VAO) indicates their involvement in AV degradation. Various analytical studies viz. UV–VIS, HPTLC, HPLC, and FTIR confirmed the biodegradation of AV by the bacterium. Based on GC‐MS analysis, a possible degradation pathway for AV was proposed. The phytotoxicity studies using Phaseolus mungo and Sorghum vulgare revealed the less toxic nature of metabolites formed after AV degradation.     

深冷环境下海水冷冻淡化性能试验研究

提出利用液态天然气(LNG)冷能实现海水冷冻淡化,针对LNG的储运工艺,开展海水在超低温环境下的过冷度、结晶、脱盐等机理研究。试验测试了海水在电导率为20～40 mS/cm、冷冻温度为-30～-80℃冷冻条件下,制冰率、制冰速率、脱盐率等性能指标,并分析了影响各性能指标的因素,得出了超低温工况下系统最优过程参数。该研究结果为基于LNG冷能实现海水冷冻淡化的工程设计提供了必要的技术基础和设计依据。     

Accumulation and exploration of gas hydrate in deep-sea sediments of northern South China Sea

The large deep-sea area from the southwestern Qiongdongnan Basin to the eastern Dongsha Islands,within the continental margin of northern South China Sea,is a frontier of natural gas hydrate exploration in China.Multiform of deep-sea sedimentations have been occurred since late Miocene,and sediment waves as a potential quality reservoir of natural gas hydrate is an most important style of them.Based on abundant available data of seismic,gravity sampling and drilling core,we analyzed the characteristics of seismic reflection and sedimentation of sediment waves and the occurrence of natural gas hydrate hosted in it,and discussed the control factors on natural gas hydrate accumulation.The former findings revealed the deep sea of the northern South China Sea have superior geological conditions on natural gas hydrate accumulation.Therefore,it will be of great significance in deep-sea natural gas hydrate exploration with the study on the relationship between deep-sea sedimentation and natural gas hydrate accumulation.     

钼催化作用下的煤成烷烃气碳同位素演化

为了阐释钼催化作用下的煤成气碳同位素演化特征和机理,采用在原煤中添加单质钼的方式,开展催化生气模拟试验,测定模拟系列气样的单体烷烃气碳同位素组成,并对其演化规律和模式进行探讨.结果表明:无论加钼与否,模拟气甲烷碳同位素组成(δ(13C1))均以镜质组反射率1.1%为界分为演化趋势截然相反的2个阶段,乙烷碳同位素组成(δ(13C2))不存在明显的演化阶段性,但加钼煤样δ(13C2)由在较低成熟度阶段重于原煤样变为在较高成熟度阶段轻于原煤样;加钼条件下,模拟烷烃气呈现出正碳同位素系列,δ(13C1)为(-25~-45)×10-3,δ(13C2)重于-29×10-3,表明钼催化成因气属于有机热成因气范畴.对比模拟烷烃气碳同位素组成与镜质组反射率之间的关系,发现模拟烷烃气碳同位素组成演化规律与前人模式有所不同.加钼煤样的不同单体烷烃气碳同位素组成随有机质成熟度变化速率的不同而不同,指示生气作用在钼催化作用下得到增强,这一效应在裂解气生成过程中更为显著;加钼煤样δ(13C2)在较高成熟度条件下轻于原煤样δ(13C2)的原因可能在于钼催化效应促进了煤中壳质组裂解生气.     

国内外页岩气研究进展及山东省页岩气资源潜力

当前国际能源供需矛盾突出,能源问题日益成为各国关注的焦点,页岩气资源勘查开发备受世界瞩目;全球页岩气资源非常丰富,主要分布在北美、中亚和中国、拉美、中东和北非、前苏联地区;近年来随着开采和利用技术的不断进步,美洲、欧洲、亚洲国家对页岩气的勘查开发正在形成热潮。中国页岩气资源丰富,对页岩气的区域勘查研究越来越多,取得了不错的成果,但总体上中国页岩气的研究和勘查尚处于起步阶段,同时中国的开发技术与国外相比还存在较大的差距。结合山东省不同类型富含有机质泥页岩的具体特点和国内外页岩气勘查经验,初步认为山东省具有一定的页岩气形成条件,山东省页岩气远景区地层主要为新生代古近纪济阳群和五图群及官庄群,中生代早白垩世莱阳群,古生代石炭—二叠纪月门沟群和石盒子群;在综合考虑页岩的赋存层位、页岩成气潜力和页岩气开发可行性的基础上,提出了山东省页岩气潜力区为:济阳坳陷区、临清坳陷区、胶莱坳陷区和黄县(龙口)凹陷以及鲁西南潜隆起区,其中济阳-临清坳陷地区页岩气潜力较好。     

Evaluation of coal bed methane content using BET adsorption isotherm equation

Coal bed methane is unconventional raw natural gas stored in coal seam with considerable reserves in China.In recent years,as the coal bed methane production,the safety and the use of resources have been paid more attentions.Evaluating coal bed methane content is an urgent problem.A BET adsorption isotherm equation is used to process the experimental data.The various parameters of BET equation under different temperatures are obtained;a theoretical gas content correction factor is proposed,and an evaluation method of actual coal bed methane is established.     

Heat calculation and numerical simulation in steam mining of permafrost gas hydrate

Steam mining method was injecting hot steam into the borehole to heat the hydrate strata at the same time of depressurization mining,which could promote further decomposition and expand mining areas of gas hydrate. Steam heat calculation would provide the basis for the design of heating device and the choice of the field test parameters. There were piping heat loss in the process of mining. The heat transfer of steam flowing in the pipe was steady,so the heat loss could be obtained easily by formula calculation. The power of stratum heating should be determined by numerical simulation for the process of heating was dynamic and the equations were usually nonlinear. The selected mining conditions were 500-millimeter mining radius,10 centigrade mining temperature and 180 centigrade steam temperature. Heat loss and best heating power,obtained by formula calculation and numerical simulation,were 21. 35 W/m and 20 kW.