Intergranular diffusion rates from the analysis of garnet surfaces: Implications for metamorphic equilibration

Novel approaches to garnet analysis have been used to assess rates of intergranular diffusion between different matrix phases and garnet porphyroblasts in a regionally metamorphosed staurolite‐mica‐schist from the Barrovian‐type area in Scotland. X‐ray maps and chemical traverses of planar porphyroblast surfaces reveal chemical heterogeneity of the garnet grain boundary linked to the nature of the adjacent matrix phase. The garnet preserves evidence of low temperature retrograde exchange with matrix minerals and diffusion profiles documenting cation movement along the garnet boundaries. Garnet–quartz and garnet–plagioclase boundaries preserve evidence of sluggish Mg, Mn and Fe diffusion at comparable rates to volume diffusion in garnet, whereas diffusion along garnet–biotite interfaces is much more effective. Evidence of particularly slow Al transport, probably coupled to Fe³⁺ exchange, is locally preserved on garnet surfaces adjacent to Fe‐oxide phases. The Ca distribution on the garnet surface shows the most complex behaviour, with long‐wavelength heterogeneities apparently unrelated to the matrix grain boundaries. This implies that the Ca content of garnet is controlled by local availability and is thought likely to reflect disequilibrium established during garnet growth. Geochemical anomalies on the garnet surfaces are also linked to the location of triple junctions between the porphyroblasts and the matrix phases, and imply enhanced transport along these channels. The slow rates of intergranular diffusion and the characteristics of different boundary types may explain many features associated with the prograde growth of garnet porphyroblasts. Thus, minerals such as quartz, Fe‐oxides and plagioclase whose boundaries with garnet are characterized by slow intergranular diffusion rates appear to be preferentially trapped as inclusions within porphyroblasts. As such grain boundary diffusion rates may be a significant kinetic impediment to metamorphic equilibrium and garnet may struggle to maintain chemical and textural equilibrium during growth in pelites.     

Numerical and theoretical research on stress distribution in the loosening zone of the trapdoor problem

The traditional theory of soil arching effect was developed on the assumption that stress distribution in the loosening zone is uniform. However, because of the deflection of principal stress' direction, the stress distribution in the loosening zone is actually ununiform. For the evaluation of principal stress axis deflection and stress redistribution, a discrete element method numerical model of trapdoor problem is established for the simulation of soil arching effect. Based on the numerical results, an arc shape of major principal stress trajectory and uniform horizontal stress distribution at the same depth of the loosening zone are adopted. An analytical model is raised to estimate the average loosening earth pressure acting on the trapdoor and stress distribution in the loosening zone at a limit state. In addition, comparison studies are carried out between the predictions of the proposed solutions and discrete element method numerical results as well as available model test results, thereby validating the accuracy of the proposed theoretical model. Both numerical and theoretical results indicate that the vertical stress distribution in the loosening zone is obviously ununiform. The load acting in the middle of loosening zone is transferred toward two sides so that the vertical stress distribution in loosening zone is concave.     

Assessing the effectiveness of imperviousness on stormwater runoff in micro urban catchments by model simulation

Imperviousness, considered as a critical indicator of the hydrologic impacts of urbanization, has gained increasing attention both in the research field and in practice. However, the effectiveness of imperviousness on rainfall–runoff dynamics has not been fully determined in a fine spatiotemporal scale. In this study, 69 drainage subareas <1 ha of a typical residential catchment in Beijing were selected to evaluate the hydrologic impacts of imperviousness, under a typical storm event with a 3‐year return period. Two metrics, total impervious area (TIA) and effective impervious area (EIA), were identified to represent the impervious characteristics of the selected subareas. Three runoff variables, total runoff depth (TR), peak runoff depth (PR), and lag time (LT), were simulated by using a validated hydrologic model. Regression analyses were developed to explore the quantitative associations between imperviousness and runoff variables. Then, three scenarios were established to test the applicability of the results in considering the different infiltration conditions. Our results showed that runoff variables are significantly related to imperviousness. However, the hydrologic performances of TIA and EIA were scale dependent. Specifically, with finer spatial scale and the condition heavy rainfall, TIA rather than EIA was found to contribute more to TR and PR. EIA tended to have a greater impact on LT and showed a negative relationship. Moreover, the relative significance of TIA and EIA was maintained under the different infiltration conditions. These findings may provide potential implications for landscape and drainage design in urban areas, which help to mitigate the runoff risk. Copyright © 2015 John Wiley & Sons, Ltd.     

面向WebGL的矢量数据三维绘制技术

矢量数据的叠加显示能够提高三维虚拟地球的表达效果与分析能力。受限于GPU的计算精度,在三维虚拟地球中矢量数据绘制普遍存在抖动现象和深度冲突现象。对基于WebGL的矢量数据三维绘制中计算精度问题进行了分析,提出了使用CPU RTC技术和GPU RTE技术提高顶点变换的精度,使用多视锥渲染算法和深度平面技术解决深度缓存精度问题。实验证明,这几种技术和算法可以有效缓解抖动现象和深度冲突现象导致的视觉干扰,改善了各种尺度和范围的矢量数据在三维地形上的叠加显示效果。     

Selection and quality assessment of Landsat data for the North American forest dynamics forest history maps of the US

Using the NASA Earth Exchange platform, the North American Forest Dynamics (NAFD) project mapped forest history wall-to-wall, annually for the contiguous US (1986–2010) using the Vegetation Change Tracker algorithm. As with any effort to identify real changes in remotely sensed time-series, data gaps, shifts in seasonality, misregistration, inconsistent radiometry and cloud contamination can be sources of error. We discuss the NAFD image selection and processing stream (NISPS) that was designed to minimize these sources of error. The NISPS image quality assessments highlighted issues with the Landsat archive and metadata including inadequate georegistration, unreliability of the pre-2009 L5 cloud cover assessments algorithm, missing growing-season imagery and paucity of clear views. Assessment maps of Landsat 5–7 image quantities and qualities are presented that offer novel perspectives on the growing-season archive considered for this study. Over 150,000+ Landsat images were considered for the NAFD project. Optimally, one high quality cloud-free image in each year or a total of 12,152 images would be used. However, to accommodate data gaps and cloud/shadow contamination 23,338 images were needed. In 220 specific path-row image years no acceptable images were found resulting in data gaps in the annual national map products.     

Upper Maastrichtian shallow marine environments and neoselachian assemblages in North Iberian palaeomargin (Castilian Ramp,Spain)

Upper Maastrichtian deposits formed in a nearshore subtidal environment within the Valdenoceda Formation (Castilian Ramp, North Iberian margin) are described together with two recently found selachian assemblages. Rare earth element concentrations (REE) have been used to assess the degree of taphonomic mixing and reworking, observing that it is minor or non-existent, and differences in degree of preservation and ecologic mixing can be explained by biostratinomic processes. The patterns of REE also helped to obtain a better understanding of the depositional environment, including the diagenetic history from burial to final degree of bone preservation.The fossil assemblages here described are close to that of the late Maastrichtian of Albaina (in the enclave of Condado de Treviño, Burgos), both in the Basque-Cantabrian Region, but their age may be slightly older (early late Maastrichtian). In total, the new assemblages consist of 17 taxa, assigned to 11 genera of shallow-water dwellers combined with individuals from the outer shelf. They represent cosmopolitan taxa (Squalicorax pristodontus, Serratolamna serrata and Rhombodus binkhorsti) together with local species (Rhinobatos echavei, Rhinobatos ibericus). Although there are not significant differences between Albaina and Quintanilla la Ojada faunas, the new assemblages add interesting taphonomic and geochemical information to the few existing uppermost Cretaceous deposits with fossil sharks in southwestern Europe.     

泡沫塑料吸附分离富集-电感耦合等离子体质谱法测定稀土矿石中的镓

采用电感耦合等离子体质谱法(ICP-MS)测定稀土矿石中的镓,高含量的稀土元素会造成严重的质谱干扰。本文采用聚氨酯泡沫塑料在6 mol/L盐酸介质中吸附样品溶液中的镓后,以0.5 mol/L氯化铵水浴加热解脱30 min,镓的吸附-解脱效率超过99%,稀土元素等干扰物质基本不进入解脱液中,即在富集镓的同时实现了镓与基体元素的高效分离,降低了质谱干扰。本方法检出限低(0.022μg/g),经土壤及水系沉积物标准物质验证,镓的测定值与标准值吻合(绝对偏差为0.38%~4.70%),实际稀土矿石样品的加标回收率为94.1%~100.6%,精密度(RSD)低于4%(n=12),可应用于分析一般地质样品以及稀土矿石中的镓。     

地球观测数据共享的发展和趋势

地球观测数据共享是地球科学和相关学科科研活动中非常重要的基础性工作,是对地观测信息生命周期中的重要环节。受到由资源提供者、资源消费者和资源加工者组成的社会生态系统发展变化的影响,共享模式经历了无共享、项目共享、部门共享、社会共享等渐进的4个发展阶段,并呈现出区域差异和阶段差异。地球观测数据共享的概念体系包含数据开放、数据共享、数据互联等不同层次的问题,并受到信息技术等使能技术的驱动。其中开放性代表数据在网络中可被访问的状态,共享性是对于数据重复使用的授权和模式,互联性则是强调可共享数据资源在科学含义上的相互理解。而地球观测数据共享的技术体系则包含数据开放技术、数据共享技术和数据出版与引用技术。目前地球观测领域的数据共享正在经历巨大的文化、政策、技术和应用变革,下一代的地球观测数据设施集中体现了数据的共享和协作,并将呈现国际化、多学科化、标准化、设施化、大数据化和公众社会化等新的技术特征,将对相关科学活动产生重大影响。     

谷歌地球在水井项目信息管理中的应用

利用Excel表建立水井项目信息数据库,设立条件关系编写KML运行程序,利用谷歌地球应用软件阅读水井信息,使水井分布和水井属性在平面内显示。极大的方便了水井项目立项、施工、维护等工作。     

湖南湘潭锰矿的地球化学特征及成矿机制

湘潭锰矿床的锰矿层赋存于新元古代南华系(成冰系)大塘坡组底部含锰黑色页岩中,含锰矿物主要为菱锰矿。湘潭锰矿的Fe/Mn值低,Th/U、V/(V+Ni)和V/Cr值等地球化学指标显示其发育在氧化-次氧化的沉积环境中,暗示菱锰矿并不是由Mn~(2+)和CO_3~(2-)直接沉淀形成的。湘潭锰矿稀土元素含量高,稀土元素配分模式存在轻微的中稀土元素富集,具有明显的Ce正异常,这些特征指示湘潭锰矿含锰矿物是以锰氧化物或氢氧化物的形式沉淀的。同时,锰矿的碳同位素富集碳的轻同位素,说明有机物参与了菱锰矿的形成过程。综合分析表明,湘潭锰矿成矿过程可以分为沉淀和转化两个阶段:在氧化性的水体中,Mn以氧化物或氢氧化物的形式沉淀;在缺氧且富含有机物质的成岩环境中,Mn氧化物或氢氧化物被有机物还原而转化生成菱锰矿。这与华南地区其他几个典型的大塘坡式锰矿的成矿机制一致。