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61.
62.
为分析冷云中冰晶的分布特征,揭示冰晶增长演变机制,根据冰晶形状和尺度特征分为8类并进行标注,同时标注1类隔断栏进行数据质量控制,将9类标签图像整合并建立图像集,利用迁移学习VGGNet16方法进行识别训练,经训练模型分类准确率达98%。将模型应用到秋季冷云冰晶特征研究中,选取3次积层混合云和3次层状云降水过程,分析冰晶形状在不同温度区间的占比及冰晶谱变化特征,结果表明,温度通过影响冰晶基面与棱面的比值来决定冰晶初始形状分布,相同温度区间积层混合云内球状冰晶和线型冰晶占比高于层状云,低于-12℃后各类冰晶占比相对固定;积层混合云内线型冰晶直径集中在300~800 μm,冰晶谱呈多峰分布,聚合体直径大于600 μm,冰晶谱首尾两端浓度相当,球状冰晶直径集中在120~300 μm,冰晶谱呈单调下降趋势。 相似文献
63.
I. S. Williams 《Australian Journal of Earth Sciences》2013,60(4):557-580
Progressive Early Silurian low‐pressure greenschist to granulite facies regional metamorphism of Ordovician flysch at Cooma, southeastern Australia, had different effects on detrital zircon and monazite and their U–Pb isotopic systems. Monazite began to dissolve at lower amphibolite facies, virtually disappearing by upper amphibolite facies, above which it began to regrow, becoming most coarsely grained in migmatite leucosome and the anatectic Cooma Granodiorite. Detrital monazite U–Pb ages survived through mid‐amphibolite facies, but not to higher grade. Monazite in the migmatite and granodiorite records only metamorphism and granite genesis at 432.8 ± 3.5 Ma. Detrital zircon was unaffected by metamorphism until the inception of partial melting, when platelets of new zircon precipitated in preferred orientations on the surface of the grains. These amalgamated to wholly enclose the grains in new growth, characterised by the development of {211} crystal faces, in the migmatite and granodiorite. New growth, although maximum in the leucosome, was best dated in the granodiorite at 435.2 ± 6.3 Ma. The combined best estimate for the age of metamorphism and granite genesis is 433.4 ± 3.1 Ma. Detrital zircon U–Pb ages were preserved unmodified throughout metamorphism and magma genesis and indicate derivation of the Cooma Granodiorite from Lower Palaeozoic source rocks with the same protolith as the Ordovician sediments, not Precambrian basement. Cooling of the metamorphic complex was relatively slow (average ~12°C/106y from ~730 to ~170°C), more consistent with the unroofing of a regional thermal high than cooling of an igneous intrusion. The ages of detrital zircon and monazite from the Ordovician flysch (dominantly composite populations 600–500 Ma and 1.2–0.9 Ga old) indicate its derivation from a source remote from the Australian craton. 相似文献
64.
65.
A garnet population in Yellowknife schist, Canada 总被引:6,自引:0,他引:6
R. KRETZ 《Journal of Metamorphic Geology》1993,11(1):101-120
Abstract Data are presented on a garnet population in a specimen of garnet-biotite-plagioclase-quartz schist from the cordierite zone of an Archaean thermal dome in the Southern Slave Province of the Canadian Shield. Garnet crystals are bounded by planar dodecahedral faces and by trapezohedral faces which on the 10-μm scale are corrugated. Crystal distribution, as revealed by dissection of a small cubic volume of rock, is random. The size distribution is normal, with a mean diameter of 0.81 mm and a standard deviation of 0.32 mm. In the largest crystal of the population (mean radius 0.83 mm), [Mn] = 100 Mn/(Fe + Mg + Mn + Ca) decreases from 14.5 at the centre to 7.5 and then increases in the outer margin to 8.5; [Fe] increases continuously from 67 at the centre to 77 at the surface; [Mg] increases from 12.5 to 13.5 and then falls sharply to 11; [Ca] remains unchanged at 4.0 and then drops to 3.3. Progressively smaller crystals have progressively lower [Mn] and higher [Fe] concentrations at their centres, while all crystals have the same margin composition. Growth vectors extending from given concentration contours to crystal surfaces are of equal length regardless of the size of the crystal in which the vector is located. A garnet-forming model is presented in which reaction was initiated by a rise in temperature. Nucleation sites were randomly selected. The nucleation rate increased with time and then declined. Crystal faces advanced at a constant linear rate, which implies an increase in volume proportional to surface area. Initially, the composition of garnet deposited on crystal surfaces was determined by van Laar equations of equilibrium, which demanded the withdrawal of Mn and Fe from within chlorite crystals. This transfer reaction was then accompanied by an ion exchange reaction which moved Mn and Fe to garnet surfaces from biotite, in exchange for Mg. The exchange reaction provides an explanation for the high overall concentration of Mn and Fe in garnet and for the observed Mn and Mg reversals in the margins of crystals. The increase of garnet volume in the garnet population is found to be parabolic, i.e. Vαα5. 相似文献
66.
根据微量元素e1、e2、e3总分配系数的相对大小,源区混合-结晶分异复合过程在它们的比值-比值相关图上造成三种综合效应。新疆阿尔泰花岗岩微量元素的比值-比值相关图清晰地反映了三种效应,暗示着源区混合-结晶分异复合过程。源区混合机制可能为沉积物质在沉积盆地里的掺合。混合端员可能为:1)成熟度差异悬殊的陆源碎屑物质;2)陆源碎屑与基性火山物质。 相似文献
67.
68.
本矿物为新发现的钇易解石族的端员矿物-钛钇易解石,产于江西省龙南县足洞燕山期中粒白云母花岗岩及其风化壳中。矿物属斜方晶系,常呈板状或短柱状,为天然晶质体,浅黄色,粒度为0.075mm,硬度4.7,比重4.73,二轴正晶,Ng=2.248,Nm=2.212,Np=2.194,Ng-Np=0.054,2V=70°。空间群为D^162h-Pmnb,a0=0.750nm,b0=1.092nm,C0=0.5 相似文献
69.
Summary The crystal structure of hendricksite, a trioctahedral mica of biotite type, characterized by high Zn2+ and Mn2+ contents has been refined by least square methods. The structural formula is: (K0.89Na0.10Ba0.04)(Mg1.57Zn0.54Mn
0.40
2+
Fe
0.25
2+
Al0.07Ti0.07Cr0.01)(Si2.92Al1.08)O10 (OH)2. The space group isC2/m and the cell parameters are:a=5.340(2) Å,b=9.524(2) Å,c=10.235(3) Å, =100.07(2)o, the cell volume isV=497.98 Å3. The final unweightedR=0.072. Average cation-anion distances in polyhedra are: T–O=1.659 Å, M(1)–O=2.093 Å, M(2)–O=2.088 Å, A–Olong=3.316 Å and A–Oshort=3.004 Å; A is the alkaline cation. The rotation angle of tetrahedra is =6.7°. The analysis of electron densities, of the dimensions and distorsions of polyhedra shows that Zn2+ is exclusively in octahedral sites; there is no order between six-fold coordinated cations. A comparison between the structural features of hendricksite and those of the two main end-members of biotites, phlogopite and annite, is presented.The effect of the strong covalence of Zn–O bonds is particularly visible on the dimensions and orientations of the thermal ellipsoids of octahedral sites M(1) and M(2) which contain zinc. In all the published structures of trioctahedral micas, the ellipsoids of cationic sites are uniaxial positive, elongated parallel toc
*. In hendricksite, this is observed only for the two zinc-free sites (T and A; in the octahedra M(1) and M(2), which contain zinc, the ellipsoids are approximately uniaxial negative, flattened parallel toa, which is a unique situation.Zinc which habitually favours the tetrahedral coordinations with oxygen, enters the octahedra only, i.e. the chemically anisotropic sites, in hendricksite. The strong polarizability of Zn2+ is proposed to explain this behaviour.An examination of the behaviour of Zn2+ in other compounds shows that this situation is general, zinc favours chemically anisotropic sites and specially those adjacent to OH or H2O.
Affinement de la structure cristalline de la hendricksite, mica trioctaédrique potassique riche en Zn et Mn; une contribution à la connaissance cristallochimique des minéraux zincifères
Résumé On a affiné par moindres carrés la structure de la hendricksite, mica trioctaédrique de type biotite, caractérisé par une teneur élevée en Zn2+ et Mn2+. La formule structurale de ce mica est: (K0m89Na0,10Ba0,04)(Mg1,57Zn0,54Mn 0,40 2+ Fe 0,25 2+ Al0,07Ti0,07Cr0,01)(Si2,92Al1,08)O10(OH)2. Le groupe spatial estC2/m et les paramètres de la maille:a=5,340(2) Å,b=9,254(2) Å,c=10,235(3) Å, =100,07(2)°; le volume de la maille estV=497,98 Å3. Le résidu final non-pondéré estR=0,072. Les distances cation-anion moyennes dans les polyèdres sont les suivantes: T–O=1,659 Å, M(1)–O=2,093 Å, M(2)–O=2,088 Å, A–Olong=3,316 Å et A–Ocourt=3,004 Å où A désigne le cation alcalin. L'angle de rotation tétraédrique, =6,7°, est très semblable à celui de la phlogopite. L'analyse des densités électroniques, des dimensions et distorsions des polyèdres montre que Zn2+ est exclusivement en coordinance octaédrique et qu'il n'y a pas d'ordre entre les cations hexacoordonnés. On présente une comparaison des caractères structuraux de la hendricksite avec ceux des deux principaux pôles des biotites, la phlogopite et l'annite.L'effet de la forte covalence de la liaison Zn–O est particulièrement visible sur les dimensions et orientations des ellipsoides d'agitation thermique des deux sites octaédriques, sites zincifères. Dans toutes les structures de micas trioctaédriques publiées, les ellipsoides des sites cationiques sont uniaxes positifs, allongés parallèlement àc *, ce qui s' observe effectivement dans les deux sites non-zincifères (T et A) de la hendricksite, par contre, dans les octaèdres M(1) et M(2), qui contiennent le zinc, les ellipsoides sont approximativement uniaxes négatifs, applatis parallèlement àa, ce qui est une situation unique.Le zinc, qui se fixe généralement en sites tétraédriques dans les structures de type oxyde, occupe les sites octaédriques, c'est-à-dire les sites chimiquement anisotropes dans la hendricksite. La forte polarisabilité de Zn2+ est proposée pour expliquer ce comportement.Un examen du comportement de Zn2+ dans d'autres phases montre que cette situation est tout à fait générale, le zinc privilégiant les sites chimiquement anisotropes et en particulier ceux adjacents à OH où H2O.相似文献
70.
通过衍射线指标和面网指标的联系讨论了晶体的对称性对衍射指标h和k互换的影响。在下列情况下衍射指标h和k是不能互换的:在低级晶族;在四方晶系C_(4h)—4/m劳厄点群,六方品系C_(6h)—6/m劳厄点群和立方晶系T_h—m3劳厄点群对于hko和kkl型衍射;在三方晶系选取六方晶胞的情况下,在C_(3i)—3劳厄点群对于hol,okl,hko和hkl型衍射,在D_(3d)—3m劳厄点群对于holokl和hkl型衍射,以及在菱面体点阵除非h和k都是三的倍数。 相似文献