污染土壤中多环芳烃的微生物降解及其机理研究进展

多环芳烃(PAHs)是一类普遍存在于环境中的难降解危险性“三致”有机污染物。微生物对多环芳烃的降解是去除土壤中多环芳烃的主要途径。研究表明，对于土壤中低分子量多环芳烃类化合物，微生物一般以唯一碳源方式代谢；而大多数细菌和真菌对四环或四环以上的多环芳烃的降解作用一般以共代谢方式开始。本文重点论述了高分子量多环芳烃：芘和苯并(a)芘的微生物降解及其机理。并介绍了多环芳烃污染的微生物—植物联合修复机制，最后展望了污染土壤中多环芳烃的研究趋势。     

Influence of Structural Non-Stationarity of Surface Roughness on Morphological Characterization and Mechanical Deformation of Rock Joints

Summary Structural non-stationarity of surface roughness affects accurate morphological characterization as well as mechanical behaviour of rock joints at the laboratory scale using samples with a size below the stationarity threshold. In this paper, the effect of structural non-stationarity of surface roughness is investigated by studying the scale dependence of surface roughness and mechanical behaviour of rock joints. The results show that the structural non-stationarity mainly affects the accurate characterization of the surface roughness of the fracture samples. It also controls the amount and location of the contact areas during shear tests, which in turn affects the mechanical properties and asperity degradation of the samples. It is concluded that for accurate determination of the morphological and mechanical properties of rock joints at laboratory and field scales, samples with size equal to or larger than the stationarity threshold are required. Author’s address: Nader Fardin, Rock Mechanics Group, Department of Mining Engineering, Faculty of Engineering, University of Tehran, P.O. Box: 11365/4563, Tehran, Iran     

青海湖流域植被盖度时空变化研究

高寒区植被变化一直是气候和生态学领域关注的热点问题。本研究基于MODIS NDVI数据计算的植被覆盖度数据和高分辨率气象数据,分析了青海湖流域2001-2017年植被覆盖度分布格局及动态变化,探讨了其对气候变化、人类活动和冻土退化的响应。结果表明：① 近十几年青海湖流域植被覆盖度整体表现为增加趋势,不同植被类型增幅存在差异性,草地增幅最大,达到6.1%/10a,其它植被类型增幅在2%~3%/10a之间;② 流域局部地区仍存在植被退化现象,研究期植被退化面积表现为先增加后减小的变化趋势。2006-2011年重度退化区集中在青海湖东岸,2011-2017年重度退化区集中在流域的西北部,这些区域是青海湖流域荒漠分布区,植被覆盖度较低,是今后生态恢复需重点关注的区域;③ 气候变化是流域植被覆盖度变化的主导因素,气候变化对青海湖流域主要植被类型覆盖度变化的贡献率为84.21%,对草原、草甸和灌丛植被覆盖度变化的贡献率分别为81.84%、87.47%和75.96%;④ 人类活动对流域主要植被类型覆盖度变化的贡献率为15.79%,对草原、草甸和灌丛植被覆盖度变化的贡献率分别为18.16%、12.53%和24.04%,环青海湖地区人类活动对植被恢复有促进效应,在青海湖流域北部部分地区人类活动的破坏力度仍大于建设力度;⑤ 冻土退化对青海湖流域草甸和灌丛植被覆盖度变化影响很小,主要影响草原植被覆盖度变化,冻土退化造成草原植被覆盖度增长速率减小了1.2%/10a。     

中国海岸湿地退化压力因素的综合分析

对我国海岸湿地类型、特点和分布进行了论述.通过分析指出围垦、城市与港口开发、污染、海岸侵蚀、油气资源开发、生物资源过度利用和海平面上升等环境压力因素是造成湿地退化的主要原因.综合矩阵因子分析表明,不同的海岸湿地类型所承受的环境压力和所遭受的环境退化程度是不同的,其中三角洲、海岸潟湖、砂质海岸、珊瑚礁、淤泥质海岸、滨岸沼泽和红树林等湿地类型遭受的环境压力最大,环境退化也最严重;指出了人为因素是造成海岸湿地环境退化的主要原因.     

三峡水库碳酸盐岩区岩溶作用与斜坡破坏

三峡水库峡谷区矗立着大量岩溶不稳定库岸,危及长江黄金水道安全。采用野外勘查和力学分析,对三峡库区碳酸盐岩区岩溶作用与斜坡破坏关系进行深入研究。野外勘查发现,三峡库区碳酸盐岩库岸存在许多与溶洞、溶隙、溶蚀带、溶槽、溶沟等表层岩溶作用有关的斜坡不稳定现象。巫峡段库岸内共发育岩溶地质灾害及隐患点186处,其中滑坡隐患点37处,大型以上危岩体6个。岩体力学分析表明：强降雨、蓄水和岩体劣化会因为有效应力减少、强度下降而造成破裂的节理/裂隙逐渐扩大。同时,水位变动带岩体劣化的裂缝扩展速率比三峡的平均溶蚀率高出约1 300倍,极大地加快了已经进入屈服状态的不稳定岩体的演化进程。溶蚀作用是岩溶岸坡中最基本的作用,库水长期波动加快了岩溶岸坡演化。本次研究将为三峡库区峡谷段不稳定库岸识别和防灾减灾提供技术支撑。     

SiO2-TiO2薄膜制备及其光催化性能研究

Sol-gel法制备SiO2-TiO2复合薄膜，进行甲醛的光催化降解实验，研究了SiO2掺杂量、薄膜焙烧温度、甲醛溶液pH值及初始浓度对光催化性能的影响。结果表明，500℃焙烧1h，掺杂质量SiO2：TiO2=12：100时，SiO2-TiO2薄膜的光催化活性最高，150min后甲醛降解率达76％，是单纯TiO2薄膜的1．3倍，该薄膜稳定性较好，经重复8次使用，最大降解率只下降4％。     

实验室条件下微生物降解原油的地球化学特征研究

通过对胜利油田四个正常原油样品微生物作用前后的族组分及饱和烃色谱质谱分析,发现实验室条件下微生物对原油有明显的降解作用。微生物作用以后的原油族组分其饱和烃相对含量降低,饱/芳比也明显降低,而芳烃、非烃和沥青质的相对含量都不同程度的升高。通过饱和烃色谱-质谱分析,发现微生物作用以后原油正构烷烃被严重降解,姥/植(Pr/Ph)比值和∑C_21-/∑C₂₂₊比值都明显降低。微生物作用原油后能产生表面活性剂,造成了培养基表面张力的降低。     

Monitoring and methods to analyse the groundwater quality degradation risk in coastal karstic aquifers (Apulia,Southern Italy)

A multi-methodological approach based on monitoring and spatio-temporal analysis of groundwater quality changes is proposed. The presented tools are simple, quick and cost-effective to give service to all sorts of users. The chief purpose of the monitoring network is the detection of the piezometric or potenziometric level in the aquifer. The spatial and multi-temporal analysis of usual chemical and physical data provides both an assessment of the spatial vulnerability of the aquifer to seawater intrusion, defining a salinity threshold between fresh groundwater and brackish groundwater and of the water quality trend in terms of salinity. The evaluation of the salinity trend or of salinity-correlated parameters highlights the effects of groundwater mismanagement. The multiparameter logging provides a rapid groundwater quality classification for each well. The whole approach allows evaluating the effects of current management criteria and designing more appropriate management targets. The Apulian karstic coastal aquifers have been selected as a case study (Southern Italy). Three types of aquifer zones can be distinguished: (1) areas with low vulnerability to seawater intrusion, (2) areas with high vulnerability and (3) areas with variable vulnerability in which the salt degradation largely depends on the ability to manage the well discharge. The water quality degradation caused by seawater intrusion appears to be a combined effect of an anomalous succession of drought periods observed from about 1980 onwards and increased groundwater pumping, particularly during drought periods. A management criterion based on aquifer zones is proposed.     

草地退化的地质指标体系

借鉴国际地质指标工作组提出的地质指标概念,从分析草地退化的各种影响因素及其对演化过程的控制作用,以及草地生态系统退化过程中的各种响应关系入手,按照“影响-状态-后果模型”（CSR模型）和“压力-状态-响应模型”（PSR模型）构建了草地退化地质指标体系。     

中国东部亚热带丘陵山地土地退化评价指标体系研究*

中国东部亚热带地区流水侵蚀所引起土地退化的形成,是由其生态环境自身的脆弱性决定的。土地退化不仅表现为土壤退化,还表现为植被退化和土地状况恶化,其发展过程是植被退化-土壤退化-地表状况恶化过程多重循环的结果。据此,提出了中国东部亚热带丘陵山地土地退化评价指标。