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141.
The monitoring of sulfur species in crater lakes has proven to be useful for forecasting episodes of volcanic unrest in certain active volcanoes, including Poás, Costa Rica; Kusatsu-Shirane, Japan; and Mt. Ruapehu, New Zealand. In this study, we have improved the current geochemical monitoring of El Chichón volcano through the setting of optimal high-performance liquid chromatography conditions (HPLC) for the analysis of S2−, SO32−, S2O32−, S4O62− and SO42− using a common chromatographic system. The procedure was applied to the analysis of lake samples taken in March, July and October of 2014 and April of 2015. The results were promising, since nearly all species were detected (with the exception of S2O32−) in measurable amounts, including S2− (<0.85–5.05 mg/L), SO32− (<2.77–26.1 mg/L), S4O62− (108.27–303.82 mg/L) and SO42− (489.58–676.26 mg/L). The spatial distribution of these species along the lakeshore showed zones of increased concentrations to the east and southeast of the lake, which provides information on the distribution of faults or cracks that feed hydrothermal fluids to the lake. This method thus provides additional information linked to the volcanic and hydrothermal activity of the volcano. 相似文献
142.
ZOU Caineng YANG Zhi PAN Songqi CHEN Yanyan LIN Senhu HUANG Jinliang WU Songtao DONG Dazhong WANG Shufang LIANG Feng SUN Shash HUANG Yong WENG Dingwei 《《地质学报》英文版》2016,90(4):1249-1283
Shale gas is one of the most promising unconventional resources both in China and abroad. It is known as a form of self-contained source-reservoir system with large and continuous dimensions. Through years of considerable exploration efforts, China has identified three large shale gas fields in the Fuling, Changning and Weiyuan areas of the Sichuan Basin, and has announced more than 540 billion m~3 of proven shale gas reserves in marine shale systems. The geological theories for shale gas development have progressed rapidly in China as well. For example, the new depositional patterns have been introduced for deciphering the paleogeography and sedimentary systems of the Wufeng shale and Longmaxi shale in the Sichuan Basin. The shale gas storage mechanism has been widely accepted as differing from conventional natural gas in that it is adsorbed on organic matter or a mineral surface or occurs as free gas trapped in pores and fractures of the shale. Significant advances in the techniques of microstructural characterization have provided new insights on how gas molecules are stored in micro- and nano-scale porous shales. Furthermore, newly-developed concepts and practices in the petroleum industry, such as hydraulic fracturing, microseismic monitoring and multiwell horizontal drilling, have made the production of this unevenly distributed but promising unconventional natural gas a reality. China has 10–36 trillion m~3 of promising shale gas among the world's whole predicted technically recoverable reserves of 206.6 trillion m~3. China is on the way to achieving its goal of an annual yield of 30–50 billion m~3 by launching more trials within shale gas projects. 相似文献
143.
As a milestone of the entire energy industry, unconventional resources have inevitably swept the world in the last decade, and will certainly dominate the global oil and gas industry in the near future. Eventually, the “unconventional” will become “conventional”. Along with the rapid development, however, some issues have emerged, which are closely related to the viability of unconventional resources development. Under the current circumstances of low crude oil and gas price, coupled with the prominent environmental concerns, the arguments about the development and production of unconventional resources have been recently heated up. This work introduced the full-blown aspects of unconventional resources especially shale reservoirs, by discussing their concepts and definitions, reviewing the shale gas and shale oil development history and necessity, analyzing the shale plays’ geology and petroleum systems with respects to key hydrocarbon accumulation elements and mechanisms, and summarizing the technology resolution. This study also discussed the relevant key issues, including significant estimation uncertainty of technically recoverable resources, the equivocal understanding of complex geology preventing the production and technologies implementation optimization, the difficulties of experiences and technologies global expanding, and the corresponding risks and uncertainties. In addition, based on the latest production and exploration data, the future perspective of the unconventional resources was depicted from global unconventional resources assessments, technology development, and limitations constraining the development. 相似文献
144.
近年来输气管道工程的大规模建设,其不可避免地要通过一些煤矿采空沉陷区和地质构造复杂区域。煤矿采空沉陷区的地表移动变形必然会使上覆的输气管道发生变形、甚至破坏,因此,分析与预测煤矿采空区地埋输气管道的安全性具有重要意义。本文以西气东输一线为例,依据弹性理论分析计算,当管道下伏分别为土体和岩体时,输气管道破坏时的岩土体垮塌宽度,并统计在垮塌影响范围一定的条件下,岩土体垮塌宽度与管道变形及最小曲率半径之间的规律。结果表明,管道的弯曲变形与垮塌宽度之间呈递增关系。 相似文献
145.
海拉尔盆地呼和湖凹陷具备形成大面积致密砂岩气藏的地质条件,其断陷期地形比较宽缓,后期改造弱,主要发育低幅度的断背斜或宽缓的向斜,在局部具备稳定的构造条件。南二段煤系源岩广泛发育,丰度均达到中等--好烃源岩级别,为致密砂岩气藏的形成提供了充足的物质基础。洼槽区南二段储层属低孔--特低渗型储集层。南二段致密储层与煤、泥岩呈频繁互层状分布,形成致密砂岩气有利的的生储盖组合。构造高部位在一定程度上控制油气丰度,稳定的负向构造区有利于寻找储层富集区。呼和湖凹陷致密砂岩气主要表现为两种成藏组合,自生自储型和内生外储型,油气呈南北向条带状分布。 相似文献
146.
运用高压压汞、液氮吸附及渗透率测试等实验,利用极差、突进系数、变异系数等参数,表征煤系页岩孔渗特征及孔隙层间非均质性,分析孔隙层间非均质性主控因素。结果表明:河南义马地区上、下石盒子组泥页岩微孔与小孔较为发育,山西组大孔较为发育,分别提供了气体吸附附着面积和储存运移空间;上石盒子组孔容与孔径相对偏差最小,孔隙分布均匀,山西组比表面积相对偏差最小,表面积分布均匀;随围压增大,渗透率不断降低,且满足负指数相关关系;渗透率级差、突进系数和变异系数显示下石盒子组渗透率非均质性较弱,山西组渗透率非均质性很弱,更易于压裂开发。非均质性宏观上主要受沉积物质组成和构造改造作用影响,微观上受成岩演化影响。 相似文献
147.
昭通国家级页岩气示范区黄金坝气田是继礁石坝和长宁—威远之后中国又一个在页岩气勘探、开发领域实现重大突破的地区,为了系统地展示黄金坝气田页岩气资源富集的储层条件,为未来的勘探工作提供参考,以五峰—龙马溪组页岩气储层为研究对象,从区域地质条件、储层岩石学、物性和地球化学4个方面对该页岩气储层进行了综合研究。结果表明稳定的区域构造和良好的顶底板条件是黄金坝地区页岩气资源富集的关键,良好的保存条件使储层维持了较高的压力(压力系数1);较高的孔隙度(平均4%)和TOC含量(目的层2%)提供了良好的储集空间,使储层具有较高的含气量(1.35~3.48 cm3/g,平均2.50 cm3/g);天然气地球化学数据表明,区内天然气主要成分为CH4(97%),其次还含有少量的C2H6、C3H8和CO2;天然气同位素数据表明烃类C同位素组成发生了倒转,表明储层具有良好的封闭性。但储层孔隙系统较为复杂,且非均质性极强,从而导致渗透率较低,在储层改造施工过程中应予以充分考虑。总体上,黄金坝气田具有较好的开发前景,生产测试表明,区内直井压裂产量为0.5×104~3.5×104m3/d/井,水平井压裂产量可达12×104~40×104m3/d/井。 相似文献
148.
系统岩心观察和高密度薄片鉴定等分析测试资料研究结果显示,济阳坳陷沙三下-沙四上泥页岩成分组成及构造类型主要受沉积作用控制,岩石结构特征主要受成岩作用控制。根据泥页岩中方解石成因及重结晶程度,结合岩石成分及构造特征,将济阳坳陷沙三下-沙四上泥页岩划分为沉积主控型、沉积-成岩双控型及成岩主控型三大成因相。沉积主控型分布最为广泛,岩相类型多样,构造特征反映成因环境;沉积-成岩双控型主要见于纹层状岩相,由泥质纹层与显晶粒状方解石纹层互层构成;成岩主控型以柱状、柱纤状方解石垂直层面呈脉状、透镜状产出为特征。成岩主控型和沉积-成岩双控型泥页岩与页岩油气关系密切,是重要的有利成因相类型。 相似文献
149.
油气上窜速度对钻井施工中下一步施工方案的制定具有重要参考价值。文章在总结分析前人经验的基础上结合现场施工实际对传统油气上窜速度计算公式加以修正,并对修正后的公式中涉及到的参数进行了逐一分析,在不影响正常施工工序的条件下使公式中各参数取值准确性进一步提高。通过现场工程测试,该方法简单实用且计算准确性较高。该计算方法在保证计算结果准确性的同时,也具备较强的现场可操作性,通过大量的实践检验后可进一步推广。 相似文献
150.