黑龙江饶河枕状玄武岩地质、地球化学特征及其构造属性

为了确定饶河玄武岩的构造属性,在野外地质观察的基础上,对玄武岩进行岩石学研究和地球化学分析。玄武岩具有典型的枕状构造、淬冷边、中空骸晶和鬣刺结构等特征,反映其形成于海底喷发环境。化学分析样品具有高TiO_2、MgO和低Al_2O_3、CaO、P_2O_5、K_2O等特征,富集大离子亲石元素(Rb、Sr和Ba),微量元素蛛网图呈向上隆起形态,稀土元素配分曲线为右倾型(∑LREE/∑HREE为5.8~6.5),无δEu异常(0.92~0.97),表明样品具有洋岛玄武岩特征。主量和微量元素构造环境判别图指示了样品形成于洋岛或板内环境。样品与亚速尔型和夏威夷型洋岛玄武岩地球化学特征对比,表现出明显的夏威夷型洋岛玄武岩特征。岩石源区分析揭示出岩浆具有地幔热柱起源,并有先期交代地幔熔体的混入,岩浆源区还受壳幔循环的影响。研究表明,饶河枕状玄武岩为夏威夷型洋岛玄武岩,形成于洋壳消减阶段的洋中脊轴外板内喷发环境,为饶河地区存在成熟的洋盆提供直接证据。结合区域研究成果,认为饶河地区经历了古太平洋板块的扩张、洋中脊轴外板内地幔柱上涌、洋壳俯冲消减以及向佳木斯地块仰冲增生的构造演化过程。     

Geological evolution and hydrocarbon potential of the salt-cored Hoodoo Dome,Sverdrup Basin,Arctic Canada

The evaporite-cored Hoodoo Dome on southern Ellef Ringnes Island, Sverdrup Basin, was examined to improve the understanding of its structural geological history in relation to hydrocarbon migration. Data from geological mapping, reflection seismic, thermal maturity and detrital apatite (U–Th)/He cooling ages are presented. Five stages of diapirism are interpreted from Jurassic to Recent times:1. 180 to 163 Ma (pre-Deer Bay Formation; development of a diapir with a circular map pattern).2. 163 to 133 Ma (Deer Bay to lower Isachsen formations; development of salt wings).3. 115 to 94 Ma (Christopher and Hassel formations; ongoing diapirism and development of an oval map pattern)4. 79 Ma (Kanguk Formation; reactivation of the central diapir).5. 42 Ma to 65 Ma (Eurekan Orogeny; tightening of the anticline).During phase1, the Hoodoo diapir was circular. During phase 2, salt wings formed along its margin. During phase 3, the Hoodoo Dome geometry evolved into a much larger, elongate, doubly plunging anticline. Phase 4 is inferred from thermochronology data as indicated by a cluster of cooling ages, but the extent of motion during that time is unknown. During Phase 5 the dome was tightened creating approximately 700 m of structural relief. Denudation since the end of the Eurekan Orogeny is estimated to be about 600 m.A one dimensional burial history model predicts hydrocarbon generation from Middle and Late Triassic source rocks between 140 and 66 Ma, with majority of hydrocarbon expulsion between 117 and 79 Ma. Hydrocarbon generation post-dates salt wing formation, so that this trap could host natural gas expelled from Triassic source rocks.     

Influence of urban expansion on the urban heat island effect in Shanghai

The urban heat island (UHI) effect resulting from rapid urbanization is attracting increasing attention among the global scientific community. This research analyzed the relationship between urban expansion and the UHI effect utilizing an integrated approach, including urban land interpretation and retrieving land surface temperature based on remote sensing, and spatial overlay analysis for revealing the relationship for different time periods between 1984 and 2014 in Shanghai, China. The results show that (1) the spatiotemporal changes in UHI are consistent with the expansion of urban land, and rapid urban expansion leads to an expansion of the UHI, in particular along roadways. (2) The mode of urban expansion is an important factor influencing the UHI effect. Urban sprawl (urban expansion in the edge-expansion way) is a form of typical expansion that leads to the rapid increase in the UHI. When the urban compactness ratio is less than 0.15, a compact design can effectively control the expansion rate of the UHI and mitigate its range of influence and intensity. However, when the urban compactness ratio is greater than 0.15, the urban design has a marked influence on the UHI ratio index: a more compact form produces a stronger UHI effect. So, finding an equilibrium between urban compactness ratio and urban expansion rate is good for effective urban management and planning.     

The geothermal formation mechanism in the Gonghe Basin: Discussion and analysis from the geological background

The Gonghe Basin, a Cenozoic down-warped basin, is located in the northeastern part of the Qinghai-Xizang (Tibetan) Plateau, and spread over important nodes of the transfer of multiple blocks in the central orogenic belt in the NWW direction. It is also called “Qin Kun Fork” and “Gonghe Gap”. The basin has a high heat flow value and obvious thermal anomaly. The geothermal resources are mainly hot dry rock and underground hot water. In recent years, the mechanism of geothermal formation within the basin has been controversial. On the basis of understanding the knowledge of predecessors, this paper proposes the geothermal formation mechanism of the “heat source–heat transfer–heat reservoir and caprock–thermal system” of the Gonghe Basin from the perspective of a geological background through data integration-integrated research-expert, discussion-graph, compilation-field verification and other processes: (1) Heat source: geophysical exploration and radioisotope calculations show that the heat source of heat in the basin has both the contribution of mantle and the participation of the earth’s crust, but mainly the contribution of the deep mantle. (2) Heat transfer: The petrological properties of the basin and the exposed structure position of the surface hot springs show that one transfer mode is the material of the mantle source upwells and invades from the bottom, directly injecting heat; the other is that the deep fault conducts the deep heat of the basin to the middle and lower parts of the earth’s crust, then the secondary fracture transfers the heat to the shallow part. (3) Heat reservoir and caprock: First, the convective strip-shaped heat reservoir exposed by the hot springs on the peripheral fault zone of the basin; second, the underlying hot dry rock layered heat reservoir and the upper new generation heat reservoir and caprock in the basin revealed by drilling data. (4) Thermal system: Based on the characteristics of the “heat source-heat transfer-heat reservoir and caprock”, it is preliminarily believed that the Gonghe Basin belongs to the non-magmatic heat source hydrothermal geothermal system (type II2₁) and the dry heat geothermal system (type II2₂). Its favorable structural position and special geological evolutionary history have given birth to a unique environment for the formation of the geothermal system. There may be a cumulative effect of heat accumulation in the eastern part of the basin, which is expected to become a favorable exploration area for hot dry rocks.     

5 000 m深部干热岩钻井方案的技术经济评价

介绍了美国芬顿山和法国苏茨深部干热岩的典型钻井技术方案,并根据我国干热岩钻井基础和地质成藏条件,从钻井深度、井身结构、钻进工艺和钻机设备等方面制定了3种不同的干热岩钻井技术方案,给出了具体技术指标数值。通过计算,对每种方案进行了技术经济评价,结果认为: 大直径钻井方案是技术可靠、经济可行的5 000 m干热岩钻探施工方案。     

全国地热资源调查评价与勘查示范工程进展

地热作为一种清洁能源,在我国经济发展与能源转型过程中正发挥着越来越重要的作用。“全国地热资源调查评价与勘查示范工程”自实施以来,主要开展了京津冀地区地热资源评价以及东南沿海和青藏高原东部干热岩的勘查等工作。这些工作的开展在获得一系列科研突破成果的同时,也解决了大量地热开发的工程问题,积累了大量成果和经验。该文对工程取得的进展及成果进行了总结,对工作开展中出现的问题进行了探讨,可用于指导我国地热资源勘查开发工作。     

印度尼西亚苏门答腊岛Woyla金矿流体包裹体研究及矿床成因分析

印度尼西亚Woyla金矿床位于西苏门答腊地体北段,为一中型规模的金矿床。本文通过对含矿石英脉开展详细的流体包裹体显微测温、成分分析,结合石英的H-O同位素和黄铁矿的S同位素特征分析,结果如下：其中,流体包裹体研究结果表明,含金石英脉中的石英主要发育气液两相包裹体,包裹体均一温度变化范围为152～324℃,集中在200～280℃。盐度为(0.88～6.16)wt%NaCleqv,集中在(1.00～3.00)wt%NaCleqv,成矿流体密度为0.70～0.94g/cm3,平均为0.82g/cm3。成矿压力为9.63～25.84MPa,平均值为18.37 MPa。成矿深度为0.96～2.58km,平均为1.86km,以上显示Woyla矿床成矿流体具有中低温低盐度和浅成的特征。包裹体气、液相成分测定显示气相成分以H2、N2、CO 、CO2、CH4和H2O为主;液相成分中阳离子以Na+、K+和Ca2+为主,阴离子以富SO42-和Cl-为特征,成矿流体属Cl--SO42--Ca2+-K+型。氢氧同位素测定显示成矿流体δ18DV-SMOW=-78.3‰～-92.4‰,δ18OH2O=-3.0‰～-5.5‰,主要来自大气降水,可能有少量岩浆水参与。黄铁矿硫同位素组成为-0.21‰～1.22‰,平均值为0.34‰,说明成矿物质的S具有深源岩浆硫的特征。结合矿床地质特征和成矿流体研究,首次提出Woyla金矿床属典型的低硫型浅成低温热液型金矿床。     

水库运行对漫湾库区洲滩水热交换影响

以澜沧江漫湾水库库区洲滩为研究对象,依据水库运行导致的水位波动特征,同步监测洲滩内部水位、水温变化过程,核算洲滩侧向潜流交换量,建立水温与水位之间的响应关系,分析潜流交换水流路径上溶解氧、溶解性碳素变化。结果表明:水库运行引起洲滩水位周期性波动,侧向潜流交换加强,洲滩水位最大变幅达2.2 m,水库一次蓄泄过程进出洲滩的水量达3 956 m^3,洲滩边缘区潜流交换量为中心区的4~5倍;在涨水过程中,洲滩水温下降,中底层温度梯度较大,而在落水过程中,洲滩水温上升,中表层温度梯度较大;溶解氧、溶解性有机碳和无机碳在河流至洲滩潜流交换路径上同步递减,分别从3.27 mg/L、7.3 mg/L和66.0 mg/L下降至0.17 mg/L、2.4mg/L和40.6 mg/L。水库运行导致的水位波动加强了库区洲滩潜流交换,对河流物质循环产生潜在影响。     

Comparative Study of Acid and Alkaline Stimulants with Granite in an Enhanced Geothermal System

The Enhanced Geothermal System (EGS) is an artificial geothermal system that aims to economically extract heat from hot dry rock (HDR) through the creation of an artificial geothermal reservoir. Chemical stimulation is thought to be an effective method to create fracture networks and open existing fractures in hot dry rocks by injecting chemical agents into the reservoir to dissolve the minerals. Granite is a common type of hot dry rock. In this paper, a series of chemical stimulation experiments were implemented using acid and alkaline agents under high temperature and pressure conditions that mimic the environment of formation. Granite rock samples used in the experiments are collected from the potential EGS reservoir in the Matouying area, Hebei, China. Laboratory experimental results show that the corrosion ratio per unit area of rock is 3.2% in static acid chemical experiments and 0.51% in static alkaline chemical experiments. The permeability of the core is increased by 1.62 times in dynamic acid chemical experiments and 2.45 times in dynamic alkaline chemical experiments. A scanning electron microscope analysis of the core illustrates that secondary minerals, such as chlorite, spherical silica, and montmorillonite, were formed, due to acid-rock interaction with plagioclase being precipitated by alkaline-rock interactions. Masking agents in alkaline chemical agents can slightly reduce the degree of plagioclase formation. A chemical simulation model was built using TOUGHREACT, the mineral dissolution and associated ion concentration variation being reproduced by this reactive transport model.     

Effect of the Dry Ashing Method on Cadmium Isotope Measurements in Soil and Plant Samples

A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ^114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study.