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11.
Organic biomarker and nannofossil assemblages are used in combination with sedimentary petrology to identify the role of diagenesis for the formation of a rhythmic calcareous succession. A record from the Early Pliocene of the Maldives (Ocean Drilling Program, ODP Leg 115) is presented containing precession and eccentricity cycles expressed as variable aragonite content. Additional sub‐Milankovitch cycles are caused by rhythmic precipitation of calcite cement in the lower part of the interval. Comparison with palaeo‐productivity indicators (nannofossils, chlorin, total organic carbon) suggests that cementation occurs preferentially in intervals characterized by increasing or decreasing productivity. The coupled variability in productivity and carbonate diagenesis is attributed to the effect of organic matter degradation in the sediment. The observed combination of primary and diagenetic factors hampers the interpretation of the cyclicity on Milankovitch and sub‐Milankovitch scales. Diagenetically stable proxies for palaeo‐productivity, such as nannofossil assemblage data, were used to distinguish between palaeoclimate and diagenetic influences. 相似文献
12.
Lallan Prasad Gupta Hodaka Kawahata Mio Ltakeuchi Hidekazu Ohta Yoshiro Ono 《Resource Geology》2006,56(2):191-196
Abstract. Oxidation and reduction processes can influence extent of leaching of elements from solid waste. Three samples of municipal solid waste combustion fly ash were subjected to oxidizing and reducing conditions in order to evaluate leaching of elements in the Milli-Q water and fly ash (liquid to solid ratio, 100) mixtures. Although the oxidizing and reducing conditions were applied for 6 hours only, elements like Cs, Li, Mg, Sb, Tl and V leached more under oxidizing condition than under reducing condition in the case of all three ash samples. Cadmium, Pb and Zn leached more from all samples under reducing condition than under oxidizing condition. Leaching of other elements like Al, Ba, Cr, Cu, Ni and Rb was inconsistent with oxidizing or reducing conditions and varied from sample to sample, suggesting that factors other than redox may be more important in controlling leaching of these elements. Strong acid neutralization capacity of the fly ash samples let the pH vary within a narrow range, and thus severely limited the extent of leaching during the course of the experiment. Lead and Zn were the most sensitive while K and Na were the least sensitive to changes in redox conditions. 相似文献
13.
Samantha R. Cook John M. Chamock Andrew Parker 《中国地球化学学报》2006,25(B08):247-247
The mainly 19th Century canal system in the UK, largely managed by British Waterways, has been increasingly brought back into operation over the last few decades, and is now widely used for both leisure, and, increasingly, transport. Both initial and routine dredging of the canal sediment is carried out and these sediments are generally disposed of to land. Because many of the canals were connected with primary industries, their sediments can locally be significantly contaminated with heavy metals, and the behaviour of these metals under differing redox conditions, when introduced into a new environment (i.e., on land) is of importance for environmental risk-assessment purposes. Canal sediments are often rich in sulfidic mineral phases, and we have attempted to quantify the influence of these sulfidic phases on the release and retention of metals in dredged canal sediments, using a combination of traditional chemical techniques (e.g. sequential extraction) and X-ray absorption spectroscopy (XAS). Sediment samples have been collected from urban fresh-water canals, one in the British Midlands and one in Northern France. It appears from XAS that Cd is largely associated with oxygen in air-dried sediment, and with sulphur in vacuum-dried sediment. 相似文献
14.
Subsidence due to peat oxidation and impact on drainage infrastructures in a farmland catchment south of the Venice Lagoon 总被引:1,自引:0,他引:1
Large agricultural areas reclaimed in the past century, south of the Venice Lagoon, have experienced significant land subsidence
due to oxidation of peat organic soils. This has exposed the region to flood hazard particularly during severe storms and
has contributed to increase the marginal management cost of the infrastructures (ditches, levees, pumping stations) designed
to operate the drainage system. Direct measurements and indirect evidence from the channel network suggest a land settlement
between 1.5 and 2 m over the past 70 years. This paper provides an overview of the problem with important information on its
most recent evolution. 相似文献
15.
16.
Warren J. de Bruyn Mike Harvey Jill M. Cainey Eric S. Saltzman 《Journal of Atmospheric Chemistry》2002,41(2):189-209
Atmospheric dimethyl sulfide (DMS) and sulfur dioxide (SO2) concentrations were measured at Baring Head, New Zealandduring February and March 2000. Anti-correlated DMS and SO2 diurnalcycles, consistent with the photochemical production of SO2 from DMS, were observed in clean southerly air off the ocean. The data is used to infer a yield of SO2 from DMS oxidation. The estimated yields are highly dependent on assumptions about the DMS oxidation rate. Fitting the measured data in a photochemical box model using model-generated OH levels and the Hynes et al. (1986) DMS + OH rate constant suggests that theSO2 yield is 50–100%, similar to current estimates for the tropical Pacific.However, the observed amplitude of the DMS diurnal cycle suggests that the oxidation rate is higher than that used by the model, and therefore, that theSO2 yield is lower in the range of 20–40%. 相似文献
17.
Annealing at 400?T?600 °C (40?P?60 MPa and HM buffer-controlled f(O2)) of tourmalines synthesised at the same T and P with NNO buffer induces an oxidation of Fe2+ into Fe3+ in some Y sites only (Mössbauer Spectroscopy data). Annealing in the same conditions of natural tourmalines is consistent with these results. FTIR spectroscopy shows that oxidation of Fe2+ into Fe3+ is charge-balanced by deprotonation of the external OH(3) groups. To cite this article: Y. Fuchs et al., C. R. Geoscience 334 (2002) 245–249. 相似文献
18.
19.
光催化氧化法处理难降解废水的研究进展 总被引:8,自引:3,他引:8
综述了光催化氧化处理难降解废水的研究现状及发展趋势。介绍了影响光催化氧化反应速率的因素及光催化氧化法在处理难降解废水中的应用。 相似文献
20.
通过对近几年来十红滩地区铀矿勘查资料及找矿成果的综合研究,系统阐述了吐哈盆地西南缘十红滩矿床的地质构造、含矿岩系沉积环境、砂体分布、层问氧化带发育特征等铀成矿条件,对矿区南、北矿带控矿层间氧化带分带性、矿体形态、规模、空间展布、铀存在形式、成矿年龄及铀成矿规律进行了详细研究。进一步总结了区域砂岩型铀成矿条件和找矿前景,指出吐哈盆地西南缘随着找矿工作进展可望成为大型地浸砂岩型铀资源基地,并对指导天山造山带及类似地区地浸砂岩型铀矿找矿具有重要意义。 相似文献