云南建水水草冲铜矿矿床地质特征及成矿物质来源

本文通过研究云南建水水草冲铜矿地质特征、围岩玄武岩和矿石矿物的微量元素、S、C、O同位素的组成,示踪了该矿床的成矿物质来源和性质。研究结果表明,云南建水水草冲铜矿位于滇东南哀牢山变质体北侧,容矿围岩为峨眉山玄武岩,矿体受北东向逆断层及其次级断裂控制,延深大于延长,形状不规则,矿体内多夹灰岩角砾及矿化玄武岩角砾,矿石矿物主要为黄铜矿,矿化蚀变以硅化、碳酸盐化、绿泥石化为主。水草冲铜矿黄铜矿与黄铁矿稀土元素具有相同的稀土元素组成与含量,ΣREE平均为1.901×l0-6,富集轻稀土元素,轻重稀土元素比(LREE/HREE)平均为8.188,（La/Yb）N值平均为10.259;δEu值平均为0.977;Ce呈现弱负异常,δCe值平均为0.808。黄铁矿中的Co/Ni比值为0.835,显示水草冲铜矿床为中温热液矿床;黄铁矿的Y/Ho比值平均为38.23,表明水草冲铜矿床的成矿流体为混合来源。结合黄铁矿的稀土微量元素特征,推断水草冲铜矿床的成矿流体是Cl多于F的流体。S的来源复杂,黄铁矿δ34SCDT（‰）的变化范围（18.3~29.4）与海水硫酸盐(海相蒸发岩)的δ34S值接近或略低;黄铜矿δ34SCDT（‰）变化范围是-0.5~10.1,表明有深部硫的参与。δ13C V-PDB（0.9‰~2.6‰）,δ18O V-SMOW（14.3‰~15.9‰）反映了方解石流体可能为热液循环萃取沉积岩地层混合形成。综上,推测成矿物质为后期构造热液萃取围岩（玄武岩和灰岩等）所得,其中铜主要来自于玄武岩本身,而硫的来源以地层硫为主。     

成藏期砂岩孔隙度对油气分布的控制作用——以东营凹陷牛庄洼陷沙三中亚段岩性油藏为例

在具有相同储集砂体和相似断层输导情况下,牛庄洼陷沙三中亚段砂岩体油藏长期存在以下难以解释的现象：1）现今砂岩孔隙度分布与油气分布不一致,高孔隙砂岩不含油而低孔隙砂岩含油;2）相同物性砂岩有的含油而有的不含油,含油砂体现今物性接近,但含油级别却存在很大差异。本文从古孔隙度恢复方面分析了牛庄洼陷西部地区沙三中砂岩储层在成藏期的储集条件,并探讨了成藏期储层临界孔隙度。研究发现：1）虽然现今储层物性下限很低,部分砂岩已经致密化,但成藏期的古孔隙度分布在18%～25%范围内,远大于成藏期临界孔隙度13.9%。但由于埋藏过程的差异导致砂岩储层后期减孔幅度不同,因而现今储层物性不能反映成藏期储层物性,成藏期孔隙度高并不能代表现今孔隙度高;2）成藏期高孔隙度带与现今油气分布范围高度一致,表明在相似断层输导条件下,由于储层物性级差优势形成油气优势运移通道,导致高孔隙度带砂体含油,因此,沙三中亚段岩性油藏富集在成藏期高孔隙带中,成藏期砂岩古孔隙度是油气成藏的重要控制因素,而现今砂岩储层高孔隙带在成藏期并不一定高。牛庄洼陷西部地区沙三中亚段储层中具有高古孔隙度的砂岩仍有较大勘探潜力。     

广西苍梧社垌石英脉型钨钼多金属矿床流体演化及来源示踪

广西苍梧社垌矿床是大瑶山隆起南侧新发现的一个大型斑岩-矽卡岩-石英脉型钨钼多金属矿床。本文重点对其中的石英脉型矿床进行了研究,依据脉体穿插关系及矿物共生组合将成矿过程划分为I石英-黄铁矿阶段、II石英-白钨矿-辉钼矿阶段、III石英-多金属硫化物阶段以及IV石英-方解石-萤石阶段,其中II和III阶段为主成矿阶段。从早到晚,均一温度逐渐下降(第一阶段550℃→370℃,第二阶段370℃→330℃,第三阶段330℃→210℃,第四阶段190℃→150℃),流体密度逐渐上升(0.61g/cm3→0.72g/cm3→0.82g/cm3→0.94g/cm3),盐度先升后降(第一阶段5.86%～8.55%NaCleqv,第二阶段4.49%～43%NaCleqv,第三阶段0.53%～46.37%NaCleqv,第四阶段0%～12.85%NaCleqv)。激光拉曼成分分析显示,社垌石英脉型矿床的成矿流体属于H2O-NaCl体系,但是该体系的流体成分在成矿前后发生了较大的变化,反映第I阶段以氧化环境为主,(II、III、)IV阶段则为还原环境。氢氧同位素研究显示成矿流体来自于岩浆水,后期大气降水的加入导致矿质发生沉淀。此外金属硫化物的δ34S组成(-3.8‰～+1.7‰)平均为-0.46‰,接近于零值,也表明为岩浆来源。引起矿质沉淀的主要原因是流体混合导致的温度下降等环境条件的改变。总体而言,社垌石英脉型钨钼多金属矿床的成矿流体主要来自岩浆热液,为中高温、中低盐度、低密度的NaCl-H2O流体体系,钨钼等多金属成矿与区内加里东期岩浆作用密切相关。     

黄土陡坡降雨冲刷试验及其三维颗粒流流-固耦合模拟

针对坡角为70°的黄土边坡,进行2.7 mm/min降雨强度下的室内坡面冲刷试验。根据边坡冲刷破坏的过程特征,将边坡侵蚀方式演变过程归纳为试验初期的片蚀、中期的细沟侵蚀、到后期的切沟侵蚀和坍塌。试验中坡顶处侵蚀强度大于其他部位,当坡面形成上下贯通的切沟之后,水流开始掏蚀沟槽底部土体,随着冲刷的持续,切沟两侧土体强度降低,坡顶土体发生坍塌。以此为基础利用三维颗粒流软件PFC3D对边坡降雨冲刷过程进行流-固耦合模拟,在模拟颗粒大变形的同时得到颗粒运动轨迹、孔隙率、流体单元内流速等重要参数,这些参数的定量变化过程反映了降雨过程中边坡遭受侵蚀程度及水流侵蚀能力的分布规律:坡顶处侵蚀最为强烈、水流侵蚀能力最强,且两者随高度降低呈减小趋势,与室内试验结果一致。     

谱模拟方法在高分辨率地震资料处理中的应用

为了克服地震子波的时变影响,避免复杂的时窗大小选取问题,使得谱模拟方法能更好地适应地震信号是平稳信号的假设条件,将改进S变换与谱模拟方法相结合,形成时频域谱模拟方法。在二维时频谱中进行谱模拟处理,该方法能够克服地震子波随地层深度变化的限制。理论模型及实际资料处理效果显示,时频域谱模拟方法能够有效提高地震分辨率,实现地震资料的高分辨处理。     

异常结构三维综合系统的开发和应用

地球化学异常结构三维综合系统的开发和应用是为了满足地球化学多维异常体系的研究而逐步展开的。应用于深部找矿预测的多维异常结构方法,从钻孔岩芯直接采样,获得了具有真三维属性的地球化学数据,研究者迫切需要在三维场景下对所获三维地球化学数据进行解读和表达。异常结构三维综合系统(3D-MDAS)是利用三维可视化和地质体三维建模技术,在MapGIS K9平台上进行二次开发获得的。本系统实现了地上、地下数据模型的一体化显示,实现了实体模型与属性模型的耦合一体化显示,在此基础上还可以对异常结构进行空间分析,建立三维地球化学找矿模型。笔者详细阐述了三维异常结构3D综合系统的三维建模思路和技术,并用安徽马头矿区的实际应用成果给以说明。     

TGP二维与三维地质预报成果对比

以TGP超前地质预报理论和实际工程资料为基础,运用信息化逻辑方法对TGP二维与三维地质预报成果进行分析对比,主要从预报地质构造的位置、规模、围岩级别和产状四个成果比较二者的相同和不同之处。结果表明,对于隧道前方岩性无明显差异的围岩,二维与三维的地质预报结果基本相同;对于与隧道斜交的地质构造,二维与三维地质预报在构造产状预报结果上相近,但二维地质预报在围岩级别预测方面有利,三维地质预报在规模和位置的预报方面有利;对于与隧道激发炮孔连线一侧边墙不相交的地质构造,二维与三维地质预报结果基本不同,且三维比二维的地质预报结果有利。     

基于最大特征值估计的C3算法及应用

第三代相干体算法(C3算法)具有分辨率高、压制噪声能力强的优点,但是该算法需要计算协方差矩阵的特征值,所以耗时较多。为提高大矩阵特征值分解的运算速度,提出了一种估计最大特征值的快速收敛算法,通过运用A2k矩阵的迹来构造一种收敛速度更快的特征值估计方法,并给出了这种方法的误差估计表达式,实现计算精度的有效控制。文中还讨论了地震数据体边缘补地震道方法,解决了将递推算法应用到平面方向时空间窗越过边界的问题。实例表明,本算法的计算效率明显高于常规的C3算法。     

Geochemistry of mafic rocks and melt inclusions and their implications for the heat source of the 14.0°S hydrothermal field,South Mid-Atlantic Ridge

Fresh rocks sampled from the 14.0°S hydrothermal field of the South Atlantic Ridge can be divided into two categories： olivine-gabbro and basalt. The olivine-gabbro is composed mainly of three types of minerals： olivine, clinopyroxene and plagioclase, while a multitude of melt inclusions occur in the plagioclase phenocrysts of the basalts. We analyzed the whole-rock, major and trace elements contents of the basaks, the mineral chemistry of phenocrysts and melt inclusions in the basalts, and the mineral chemistry of olivine-clinopyroxene-plagioclase in the olivine-gabbro, then simulated magma evolution within the crust using the COMAGMAT program. The whole-rock geochemistry shows that all the basalts exhibit typical N-MORB characteristics. In addition, the mineral chemistry characteristics of the olivine-gabbro （low-Fo olivine, low-Mg# clinopyroxene, high-TiO2 clinopyroxene, low-An plagioclase）, show that strong magma differentiation occurred within the crust. Nevertheless, significant discrepancies between those minerals and phenocrysts in the basalts （high-Fo olivine, high-An plagioclase） reflect the heterogeneity of magma differentiation. High Mg# （-~0.72） melt inclusions isobaric partial crystallization simulations suggest that the magma differentiation occurred at the depth shallower than 13.03 km below the seafloor, and both the vertical differentiation column shows distinct discrepancies from that of a steady-state magma chamber. Instead, a series of independent magma intrusions probably occurred within the crust, and their corresponding crystallized bodies, as the primary high-temperature thermal anomalies within the off-axis crust, probably act as the heat source for the development of the 14.0°S hydrothermal system.     

Correlation analysis and partial least square modeling to quantify typical minerals with Chang＇E-3 visible and near-infrared imaging spectrometer＇s ground validation data

In 2013, Chang＇E-3 program will develop lunar mineral resources in-situ detection. A Visible and Near-infrared Imaging Spectrometer （VNIS） has been selected as one payload of CE-3 lunar rover to achieve this goal. It is critical and urgent to evaluate VNIS＇ spectrum data quality and validate quantification methods for mineral composition before its launch. Ground validation experiment of VNIS was carried out to complete the two goals, by simulating CE-3 lunar rover＇s detection environment on lunar surface in the laboratory. Based on the hyperspectral reflectance data derived, Correlation Analysis and Partial Least Square （CA-PLS） algorithm is applied to predict abundance of four lunar typical minerals （pyroxene, plagioclase, ilmenite and olivine） in their mixture. We firstly selected a set of VNIS＇ spectral parameters which highly correlated with minerals＇ abundance by correlation analysis （CA）, and then stepwise regression method was used to find out spectral parameters which make the largest contri- butions to the mineral contents. At last, functions were derived to link minerals＇ abundance and spectral parameters by partial least square （PLS） algorithm. Not considering the effect of maturity, agglutinate and Fe~, we found that there are wonderful correlations between these four minerals and VNIS＇ spectral parameters, e.g. the abundance of pyroxene correlates positively with the mixture＇s absorption depth, the value of absorption depth added as the in- creasing of pyroxene＇s abundance. But the abundance of plagioclase correlates negatively with the spectral parame- ters of band ratio, the value of band ratio would decrease when the abundance of plagioclase increased. Similar to plagioclase, the abundance of ilmenite and olivine has a negative correlation with the mixture＇s reflectance data, if the abundance of ilmenite or olivine increase, the reflectance values of the mixture will decrease. Through model validation, better estimates of pyroxene, plagioclase and ilmenite＇s abundances are given. It is concluded that VNIS has the capability to be applied on lunar minerals＇ identification, and CA-PLS algorithm has the potential to be used on lunar surface＇s in-situ detection for minerals＇ abundance prediction.