Toward an improved global network for determination of tropospheric ozone climatology and trends

An examination of typical tropospheric ozone variability on daily, monthly, annual and interannual timescales and instrumental precision indicates that the current ozonesonde network is insufficient to detect a trend in tropospheric ozone of 1% per year at the 2 level even at stations with records a decade in length. From a trend prediction analysis we conclude that in order to detect a 1% per year trend in a decade or less it will be necessary to decrease the time between observations from its present value of 3–7 days to 1 day or less. The spatial distribution of the current ozonesonde stations is also inadequate for determining the global climatology of ozone. We present a quantitative theory taking into account photochemistry, surface deposition, and wind climatology to define the effectively sampled region for an observing station which, used in conjunction with the instrumental precision and the above prediction analysis, forms the basis for defining a suitable global network for determining regional and global ozone climatology and trends. At least a doubling of the present number of stations is necessary, and the oceans, most of Asia, Africa, and South America are areas where more stations are most needed. Differential absorption lidar ozone instruments have the potential for far more frequent measurements of ozone vertical profiles and hence potentially more accurate climatology and trend determinations than feasible with ozonesondes but may produce a (fair weather) biased data set above the cloud base. A strategy for cloudy regions in which either each station utilizes both lidars and sondes or each station is in fact a doublet comprised of a near-sea-level lidar and a proximal-mountain-top lidar could serve to minimize this bias.     

大陆岩石圈强度研究

岩石圈强度或有效弹性厚度(Te)控制着岩石圈对长期负载的响应及其演化过程和空间构型,包含丰富的地球动力学信息,对解译地壳、岩石圈乃至地幔介质的力学性质和动力学过程及机理具有重要的科学意义。本文拟回顾从均衡概念的提出至今关于岩石圈强度研究的发展历程,重点从历史角度梳理岩石圈强度研究的沿革脉络、各种方法发展的逻辑关联,并对岩石圈强度与壳幔耦合、岩石圈有效弹性厚度与地震孕震层厚度的关系以及岩石圈有效弹性厚度各向异性等问题进行初步探讨。     

一种基于双通道的水下图像增强卷积神经网络

近年来各国对于海洋生物的保护意识日益强烈,用来监测海洋生物生存状态的水下机器人装备的研发是保护海洋生物资源的关键。水下相机是这类机器人在水下进行海洋生物监测时的光学感知设备。然而水下环境复杂,拍摄到的图像模糊不清,为解决水下图像模糊等问题,提出了一种基于双通道的水下图像增强卷积神经网络。在网络的编码器中采用双通道结构,其中一个通道采用了密集连接和高效通道注意力机制,提取水下图像的细节特征,另一个通道采用多尺度结构,提取原始图像的多尺度语义特征。接着,在网络中引入残差注意力模块和自适应特征融合模块,进一步优化了特征。最后将优化后的特征输入解码器重建出增强后的水下图像。试验表明：提出的网络算法在UIQM指标和Entropy指标上分别为3.005 6和7.654 7,较第二名的算法分别高出0.097 5和0.123 2。     

波致液化粉质土有效应力变化的试验数据分析

海床不稳定性的现象很多都是海底液化引起的。根据之前的研究,粉土在液化之后有效应力会依然存在,关于波浪作用下海床液化之后有效应力变化的研究很少。采用波浪水槽实验,在未液化和液化2种情况下,分别施加不同波高的波浪,对底床各层位土体孔隙水压力进行采集,并对比研究。实验结果表明,液化后有效应力的相对值相对于液化前有很明显的减小,并且在深度上表现出显著的差异性,这种差异性随着波高的增大而减小。当相同深度处同一种波高作用一定时间时,有效应力会出现极大值,然后有效应力会减小。     

1970-2019年黄浦江上游年最高潮位变化及驱动因子

黄浦江年最高潮位变化关系到上海市的防洪安全,本文基于米市渡站1970－2019年年最高潮位、太湖流域降水量等数据,研究了近50 年来黄浦江上游年最高潮位的变化趋势和变异特性、发生频率变化以及潮位变化的驱动因子。结果表明：年最高潮位在1970－2019年总体呈显著上升趋势,上升幅度为81 cm,年均上升1.62 cm。1995年之后出现跳跃式的波动上升,1996－2002年相对1995年之前较大幅度上升,2003－2011年相比1996－2002年出现较明显下降,之后又较大幅度上升。随着潮位升高,各频率对应的最高潮位均较大幅度增加,升高幅度均达0.9 m以上,五十年一遇、百年一遇、千年一遇高潮位分别由1970年条件下的3.77 m、3.81 m、3.94 m升高到2019年条件下的4.71 m、4.75 m、4.92 m。与此同时,相同潮位下的重现期急剧减小,高潮位发生频率大幅度增加。分析认为,年最高潮位升高受气候变化和人类活动的综合影响,1970－1995年主要受降水量变化等气候因素的影响,1996－2019年主要受水利工程、台风频率增加等因素的影响,尤其是太湖流域太浦河等工程的修建起重要作用。     

基于滑动窗口导纳技术反演西太平洋中部岩石圈的有效弹性厚度

西太平洋中部地区是西太平洋板块边缘沟-弧-盆体系构造演化的关键区域,其地质特征与构造演化一直是地学家关注的焦点问题之一。开展岩石圈有效弹性厚度的研究对于认识该区域的形成演化具有重要的科学意义。本文采用滑动窗口导纳技术,并在挠曲模型中考虑了表面荷载和内部荷载同时存在的情况,计算得到该区域的岩石圈有效弹性厚度(Te)。计算结果显示,研究区的Te值整体上为0~50 km,其变化基本上与构造单元相吻合,且与主要的构造边界密切相关。除海底火山具有相对较小的Te值(15~20 km)外,太平洋板块整体上具有较强的岩石圈强度(25~30 km)。马里亚纳海沟和菲律宾海沟的岩石圈强度从外隆起到海沟方向表现为明显的减弱,表明岩石圈由外隆起向海沟发生了弱化。帕里西维拉海盆西部相较于东部具有较弱的岩石圈强度,这可能与海盆的非对称扩张有关。卡罗琳板块的岩石圈整体上表现为相对均一的低Te值特征(<15 km)。欧里皮克海隆、卡罗琳海岭和索罗尔海槽的Te值为3 km,这可能是强烈的火山作用所导致的结果。     

末次盛冰期长江南京段古河槽特征

根据南京长江大桥、三桥、四桥的地质钻孔资料,绘制南京段长江古河槽地质剖面示意图,对拟建南京长江四桥附近的4个钻孔进行了采样分析,从钻孔沉积物样品的14C年代及阶地形成时间可以判断,南京段约-60~-90 m的深槽为末次盛冰期时的长江河槽,钻孔揭示,南京段长江古河槽狭窄陡峭,呈V型,在南京长江大桥附近形成局部深切。     

Numerical Simulation of Water Level Under Interaction Between Runoff and Estuarine Dynamics in Tidal Reach of the Yangtze River

The Yangtze Estuary, the largest estuary in China, is under an obvious interaction between runoff and astronomical tide. The research on the interaction is very important for the exploitation and utilization of water resources in this area. A horizontal 2D hydrodynamic numerical model is established and verified in the present study with the modeling range from Datong to the Yangtze Estuary. Based on the comparison of high water levels under the interaction between different runoff and estuarine dynamics, s...     

DPD比色法测定电解海水产生的有效氯浓度

论文是用DPD(N,N-二乙基-1,4-苯二胺)比色法测定电解海水中的有效氯浓度,并将测定结果与碘量滴定法测定有效氯浓度相比较。此外,对该方法在海水中的实验条件进行了试验。结果得出,在海水环境下,DPD比色法在常温下,波长为550 nm,pH值6.5左右,显色后10 m in内测定。在海水中用此方法测定有效氯浓度的范围在0~2 m g/L,误差在5%以下。     

A laboratory study on capillary sealing efficiency of Iranian shale and anhydrite caprocks

Caprock has the most important role in the long term safety of formation gas storage. The caprocks trap fluid accumulated beneath, contribute to lateral migration of this fluid and impede its upward migration. The rapid upward passage of invasive plumes due to buoyancy pressure is prevented by capillary pressure within these seal rocks. In the present study, two main seal rocks, from the Zagros basin in the southwest of Iran, a shale core sample of Asmari formation and an anhydrite core sample of Gachsaran formation, were provided. Absolute permeabilities of shale and anhydrite cores, considering the Klinkenberg effect, were measured as 6.09 × 10⁻¹⁸ and 0.89 × 10⁻¹⁸ m², respectively. Capillary sealing efficiency of the cores was investigated using gas breakthrough experiments. To do so, two distinct techniques including step by step and residual capillary pressure approaches were performed, using carbon dioxide, nitrogen and methane gases at temperatures of 70 and 90 °C, under confining pressures in the range 24.13–37.92 MPa. In the first technique, it was found that capillary breakthrough pressure of the cores varies in the range from 2.76 to 34.34 MPa. Moreover, the measurements indicated that after capillary breakthrough, gas effective permeabilities lie in range 1.85 × 10⁻²¹ – 1.66 × 10⁻¹⁹ m². In the second technique, the minimum capillary displacement pressure of shale varied from 0.66 to 1.45 MPa with the maximum effective permeability around 7.76 × 10⁻²¹ – 6.69 × 10⁻²⁰ m². The results indicate that anhydrite caprock of the Gachsaran formation provides proper capillary sealing efficacy, suitable for long term storage of the injected CO₂ plumes, due to its higher capillary breakthrough pressure and lower gas effective permeability.