Crystal chemistry of a Mg-vesuvianite and implications of phase equilibria in the system CaO-MgO-Al2O3-SiO2-H2O-CO21

Abstract Chemical analysis (including H₂, F₂, FeO, Fe₂O₃) of a Mg-vesuvianite from Georgetown, Calif., USA, yields a formula, Ca_18.92Mg_1.88Fe³⁺_0.40Al_10.97Si_17.81- O_69.0.1(OH)_8.84F_0.14, in good agreement on a cation basis with the analysis reported by Pabst (1936). X-ray and electron diffraction reveal sharp reflections violating the space group P4/nnc as consistent with domains having space groups P4/n and P4nc. Refinement of the average crystal structure in space group P4/nnc is consistent with occupancy of the A site with Al, of the half-occupied B site by 0.8 Mg and 0.2 Fe, of the half-occupied C site by Ca, of the Ca (1,2,3) sites by Ca, and the OH and O(10) sites by OH and O. We infer an idealized formula for Mg-vesuvianite to be Ca₁₉Mg(MgAl₇)Al₄Si₁₈O₆₉(OH)₉, which is related to Fe^3+-vesuvianite by the substitutions Mg + OH = Fe³⁺+ O in the B and O(10) sites and Fe³⁺= Al in the AlFe site. Thermodynamic calculations using this formula for Mg-vesuvianite are consistent with the phase equilibria of Hochella, Liou, Keskinen & Kim (1982) but inconsistent with those of Olesch (1978). Further work is needed in determining the composition and entropy of synthetic vs natural vesuvianite before quantitative phase equilibria can be dependably generated. A qualitative analysis of reactions in the system CaO-MgO-Al₂O₃-SiO₂-H₂O-CO₂ shows that assemblages with Mg-vesuvianite are stable to high T in the absence of quartz and require water-rich conditions (XH₂O > 0.8). In the presence of wollastonite, Mg-vesuvianite requires very water-rich conditions (XH₂O > 0.97).     

单元刚度矩阵的几何量分析

本文利用向量和矩阵的运算推导了单元刚度矩阵的几何量表示,分析了受三角形单元和矩形单元几何形状影响的单元刚度矩阵的性质,并将有限元网格与总体刚度矩阵相联系,直接说明了合理剖分区域Ω的基本原则。     

基于MICAPS 4的精细化天气预报平台设计及应用

基于气象信息综合分析处理系统第4版(Meteorology Information Comprehensive Analysis Process System4,MICAPS 4)的精细化天气预报平台的设计与应用。从我国精细化气象格点预报业务需求出发,介绍了精细化预报系统的总体组织结构和数据流程,基于MVVM模式的总体架构设计、功能设计以及实现。平台采用高性能的分布式内存对象缓存技术,提高了系统运行效率;采用模型视图分离,将数据逻辑与用户界面剥离,增强其可扩展性,更便于省级本地化应用;开发了要素场协调性处理功能,集成了降水、温度等客观预报算法,并提供丰富的主/客观交互工具。目前,该平台已在业务中应用,为全国精细化预报业务提供了重要支撑。     

金矿复杂地层金刚石取心钻头选型试验研究

金矿复杂地层金刚石钻进存在岩石坚硬、地层打滑、漏失等问题,影响钻头寿命和钻进效率。在山东招远某金矿勘探中,通过对3个单位制造的金刚石钻头进行现场对比试验研究,证明JBD-75S仿生金刚石钻头在提高钻头寿命方面具有较大的优越性,适合该复杂地层钻进。     

Delaunay三角网的并行构网算法

针对传统的Delaunay三角网的并行构建算法负载均衡性不高、运行效率较低等问题,该文在综合逐点插入算法和分治算法各自优点的基础上,提出了一种Delaunay三角网并行构建算法。该算法首先使用动态格网剖分点要素集,从而得到若干点要素子集;然后根据点要素子集数量初始化线程池,每个点要素子集由一个线程按照插入点法构建Delaunay子网;当所有线程完成子三角网构建,最后使用逐点插入法合并所有子网,从而实现所有点要素的Delaunay三角网构建。分析与实验结果表明,相对于传统的并行算法,该并行算法的负载均衡性好、运行时间少、加速比高,具有较好的构建效率,而且构建结果满足Delaunay规则。     

金刚石中的矿物包裹体

山东、辽宁金伯利岩区金刚石中的矿物包裹体是单晶相及多晶相的。大部分原生矿物包裹体为橄榄石,也有铬尖晶石、镁铝榴石、单斜辉石、斜方辉石、自然铁、针镍矿、柯石英、方解石及石墨。云母为后生包裹体矿物。橄榄石包裹体矿物富含Fo及Cr_2O_3。镁铝榴石矿物包裹体为紫红色,含Cr_2O_3,MgO及镁铬榴石分子高,形成压力为7.5GPa。单斜辉石包裹体矿物为绿色,形成温度和压力分别为:1531℃和4.5GPa。铬尖晶石包裹体矿物含Cr_2O_3及Cr/(Cr+Al)比值高,而含Al_2O_3低。柯石英的SiO_2含量为99.15％。自然铁含有少量的Co,Ni。针镍矿在金刚石中较常见。在橄榄石矿物包裹体内,见有方解石产出,其为同生矿物包裹体。     

Tectonic Framework and Evolution of the Dabie Mountains in Anhui, Eastern China

The Dabie Mountains are believed to be a collisional orogenic belt between the Yangtze amd Sino-Koreancontinental plates. It is composed of the foreland fold-thrust zone, the subducting cover and basement of theYangtze continental plate, the coesite- and diamond-bearing ultra-high pressure metamorphic zone and themeta-ophiolitic melange zone in the subducting basement, the fore-arc flysch nappe and the back thrust zoneoccurring respectively on the southern and northern margins of the Sino-Korean continental plate and the in-herited basin with molassic deposits on the northern margin. When the palaeo-Dabie oceanic plate subductednorthward in the Early Palaeozoic, volcanic arc and back arc basin probably formed on the southern margin ofthe Sino-Korean continental plate. The Sm / Nd isotopic dating of the strata and eclogite which were drawn in-to the foreland fold-thrust zone indicates that the intense collision of the two continental plates took place inthe Early Mesozoic.     

浅谈微粒金刚石在找矿中的作用

微粒金刚石是指粒度<0.5mm的金刚石,用作找矿指示矿物可帮助发现不含或少含其他找矿指示矿物的金刚石原生矿。找矿中遇到可疑的风化岩体,筛取<4mm的泥砂,细砾样品40kg,运回室内加工处理,淘洗时水中应加入肥皂水,使泥水表面起一层皂泡,以防微粒金刚石悬浮进入废弃的尾泥中。磁选后对<0.5mm无磁性精矿采用磁液電力分离仪选取微粒金刚石。     

上海地区重磁场特征与断裂构造关系初探

本文介绍了利用重磁场及其向上延拓计算资料,分析研究重磁场的空间变化特征。文中结合有关地质资料着重探讨了重磁场特征与断裂构造的关系,然后解释推断出上海及邻近地区的20条断裂带。     

无色-近无色高温高压合成钻石的谱图特征及其鉴别方法

实验室发现大量小颗粒的无色高温高压(HPHT)合成钻石与天然钻石混杂镶嵌在各种饰品中,前人提出荧光和磷光特征是主要的快速区分特征,然而荧光、磷光特征的差异并不能完全将HPHT合成钻石与天然钻石区分开来。本文将常规的宝石学观察分析与多种高精度谱学测试相结合,对五粒不同的无色-近无色HPHT合成钻石样品进行深入研究。结果表明,五粒钻石在紫外可见吸收光谱无270 nm吸收或是只有极弱的270 nm吸收,随着颜色级别的降低,270 nm吸收越明显。红外光谱测试显示,各粒样品中都含有不等量的硼元素。光致发光光谱测试表明,HPHT合成钻石含有与微量N、Ni、Si等相关的晶格缺陷。超短波紫外光源激发下,所有的HPHT合成钻石都有强磷光,在钻石观察仪下可以观测到清晰的八面体和立方体分区特征。显然,不同的合成钻石的特征略有差异,但综合其荧光及磷光特征以及红外、紫外、光致发光光谱特征,可以准确地将无色HPHT合成钻石与对应的天然钻石区分开来。