Neoarchean and Rhyacian TTG-Sanukitoid suites in the southern São Francisco Paleocontinent,Brazil: Evidence for diachronous change towards modern tectonics

The southern portion of the Sao Francisco Palaeocontinent in Brazil is denoted by Archean nuclei and Paleoproterozoic magmatic arcs that were amalgamated during Siderian to Orosirian orogenic processes(ca.2.4-2.1 Ga).New isotopic U-Pb in zircon and Sm-Nd whole rock combined with major and trace element composition analyses constrain the crystallization history of the Neoarchean Piedade block(at ca.2.6 Ga) and the Paleoproterozoic Mantiqueira Complex(ca.2.1-1.9 Ga).These therefore display quite different magmatic histories prior to their amalgamation at ca.2.05 Ga.Sm-Nd and Rb-Sr isotopes imply a mixed mantle-crustal origin for the samples in both units.A complete Palaeoproterozoic orogenic cycle,from subduction to collision and collapse,is recorded in the Piedade Block and the Mantiqueira Complex.Rhyacian to Orosirian subduction processes(ca.2.2-2.1 Ga) led to the generation of coeval(ca.2.16 Ga)TTG suites and sanukitoids,followed by late(2.10-2.02 Ga) high-K granitoids that mark the collisional stage.The collisional accretion of the Mantiqueira Complex against the Piedade Block at 2.08-2.04 Ga is also recorded by granulite facies metamorphism in the latter terrane,along the Ponte Nova suture zone.The collisional stage was closely followed by the emplacement of within-plate tholeiites at ca.2.04 Ga and by alkaline rocks(syenites and enriched basic rocks) at ca.1.98 Ga,marking the transition to an extensional tectonic regime.The discovery of two episodes of TTG and sanukitoid magmatism,one during the Neoarchean in the Piedade Complex and another during the Rhyacian in the Mantiqueira Complex,indicates that the onset of subduction-related melting of metasomatized mantle was not restricted to Neoarchean times,as generally believed,but persisted much later into the Paleoproterozoic.     

Petrogenesis and tectonic implications of Indosinian granitoids from Western Qinling Orogen,China:Products of magma-mixing and fractionation

The Western Qinling Orogen(WQO) is characterized by voluminous distribution of Indosinian granitoids,the formation of which provides an important window to unravel the geochemical and geodynamic evolution and associated metallogeny.Here we investigate a group of intrusions termed "Five Golden Flowers" based on petrological,geochemical,zircon U-Pb geochronological and Lu-Hf isotopic studies on the granitoids and their mafic microgranular enclaves(MMEs).Our results show that these intrusions are genetically divided into two types,namely,magma-mixing and highly fractionated.The Jiaochangba,Lujing,Zhongchuan,and Luchuba granitoids are biotite monzogranites(220±0.8 Ma to 217±2.6 Ma) with abundant coeval MMEs(220±.1 Ma to 217±2.7 Ma).The rocks contain moderate to high SiO_2,high MgO,Rb,Sr,Ba,and Th contents,but low TiO_2,P_2 O_5,and Sc values,A/CNK of 1.1,and a range of ε_(Hf)(t) values of-11.7 to +2.23 with corresponding T_(DM2)values of 1967-1228 Ma.The MMEs possess K-feldspar megacrysts,abundant acicular apatites,and show lopsided textures.They have lower SiO_2,Al_2 O_3,and Th contents,but higher MgO,TiO_2,and Sc,with ε_(Hf)(t) values of-18.0 to +3.18 and T_(DM1) of 849-720 Ma.The data indicate that the MMEs were derived from a magma sourced from the enriched lithospheric mantle.We suggest that these host granitoids were produced by partial melting of latePaleoproterozoic to early-Mesoproterozoic lower crust with the involvement of Neoproterozoic SCLM-derived mafic magmas.The Baijiazhuang pluton is dominantly composed of leucogranite(muscovite granite and twomica monzogranite,216±1.5 Ma) without MMEs.The rocks are peraluminous with high A/CNK(1.06-1.27).Compared with the other four granitoids,the Baijiazhuang leucogranite shows higher SiO_2 content,markedly lower concentrations of TiO_2,MgO,Al_2 O_3,CaO,and Fe_2 O_3~T,and lower LREE/HREE and(La/Yb)N values.These leucogranites are also rich in Rb,Th,and U,and display marked depletions in Ba,Sr,Ti,and Eu,indicating that they experienced significant fractionation.Zircon ε_(Hf)(t) values(-10.2 to-3.27) and T_(DM2)(1868-1424 Ma),as well as the Nb/Ta and K_2 O/Na_2 O values are similar to the other four granitoids,indicating that they are likely to have been derived from a similar source;with sediments playing only a minor role in the magma generation.The low contents of Yb and Y suggest that their partial melting was controlled by garnets and micrographic texture of K-feldspar reflects high-temperature melting through undercooling.Based on the above features,we infer that the Baijiazhuang leucogranite likely represents the product of high degree fractionation of the I-type biotite monzogranite magma which generated the other four granitoids at relatively high temperatures,within magma chambers at mid-crust depths.We propose that the granitoid suite was formed in the transitional setting from synto post-collision during the collisional orogeny between the SCB and NCB,following break-off of the subducted South China Block lithosphere during 220-216 Ma.     

江西永平铜矿花岗质岩石的岩石结构、地球化学特征及其成矿意义

江西永平铜矿位于华南怀玉山-北武夷山铜铅锌多金属成矿带内,是赣东北地区除了德兴铜矿外的另一个大型铜矿基地.该矿区存在两种类型的花岗质岩石,一种是花岗岩;另一种是英安斑岩.英安斑岩具有典型斑状结构和石英眼结构,而花岗岩则具有单向固结结构.在化学成分上,两者属于高钾的钙碱性系列岩石,英安斑岩贫硅、富Al、Fe、Mg、Ca,以及具有较大的Na2O/K2O(0.02～0.64)等特点;而花岗岩富硅、贫Al、Ca,以及富碱和具有较小的Na2O/K2O(0.02～0.03)等特点.两种类型的岩石具有一致的REE配分曲线.它们均富集大离子亲石元素(Ba、Rb、K),亏损高场强元素(Th、Nd、Ta、Ti)以及元素Sr和P,显示了与俯冲作用有关的岩浆作用.在结构和化学成分上,花岗岩则类似于美国Climax斑岩钼(铜)矿成矿斑岩的性质(如具有单向固结结构、较高的分异指数、富Si、贫Al、Ca、富Na2O K2O以及K2ONa2O).与英安斑岩有关的蚀变作用主要有夕卡岩化、黑云母化、白云母化、绿泥石化和萤石化,而与花岗岩有关的蚀变作用主要是白云母化和萤石化;相应地,与英安斑岩有关的成矿作用主要为铜,而与花岗岩有关的成矿作用则主要为钼.2件辉钼矿样品的Re-Os年龄分别为156.7±2.8Ma和155.7±3.6M8,表明与花岗岩有关的钼成矿作用发生在156Ma左右.本文认为,永平铜钼矿的成矿地球动力学背景应是由挤压向伸展的转换环境.     

辽宁阜新盆地中、新生代构造转折及其地质意义

通过对阜新盆地构造运动、岩浆活动、沉积充填、成矿作用的总结,识别出阜新中、新生代发生的三次构造转换,即挤压—伸展,伸展—挤压,挤压—伸展,其时限分别是(135~120)Ma、100Ma和40Ma。深部岩石圈的构造变动是盆地表壳层地质作用的根本控制因素;盆地内的岩浆岩、沉积充填以及成矿作用是地球深部作用的浅部响应。     

宝鸡古土壤层S7和黄土层L8的天然剩磁锁定深度初探

详细的古地磁及岩石磁学研究表明磁铁矿和赤铁矿是宝鸡古土壤层S7和黄土层L8的特征剩磁的主要载磁矿物,在稳定的正反极性期间,这两种磁性矿物携带的剩磁方向完全一致。然而,在地磁漂移事件或者松山-布容（M-B）极性转换的过程中,这两种载磁矿物有时携带的剩磁方向不同。高分辨率的磁性地层结果证实宝鸡古土壤层S7和黄土层L8能记录300500年的短期地球磁场极性倒转事件。经与日本大阪湾高分辨率的海洋沉积物中记录的同期短期极性倒转事件相比,估算宝鸡剖面土壤层S7和黄土层L8的天然剩磁锁定深度小于58cm。     

咸淡水过渡带化学过程的试验研究

通过不同比例的咸淡水混合作用及水岩作用的室内模拟实验,对咸淡水过渡带的水文地球化学作用进行了研究。在咸淡水混合作用的过程中,海水与淡水的混合是以机械混合为基础的复杂的化学过程,混合液的总碱度和pH值均显著上升,而电导率明显下降,方解石和石膏的饱和指数均明显增大,而Pco2降低。在水岩作用的过程中,混合液的pH值、总碱度和电导率均显著上升,石膏的饱和指数由～1．06～-0．71升高至-0．86～-0．50,石膏发生溶解;方解石的饱和指数由0．69～1．07降至0.00-0．10,方解石发生沉淀．最后接近平衡状态。     

Behavior of sand–rubber particle mixtures: experimental observations and numerical simulations

A series of laboratory experiments and numerical simulations are conducted to explore the characteristics of mixtures composed of sand and rubber particles of the same median diameter. The mixtures are prepared with different volumetric sand fractions (sf = V_sand/V_total). The experiment focuses on assessing the strain level on the characteristics of the mixture with the volume fraction of each component. Numerical simulations using the discrete element method are performed to obtain insight into the microscale behavior and internal mechanism of the mixtures. The experimental results show that the behavior of the mixtures is dependent on the relative sand and rubber particles composition with variation in the strain levels. The numerical simulation reveals the effect of the soft rubber particle inclusion in the mixture on the micromechanical parameters. In low sand fraction mixtures, a high shear stress along the contact is mobilized, and the stress state is driven to a more anisotropic condition because of the relatively high particle friction angle of the rubber. The rubber particles play different roles with the strain level in the mixture, including increasing the coordination number and controlling plasticity of the mixture in a small strain, preventing buckling of the force chain in an intermediate strain, and leading to contractive behavior in a large strain. Copyright © 2014 John Wiley & Sons, Ltd.     

Vibrational spectroscopy of beta-eucryptite (LiAlSiO<Subscript>4</Subscript>): optical phonons and phase transition(s)

The structural behavior of -eucryptite (LiAlSiO₄) has been investigated using infrared (IR) spectroscopy over a temperature range of 20 to 900 K and FT-Raman spectroscopy at room temperature. IR reflectance measurements show that -eucryptite possesses high reflectivity in the far-IR region, as is consistent with its reported superionic conductivity along the c-axis. On heating, the Li-related IR bands near 246 and 300 cm^–1 (with A₂ symmetry) broadened and weakened dramatically, presumably as a result of Li⁺ positional disordering along the structural channels parallel to c. The disordering process appears to induce a framework distortion, as is evidenced by the broadening of some vibrations of Si(Al)–O with increasing temperature. A change in slope in the temperature dependence of the phonon frequency near 300 cm^–1 and the linewidth of the 760 cm^–1 band at 715 K indicates that Li becomes completely disordered above this temperature. In addition, the temperature dependence of the linewidth for the 760 cm^–1 band exhibits an additional change in slope at 780 K, implying the existence of an intermediate state within this temperature range. The detailed structure of this intermediate phase, however, needs further study. Our IR data provide no indication of structural changes between room temperature and 20 K.     

Fluvial style changes during the last glacial-interglacial transition in the middle Tisza valley (Hungary)

The Weichselian Late Pleniglacial, Lateglacial and Holocene fluvial history of the middle Tisza valley in Hungary has been compared with other river systems in West and Central Europe, enabling us to define local and regional forcing factors in fluvial system change. Four Weichselian to Holocene floodplain generations, differing in palaeochannel characteristics and elevation, were defined by geomorphological analysis. Coring transects enabled the construction of the channel geometry and fluvial architecture. Pollen analysis of the fine-grained deposits has determined the vegetation development over time and, for the first time, a bio(chrono)stratigraphic framework for the changes in the fluvial system. Radiocarbon dating has provided an absolute chronology; however, the results are problematic due to the partly reworked character of the organic material in the loamy sediments. During the Late Pleniglacial, aggradation by a braided precursor system of the Tisza and local deflation and dune formation took place in a steppe or open coniferous forest landscape. A channel pattern change from braided to large-scale meandering and gradual incision occurred during the Late Pleniglacial or start of the Lateglacial, due to climate warming and climate-related boreal forest development, leading to lower stream power and lower sediment supply, although bank-full discharges were still high. Alternatively, this fluvial change might reflect the tectonically induced avulsion of the River Tisza into the area. The climatic deterioration of the Younger Dryas Stadial, frequently registered by fluvial system changes along the North Atlantic margin, is not reflected in the middle Tisza valley and meandering persisted. The Lateglacial to Holocene climatic warming resulted in the growth of deciduous forest and channel incision and a prominent terrace scarp developed. The Holocene floodplain was formed by laterally migrating smaller meandering channels reflecting lower bank-full discharges. Intra-Holocene river changes have not been observed.     

Ductile-brittle transition in pre-Alpine amphibolite facies mylonites during evolution from water-present to water-deficient conditions (Mont Mary nappe, Italian Western Alps)

In the Austroalpine Mont Mary nappe (Italian Western Alps) discrete zones of mylonites–ultramylonites developed from coarse-grained, upper amphibolite facies metapelites of pre-Alpine age. The syn–mylonitic mineral assemblage is quartz–biotite–muscovite–plagioclase–garnet–sillimanite–ilmenite–graphite, and formed via the model hydration reaction: Grt₁+Kfs+H₂O=Bt₂+Ilm₂+Qtz+Ms± Sil .Grain-size reduction of about three orders of magnitude was accompanied by extensive recrystallization of all minerals except sillimanite, and by compositional changes of garnet and biotite. Deformation took place at temperatures of 510–580  °C under low-pressure conditions (0.25–0.45 GPa) and corresponds to the latest stages of pre-Alpine metamorphic evolution. The pre-Alpine mylonitization conditions were close to the brittle-ductile transition, as indicated by syn–mylonitic generation of pseudotachylytes and high differential stress inferred from quartz grain-size piezometry. The brittle-ductile behaviour at a relatively high temperature, and the absence of annealing textures in quartz aggregates, are suggestive of water-deficient conditions during mylonitization. These were accomplished through progressive consumption of water by syn–kinematic hydration reaction and by adsorption onto the greatly increased grain boundary area resulting from dynamic recrystallization.