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41.
42.
悬浮液进样氢化物发生原子荧光法测定海洋沉积物样品中痕量砷 总被引:6,自引:0,他引:6
人类对砷的认识已有很长的历史,近几十年来关于砷对环境的污染以及对人体健康的影响日益受到人们的关注.砷是海洋沉积物中常见的主要环境污染元素之一,目前测定它的常用方法有砷钼酸-结晶紫分光光度法[1]、氢化物-原子吸收分光光度法[1]、催化极谱法[1]、氢化物-原子荧光光谱法[2],但是这些方法需将样品制备成溶液,处理过程冗长,易引起操作沾污和待测成分损失,而且试剂消耗量大,同时产生的酸气对操作人员的身体健康非常有害,为此分析工作者一直在寻求一些新的前处理技术. 相似文献
43.
大气气溶胶中若干有机物的含量和季节变化 总被引:2,自引:2,他引:2
研究、探讨青岛近岸大气气溶胶中多芳烃类化合物的浓度水平、变化特征及影响因素。用高效液相色谱荧光检测法分析了青岛近岸大气气溶胶中的多环芳烃(PAHs)的含量水平,共检出13种多环芳烃化合物。结果表明该类化合物总量(∑PAHs)具有明显的季节特征,呈现春季<秋季<冬季的特征,人类活动可能是其主要来源。 相似文献
44.
HPLC方法分析表层海水叶绿素a含量 总被引:6,自引:0,他引:6
以ODS-2 Spherisorb C18反相HPLC分析柱,流动相A(体积比为80:20的甲醇,pH=7.2的0.5mol/L乙酸氨水溶液,0.01%BHT W:V)、流动相B(87.5:12.5的乙腈:水,0.01%BHT W:V)和流动相C(乙酸乙酯),梯度洗脱,流速为1mL/min,紫外检测波长为436nm,HPLC方法分析辽东湾表层海水中的叶绿素a含量。该方法灵敏度高,检测限为10ng/L。对HPLC、荧光法和分光光度法的叶绿素a分析结果进行了比较。 相似文献
45.
Joo Serdio Helena Coelho Snia Vieira Snia Cruz 《Estuarine, Coastal and Shelf Science》2006,68(3-4):547
The migratory response of intertidal microphytobenthos to changes in irradiance was studied on undisturbed estuarine sediments. Two non-destructive optical techniques were used to trace variations in vivo of surface biomass: PAM fluorometry, for measuring the minimum fluorescence level (Fo); and spectral reflectance analysis, for quantifying the normalized difference vegetation index (NDVI). Following the formation of a dense biofilm at the surface, replicated sediment samples were simultaneously exposed to six different irradiance levels, ranging from 50 to 1500 μmol m−2 s−1, during a period of 120 min. The migratory photoresponse of the biofilms was characterised by constructing biomass vs. light curves (BLC), relating the accumulation of microalgal biomass after that period (estimated by Fo or NDVI) to the irradiance level incident on the surface. BLCs allow characterising the main features of the migratory photoresponse of intact biofilms. Typical BLC showed a clear biphasic pattern, with an increase in microalgal accumulation under irradiances below 100 μmol m−2 s−1, maximum values under 100–250 μmol m−2 s−1, and a gradual decrease of surface biomass under higher irradiances, indicating a strong photophobic downward migratory response. Similar BLC patterns were obtained when measuring Fo or NDVI. The construction of BLCs for biofilms from intertidal sites with distinctive sediment characteristics and diatom taxonomic composition allowed to detected significant differences in the migratory photoresponse. Biofilms from a muddy sediment exhibited considerably larger amplitude in the migratory photoresponse than the biofilms from a sandy mud site, especially under high irradiances. The photophobic migratory response to high light was found to vary among diatom species, particularly in the case of the biofilms from the muddy sediments. 相似文献
46.
原子荧光光谱法测定化探样品时有机质对As,Sb,Bi的干扰 总被引:1,自引:0,他引:1
通过研究黑龙江省森林沼泽景观区有机水系沉积物(泥炭)、土壤中As,Sb,Bi的测定结果,发现样品中的有机质对王水消解氢化物原子荧光法测定上述元素存在极大的干扰,提出采用低温(<450℃)灰化处理可完全消除干扰。对比研究还发现,过去森林沼泽景观区的区域化探扫面资料中的As,Sb,Bi数据存在问题,应专门对其进行评价研究。 相似文献
47.
48.
微波辅助提取-氢化物发生原子荧光光谱法测定土壤中无机砷 总被引:1,自引:1,他引:1
建立了微波辅助提取-氢化物发生原子荧光光谱法测定土壤中无机砷的分析方法。用正交试验设计结合单因素试验优化了样品粒度、提取温度、提取时间、固液比等微波提取条件,研究了共存离子对无机砷测定的干扰情况。方法的线性范围为0.25~40.0μg/g,无机砷的检出限为0.05μg/g,样品加标回收率为92.9%~105.0%。方法的精密度(RSD,n=11)为0.3%。与水浴提取法相比,微波辅助提取法具有快速、高效的优势。方法已用于分析3个不同产地有代表性土壤中无机砷含量。 相似文献
49.
An in vivo three-dimensional fluorescence method for the determination of algae community structure was developed by parallel factor analysis(PARAFAC) and CHEMTAX. The PARAFAC model was applied to fluorescence excitation-emission matrix(EEM) of 60 algae species belonging to five divisions and 11 fluorescent components were identified according to the residual sum of squares and specificity of the composition profiles of fluorescent. By the 11 fluorescent components, the algae species at different growth stages were classified correctly at the division level using Bayesian discriminant analysis(BDA). Then the reference fluorescent component ratio matrix was constructed for CHEMTAX, and the EEM–PARAFAC–CHEMTAX method was developed to differentiate algae taxonomic groups. The correct discrimination ratios(CDRs) when the fluorometric method was used for single-species samples were 100% at the division level, except for Bacillariophyta with a CDR of 95.6%. The CDRs for the mixtures were above 94.0% for the dominant algae species and above 87.0% for the subdominant algae species. However, the CDRs of the subdominant algae species were too low to be unreliable when the relative abundance estimated was less than 15.0%. The fluorometric method was tested using the samples from the Jiaozhou Bay and the mesocosm experiments in the Xiaomai Island Bay in August 2007. The discrimination results of the dominant algae groups agreed with microscopy cell counts, as well as the subdominant algae groups of which the estimated relative abundance was above 15.0%. This technique would be of great aid when low-cost and rapid analysis is needed for samples in a large batch. The fluorometric technique has the ability to correctly identify dominant species with proper abundance both in vivo and in situ. 相似文献
50.
氯化亚锡还原冷蒸汽无色散原子荧光光谱法测定痕量汞,采用硫酸、双氧水、王水逐次加入低温分析样品,可以保证样品分解完全又可避免汞的损失。汞的检出限为6.0×10~(-10)g,精密度RSD%=4.1。该方法操作简便,快速、准确、费用低,可应用于大批量地球化学样品的分析。 相似文献