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911.
N. Carrasco J. F. Doussin M. O’Connor J. C. Wenger B. Picquet-Varrault R. Durand-Jolibois P. Carlier 《Journal of Atmospheric Chemistry》2007,56(1):33-55
This article presents a complete study of the diurnal chemical reactivity of the biogenic volatile organic compound (BVOC), 2-methyl-3-buten-2-ol (MBO) in the troposphere. Reactions of MBO with OH and with ozone were studied to analyse the respective parts of both processes in the global budget of MBO atmospheric reactivity. They were investigated under controlled conditions for pressure (atmospheric pressure) and temperature (298 ± 2 K) using three complementary European simulation chambers. Reaction with OH radicals was studied in the presence of and in the absence of NO
x
. The kinetic study was carried out by relative rate study using isoprene as a reference. The rate constant found for this reaction was molecule−1 cm3 s−1. FTIR spectroscopy, DNPH- and PFBHA-derivatisation analyses were performed for reactions with both OH radicals and ozone. In both reactions, the hydroxycarbonyl compound, 2-hydroxy-2-methylpropanal (HMPr) was positively identified and quantified, with a yield of in the reaction with OH, and a yield of and 0.84 ± 0.08 in the reaction with ozone under dry (HR < 1%) and humid conditions (HR = 20%–30%). A primary production of two other carbonyl compounds, acetone , and formaldehyde was found in the case of the dry ozonolysis experiments. Under humid conditions, only formaldehyde was co-produced with HMPr as a primary carbonyl compound, with a yield of . For the reaction with OH, three other carbonyl compounds were detected, acetone , formaldehyde and glycolaldehyde . In addition some realistic photo-oxidation experiments were performed to understand in an overall way the transformations of MBO in the atmosphere. The realistic photo-oxidation experiments were conducted in the EUPHORE outdoor simulation chamber. It was found that this compound is a weak secondary aerosol producer (less than 1% of the carbon balance). But it was confirmed that it is a potentially significant source of acetone, Δ[Acetone]/Δ[MBO] = 0.45. With our experimental conditions ([MBO]0 = 200 ppb, [NO]o = 50 ppb), an ozone yield of Δ[O3]/Δ[MBO] = 1.05 was found. 相似文献
912.
西太平洋深海沉积物古菌多样性垂直分布 总被引:3,自引:2,他引:1
以提取并纯化的西太平洋深海沉积物DNA为模板,利用古菌PCR特异性引物扩增出样品中古菌的16S rDNA片段,构建其克隆文库,建立阳性克隆子RFLP(Restriction Fragment Length Polymor-phism)酶切图谱。据酶切图谱对所获得的120个克隆进行测序,并与数据库中的序列进行比对,从而进行古菌的多样性和系统发育分析。结果表明,沉积物中扩增的16S rDNA古菌序列分别来自泉古生菌(Crenarchaeota)和广古生菌(Euryarchaeota),以Marine Benthic Group B(11.8%)、Marine Benthic Group D(13.6%)、Marine Crenarchaeotic Group(68.69%)为主。少量序列为South African Gold Mine Euryarchaeotic Group(1.07%)、Deep-Sea Hydrothermal Vent Euryarchaeotic Group(1.61%)、UIIB(1.25%)、VALIII(1.79%)、Marine Benthic Group E(0.18%)。以上结果表明西太平洋深海沉积物中有丰富多样的古菌群落。 相似文献
913.
以提取并纯化的西太平洋深海沉积物DNA为模板,利用古菌PCR特异性引物扩增出样品中古菌的16S rDNA片段,构建其克隆文库,建立阳性克隆子RFLP(Restriction Fragment Length Polymor-phism)酶切图谱。据酶切图谱对所获得的90个克隆进行测序,并与数据库中的序列进行比对,从而进行古菌的多样性和系统发育分析。结果表明,沉积物中扩增的16S rDNA古菌序列分别来自泉古生菌(Crenarchaeota)和广古生菌(Euryarchaeota),以Marine Benthic Group B (11.8%)、Marine Benthic Group D (13.6%)、Marine Crenarchaeotic Group (68.69%)为主。少量序列为South African Gold Mine Euryarchaeotic Group (1.07%)、Deep-Sea Hydrothermal Vent Euryarchaeotic Group (1.61%)、UIIB(1.25%)、VALIII(1.79%)、Marine Benthic Group E (0.18%)。以上结果表明西太平洋深海沉积物中有丰富多样的古菌群落。 相似文献
914.
添加剂对KAlSi_3O_8-CaSO_4-CaCO_3体系反应表观活化能的影响 总被引:2,自引:0,他引:2
首先测定了KAlSi3O8-CaSO4-CaCO3体系在不同焙烧条件下钾长石转化成可溶性氧化钾的转化率,进而通过模拟计算表明:KAlSi3O8-CaSO4-CaCO3体系的固相扩散动力学过程符合金斯特林格动力学方程,反应表观活化能Ea为128.92kJ/mol。并着重考察了4种添加剂Na2SO4、Na2SO3、NaCl和NaF对KAlSi3O8-CaSO4-CaCO3体系的影响,结果表明:向体系中分别加入占反应物总质量3%的Na2SO4、Na2SO3、NaCl和1%的NaF后,体系的反应表观活化能Ea从原来的128.92kJ/mol依次下降至87.15、98.71、117.38和126.14kJ/mol,这表明4种添加剂中Na2SO4的效果最好,它能较大程度上降低反应表观活化能,从而降低反应温度和提高固相反应速率。 相似文献
915.
916.
针对中国一些沿海地区地下水超采及由此带来的海水入侵问题,将地表水补给、抽水量及地下水位等相嵌在一起,建立了沿海地区地下水模拟优化管理模型。将人工鱼群算法和基于MODFLOW2000的变密度地下水流及溶质运移模型耦合起来,对沿海地区地下水模拟优化管理模型进行求解。以山东省威海市节水示范区为例,验证模型的有效性和可靠性。结果表明,10、11、12月份抽水量最大,以后至第2年5月份依次是减少的;从区域分布上看,在临海区域1号井处抽水量是3500~1120m3/月,在其它井处是6540~2920m3/月;与现行方案相比,增加总有效供水1990m3,地下水平均水位升高0.29m,海水入侵问题能够得到解决。计算结果合理可行,为沿海地区地下水资源的科学管理和持续利用提供可靠依据。 相似文献
917.
基于中荷合作项目"建立关于荒漠化和粮食保障的中国能量与水平衡监测系统"(CEWBMS),在国家卫星气象中心和国家林业总局的支持下,乾安大孔径闪烁仪于1999年10月安装并正式运行.利用2000-2005年5~9月大孔径闪烁仪(LAS)观测的大气折射指数的结构参数Cn2,采用独立性检验,证实了Cn2的高低与未来32h是否出现降雨(晴雨)存在显著相关关系.结合乾安气象站的有关气象观测数据,初步选择Cn2白天值以及夜间值以Cn2的24 h变量作为预报依据,建立基于Cn2预报未来32h晴雨的预报流程;并利用2006年Cn2的观测数据,依照预报流程对2006年进行了回报预报试验,正确率为42/47. 相似文献
918.
919.
920.
ULRICH HEIMHOFER DANIEL ARIZTEGUI MARC LENNIGER STEPHEN P. HESSELBO DAVID M. MARTILL ARISTOTELES M. RIOS‐NETTO 《Sedimentology》2010,57(2):677-694
The laminated limestones of the Early Cretaceous Crato Formation of the Araripe Basin (North‐eastern Brazil) are world‐famous for their exceptionally well‐preserved and taxonomically diverse fossil fauna and flora. Whereas the fossil biota has received considerable attention, only a few studies have focused on the sedimentary characteristics and palaeoenvironmental conditions which prevailed during formation of the Crato Fossil Lagerstätte. The Nova Olinda Member represents the lowermost and thickest unit (up to 10 m) of the Crato Formation and is characterized by a pronounced rhythmically bedded, pale to dark lamination. To obtain information on palaeoenvironmental conditions, sample slabs derived from three local stratigraphic sections within the Araripe Basin were studied using high‐resolution multiproxy techniques including detailed logging, petrography, μ‐XRF scanning and stable isotope geochemistry. Integration of lithological and petrographic evidence indicates that the bulk of the Nova Olinda limestone formed via authigenic precipitation of calcite from within the upper water column, most probably induced and/or mediated by phytoplankton and picoplankton activity. A significant contribution from a benthonic, carbonate‐secreting microbial mat community is not supported by these results. Deposition took place under anoxic and, at least during certain episodes, hypersaline bottom water conditions, as evidenced by the virtually undisturbed lamination pattern, the absence of a benthonic fauna and by the occurrence of halite pseudomorphs. Input of allochthonous, catchment‐derived siliciclastics to the basin during times of laminite formation was strongly reduced. The δ18O values of authigenic carbonate precipitates (between ?7·1 and ?5·1‰) point to a 18O‐poor meteoric water source and support a continental freshwater setting for the Nova Olinda Member. The δ13C values, which are comparatively rich in 13C (between ?0·1 and +1·9‰), are interpreted to reflect reduced throughflow of water in a restricted basin, promoting equilibration with atmospheric CO2, probably in concert with stagnant conditions and low input of soil‐derived carbon. Integration of lithological and isotopic evidence indicates a shift from closed to semi‐closed conditions towards a more open lake system during the onset of laminite deposition in the Crato Formation. 相似文献