泰山太古宙岩浆杂岩体的岩石化学和地球化学特征

本文将泰山岩浆杂岩分为两个成因系列,即:壳源深熔花岗岩系列,包括所有花岗岩;岩浆分异型闪长岩系列,包括所有闪长岩。     

新疆北部晚古生代以来中基性岩脉的年代学、岩石学、地球化学研究

新疆北部中基性岩脉K-Ar表观年龄为187～271Ma,岩性以辉长、辉绿岩以及闪长、闪长玢岩为主,属于亚碱性系列.主量元素、稀土元素以及微量元素分析表明,中基性岩脉经历了源区地壳物质的混合以及侵位过程中的分离结晶作用,并在区域分布特点上受部分熔融程度的影响,而且由于结晶分异和部分熔融的不同,还出现了中基性岩脉系列的成分变异.排除上述岩浆作用的干扰,有证据显示岩脉起源于亏损地幔,由于Nd同位素模式年龄tDM集中在363～769Ma,反映源区是一个古生代时期的新生岩石圈地幔,该地幔源区属于大洋岩石圈地幔.新疆北部广泛出露的中基性岩脉在时间和空间上具有多样性,但是在产状、岩性组合和同位素特征上具有相似的特点,指示研究区在古生代以来具有一个相对统一和完整的源区,推测这个源区与北疆地区古生代以来长期存在的残余洋盆及其相关岩石圈有关.     

锆石中钛温度计在鲁西—苏北地区中生代侵入杂岩中的应用

利用锆石中钛地质温度计对鲁西—苏北地区出露的8个中生代侵入杂岩的岩浆岩结晶温度进行计算,结果表明研究区斑井岩体的平均岩浆结晶温度为715~716℃,蔡山岩体为653℃,丰山岩体为697℃,夹沟岩体为711℃,利国岩体为737℃,铁铜沟岩体为766℃,上峪岩体为889℃,金岭岩体为770℃。岩体的岩浆结晶温度沿侵入杂岩带展布方向,从S到N依次增高,暗示其岩浆起源深度逐渐加大。岩浆结晶温度计算结果大致限定了各岩体的岩浆源区深度范围,结合锆石寄主岩石和寄主岩石中的深源包体的研究表明研究区中生代侵入杂岩体的母岩浆起源于上地幔和/或下地壳。     

斑岩型Au矿床的包裹体标志:以黑龙江金厂金矿矿床为例

通过对黑龙江金厂金矿床和河北蔡家营铅．锌．银矿床的对比研究,发现斑岩中包裹体的演化和成分特征反映了成矿流体的演化、成矿能力和矿床成因,对这类矿床的找矿评价也具有一定的参考价值。金厂金矿床中代表岩浆演化各个阶段的包裹体类型完全,且包裹体富含盐类、成矿物质和挥发组分,表明该区岩浆结晶分异作用完善、具有较强的成矿能力,能形成斑岩型矿床。而河北蔡家营铅-锌-银矿床,斑岩中只有硅酸盐玻璃包裹体和后期盐水溶液包裹体,反映该岩浆分异演化程度不高、分异作用极不完善。含盐度较高而且大量挥发组分的存在可能是后期热液活化萃取围岩成矿物质的重要因素。     

Mafic and Felsic Magma Interaction in Granites: the Hercynian Karkonosze Pluton (Sudetes, Bohemian Massif)

The Hercynian, post-collisional Karkonosze pluton contains severallithologies: equigranular and porphyritic granites, hybrid quartzdiorites and granodiorites, microgranular magmatic enclaves,and composite and lamprophyre dykes. Field relationships, mineralogyand major- and trace-element geochemistry show that: (1) theequigranular granite is differentiated and evolved by smalldegrees of fractional crystallization and that it is free ofcontamination by mafic magma; (2) all other components are affectedby mixing. The end-members of the mixing process were a porphyriticgranite and a mafic lamprophyre. The degree of mixing variedwidely depending on both place and time. All of the processesinvolved are assessed quantitatively with the following conclusions.Most of the pluton was affected by mixing, implying that hugevolumes (>75 km³) of mafic magma were available. This maficmagma probably supplied the additional heat necessary to initiatecrustal melting; part of this heat could have also been releasedas latent heat of crystallization. Only a very small part ofthe Karkonosze granite escaped interaction with mafic magma,specifically the equigranular granite and a subordinate partof the porphyritic granite. Minerals from these facies are compositionallyhomogeneous and/or normally zoned, which, together with geochemicalmodelling, indicates that they evolved by small degrees of fractionalcrystallization (<20%). Accessory minerals played an importantrole during magmatic differentiation and, thus, the fractionalcrystallization history is better recorded by trace rather thanby major elements. The interactions between mafic and felsicmagmas reflect their viscosity contrast. With increasing viscositycontrast, the magmatic relationships change from homogeneous,hybrid quartz diorites–granodiorites, to rounded magmaticenclaves, to composite dykes and finally to dykes with chilledmargins. These relationships indicate that injection of maficmagma into the granite took place over the whole crystallizationhistory. Consequently, a long-lived mafic source coexisted togetherwith the granite magma. Mafic magmas were derived either directlyfrom the mantle or via one or more crustal storage reservoirs.Compatible element abundances (e.g. Ni) show that the maficmagmas that interacted with the granite were progressively poorerin Ni in the order hybrid quartz diorites—granodiorites—enclaves—compositedykes. This indicates that the felsic and mafic magmas evolvedindependently, which, in the case of the Karkonosze granite,favours a deep-seated magma chamber rather than a continuousflux from mantle. Two magma sources (mantle and crust) coexisted,and melted almost contemporaneously; the two reservoirs evolvedindependently by fractional crystallization. However, maficmagma was continuously being intruded into the crystallizinggranite, with more or less complete mixing. Several lines ofevidence (e.g. magmatic flux structures, incorporation of granitefeldspars into mafic magma, feldspar zoning with fluctuatingtrace element patterns reflecting rapid changes in magma composition)indicate that, during its emplacement and crystallization, thegranite body was affected by strong internal movements. Thesewould favour more complete and efficient mixing. The systematicspatial–temporal association of lamprophyres with crustalmagmas is interpreted as indicating that their mantle sourceis a fertile peridotite, possibly enriched (metasomatized) byearlier subduction processes. KEY WORDS: Bohemian Massif; fractional crystallization; geochemical modelling; hybridization; Karkonosze     

岩浆分离结晶作用的微量元素广义初始比值计算方法

本文提出了一种如何从分异的派生岩浆追溯和反演演化前的原生岩浆的微量元素初始比值的方法。据分离结晶方程logaC_1~q=k·loga C_1~p b,得广义初始比值:C_0~q/(C_0~p)~k=a~b。它与已公认的原生岩浆的判别参数如~(87)Sr/~(86)初始比、δ~(18)O‰、SI、Mg′值及微量元素丰度等有极好的一致性。并将这种方法应用于两个实例,得出大宁花岗闪长岩及其暗色微粒包体分属壳源和幔源;五大连池富钾火山岩的原生岩浆为白榴苦橄碧玄岩浆,而其中的超镁铁质岩包体则是分离结晶的火成堆晶体。     

西南极菲尔德斯半岛第三纪钙碱性火山岩的生成与演化

西南极菲尔德斯半岛第三纪火山岩的岩石学和岩石化学特征表明,它们基本属于钙碱性火山岩系列,是岛弧火山作用的产物。该岩石组合中,随岩石中SiO_2含量的增加,斜长石斑晶数量减少,微量元素Cr、V丰度降低,Sr、Ba丰度下降,这些揭示了岩浆中斜长石和单斜辉石的分离结晶作用。稀土元素的系统变化也证明了这一点。主元素和微量元素的定量计算所验证了岩浆的分离结晶作用演化过程。     

Crystallization of microlites during magma ascent: the fluid mechanics of 1980–1986 eruptions at Mount St Helens

Eruptions of Mount St Helens (Washington, USA) decreased in intensity and explosivity after the main May 18, 1980 eruption. As the post-May 18 eruptions progressed, albitic plagioclase microlites began to appear in the matrix glass, although the bulk composition of erupted products, the phenocryst compositions and magmatic temperatures remained fairly constant. Equilibrium experiments on a Mount St Helens white pumice show that at 160 MPa water pressure and 900°C, conditions deduced for the 8 km deep magma storage zone, the stable plagioclase is An₄₇. The microlites in the natural samples, which are more albitic, had to grow at lower water pressures during ascent. Isothermal decompression experiments reported here demonstrate that a decrease in water pressure from 160 to 2 MPa over four to eight days is capable of producing the albitic groundmass plagioclase and evolved melt compositions observed in post-May 18 1980 dacites. Because groundmass crystallization occurs over a period of days during and after decreases in pressure, microlite crystallization in the Mount St Helens dacites must have occurred during the ascent of each magma batch from a deep reservoir rather than continuously in a shallow holding chamber. This is consistent with data on the kinetics of amphibole breakdown, which require that a significant portion of magma vented in each eruption ascended from a depth of at least 6.5 km (160 MPa water pressure) in a matter of days. The size and shape of the microlite population have not been studied because of the small size of the experimental samples; it is possible that the texture continues to mature long after chemical equilibrium is approached. As the temperature, composition, crystal content and water content of magma in the deep reservoir remained approximately constant from May 1980 to at least March 1982, the spectacular decrease in eruption intensity during this period cannot be attributed to changes in viscosity or density of the magma. Simple fluld mechanical considerations indicate, however, that the observed changes in mass flux of magma can be modelled by a five-fold decrease in conduit radius from 35 to 7 m, produced perhaps by plating of magma along the conduit walls. The decreased ascent rates which accompanied the decrease in conduit radius can explain the change from closed-system to open-system degassing and the shift from explosive to effusive eruptions during 1980.     

CaCO3生物矿化的研究进展——有机质的控制作用

生物CaCO₃是自然界分布最广泛的一类生物矿物,其组成除了无机相的CaCO₃外,还含有少量的有机质,包括水可溶(SM)和水不可溶有机质(IM),SM富含阴离子基团,是控制CaCO₃结晶的重要因素之一。通过有机—无机界面分子识别,有机质选择性地与CaCO₃晶体特定方向的面网相互作用,从而对CaCO₃的生长、形貌、多型及结晶学定向等产生明显的控制作用。有机—无机界面的分子识别机制包括静电、晶格几何匹配和立体化学互补等。仿生矿化的研究为进一步深入了解生物矿化的机理及制造高级复合材料提供了新的方法。