Transport of dissolved methoxy-nonafluorobutane through a saturated column

Solute transport experiments were conducted in a one-dimensional saturated column using dissolved methoxy-nonafluorobutane (HFE-7100), a Novec engineered fluid developed by the 3M Corporation, as the solute. Novec engineered fluids are considered dense non-aqueous phase liquids (DNAPLs) because they are immiscible with water and have a specific gravity greater than one. The HFE-7100 fluid is safer and environmentally friendlier than common DNAPL contaminants such as tetrachloroethylene (PCE) or trichloroethylene (TCE); thus, it is an ideal substitute DNAPL for laboratory groundwater contamination research. Three sets of solute transport experiments were conducted. The first set of experiments was conducted in a glass-bead-packed column using dissolved HFE-7100 as the solute. The second set of experiments was conducted in a sand-packed column using dissolved HFE-7100 as the solute. The third set of experiments was conducted in a sand-packed column using dissolved PCE as the solute. The dissolved HFE-7100 column breakthrough concentrations were compared with dissolved PCE breakthrough concentrations. Results show that the one-dimensional solute transport equation was successful in describing the transport behavior of dissolved HFE-7100. This study demonstrates that the HFE-7100 fluid can be used as a safer substitute DNAPL for groundwater contaminant dissolution and transport research.     

Contrasting komatiite belts,associated Ni–Cu–(PGE) deposit styles and assimilation histories

The Agnew–Wiluna greenstone belt in the Yilgarn Craton of Western Australia is the most nickel-sulfide-endowed komatiite belt in the world. The Agnew–Wiluna greenstone belt contains two mineralised units/horizons that display very different volcanological and geochemical features. The Mt Keith unit comprises >500 m-thick spinifex-free adcumulate-textured lenses, which are flanked by laterally extensive orthocumulate-textured units. Spinifex texture is absent from this unit. Disseminated nickel sulfides, interstitial to former olivine crystals, are concentrated in the lensoidal areas. Massive sulfides are locally present along the base or margins of the lenses or channels. The Cliffs unit is locally >150 m thick and comprises a sequence of differentiated spinifex-textured flow units. The basal unit is the thickest, and contains basal massive nickel-sulfide mineralisation. The Mt Keith and Cliffs units display important common features: (i) MgO contents of 25–30% in inferred parental magmas; and (ii) Al/Ti ratios of ～20 (Munro-type). However, the Mt Keith unit is highly crustally contaminated (e.g. LREE-enriched, high HFSEs), whereas the Cliffs unit does not display evidence of significant crustal assimilation. We argue that the distinct trace-element concentrations and profiles of the two komatiite units reflect their different emplacement style and country rocks: the Mt Keith unit is interpreted to have been emplaced as an intrusive sill into dacitic volcanic units whereas the Cliffs unit was extruded as lava flow onto tholeiitic basalts in a subaqueous environment. The mode of emplacement and nature of country rock is the single biggest factor in controlling mineralisation styles in komatiites. On the other hand, evidence of crustal contamination does not necessarily provide information of the prospectivity of komatiites to host Ni–Cu–(PGE) mineralisation, despite being a good proxy for the style of komatiite emplacement and the nature of country rocks.     

SOURCE RADIATION AND RESPONSES OF WAVE PROPAGATION

Recordings of seismic waves propagating from earthquake source to a station at the earth's surface are a system response function.The convolution operator in time domain can be simplified as a multiplication operator in frequency domain.We discuss in frequency domain the separation of source,path and site effects for global scaling of earthquake source radiation.Also discussed are source scaling model,faulting mechanism,and the H/V inversion problems with crustal and near surface structures.Gross features of apparent source spectra appear to be not much region-dependent although there may be difference between tectonic styles within a region of tectonic mixture for which we need further study as data accumulate.Vertical spectra may be a better approach to approximate source radiation,as it has less crustal amplification effects than horizontal spectra.The H/V ratio is evidently a comprehensive indicator of amplification effects from near surface to deep structure.This gives it potential as an inversion tool to deduce site crustal structure.     

甘蒙北山北带古生代地壳演化与成矿作用

北山北带古生代期间先后经历了两期板块构造体制和两次主要的造山作用。早古生代以沙泉子—明水—小黄山蛇绿岩带洋壳残片,显示俯冲带的存在,早泥盆世闭合、碰撞造山,这是早期板块体制。与此同时形成了一系列的金属矿床（点）,比如方山口、双鹰山和塔水等钒—磷—铀或磷矿床（点）,白云山—东七一山火山热液—沉积型的铜铁矿床（点）,公婆泉...     

Distribution of heavy metals in soils of Port Harcourt and its environs,Niger Delta,Nigeria

Geochemical evaluation of the distribution of heavy metals in soils of Port Harcourt and its environs in the Niger Delta region is presented in respect of anthropogenic factor and index of geoaccumulation. Sixteen (16) soil samples were collected from two horizons (0-10 cm and 100 cm) from the various grids and analyzed. The geo-chemical analyses showed the vertical and horizontal distributions of heavy metals. The results showed the ranges of the metals determined as follows: Pb (6.86-2.49)×10-6, with an average of 4.63×10-6; Cd (0.05-0.00)×10-6, with an average of 0.02×10-6, As (0.01-0.00)×10-6, with an average of 0.00×10-6. Cu (15.36-10.80) ×10-6, with an average of 13.36×10-6, and V (1.36-0.20)×10-6, with an average of 0.94×10-6. Quantification of the degree of pollution was carried out using anthropogenic factor (AF) and index of geoaccumulation (Igeo). The Igeo values of 0.06, 0.02 and 0.00 for Pb, Cd and As, respectively indicate low-level contamination while Zn (1.14) and V (1.40) show me-dium-level contamination. The sources of contamination are attributed to urbanized anthropogenic activities. The majority of the samples analyzed show that the AF values are less than 1 with the exception of vanadium (V) whose AF values range from 2.73 to 13.60×10-6. Vanadium is more enriched than As, Cd, Pb, and Cu. The order of degrees of anthropogenic contamination and index of geoaccumulation in the soil is V >Zn >Pb >Cu >Cd >AS. Metals were retained near the top soil and their concentrations in the deepest horizons were lower and normal for uncontaminated soils. Metal concentrations in the top soil horizons were significantly related to distance from the industrial and hu-man activities.     

Extrinsic and intrinsic forcing of fluvial development: understanding natural and anthropogenic influences

This paper introduces a special issue arising from the biennial meeting of the Fluvial Archives Group (FLAG) that took place in September 2008 in Budapest, Hungary. Combining a two-day conference and three-day field excursion, this meeting provided an excellent opportunity for presentation and discussion of recent advances in research on fluvial evolution from the Plio-Pleistocene to the historical period. This editorial seeks to place these advances within the contexts both of long-term geomorphological research and the achievements of FLAG. It thus highlights progress towards a better understanding of fluvial responses to internal and external (including anthropogenic) forcing. It also points out some of the main obstacles, which can be targeted as goals for further research. Typically these relate to observed discrepancies in fluvial system responses, such as in patterns of lateral erosion and the timing of terrace incision, despite apparently similar fluvial parameters. Possible explanations for these discrepancies are mentioned, and the potential of new methods (especially in geochronology and modelling) to clarify such discrepancies is underlined. Finally the editorial provides brief reviews of the ten papers in this special issue (many of them developed from presentations in Budapest), which cover various areas in Europe (Hungary, England, Germany, Portugal, Russia), Asia (India) and South America (Bolivian Andes), placing them, in turn, within the context of this wider review of fluvial research.     

鲁西地壳隆升的伸展构造模式

伸展链锁断层系，形成了鲁西的主导造格局，即“块断”构造。它是由中、生代两次伸展运动形成的。伸展运动幔源岩浆活动有着密切的成生联系。伸展运动的结果，形成了以泰山－鲁山－沂山为核心的鲁中块隆，它至今耸立于周围以平原地貌为标志的地堑系之间，隆起的高点，就是当今的泰山。     

中国区域地壳稳定性定量化评价与分区

中国地处环太平洋构造带与地中海构造带交接部位,地质构造复杂,活动性较为强烈,各种内动力地质灾害比较严重,总体看来中国区域地壳稳定性相对较差。为了使区域地壳稳定性评价与分区获得定量化认识,更好地服务于经济建设和减灾防灾,本文在分析中国现今活动的主要构造体系与内动力地质灾害的分布规律的基础上,首先进行区域地壳稳定性定量化评价待评区的划分;其次进行定量化评价指标的选定、取值、权重分配及评价标准的确定;最后运用模糊数学进行中国区域地壳稳定性定量化评价与分区。      

A modified DRASTIC model for Siting Confined Animal Feeding Operations in Williams County,Ohio, USA

Three of DRASTIC’s parameters (Depth to Water, Soil Media, and Topography) were modified and another parameter was added (land use/land cover) to the model to determine the potential impact on groundwater from Confined Animal Feeding Operations (CAFO) manure lagoon settings and manure application as fertilizer. Williams County is a mostly agricultural county located in northwest Ohio, USA. It currently has three CAFOs, all dairy, with the possibility of the construction of a multi-million chicken egg CAFO in the near future. A Geographic Information System (GIS) was utilized to modify the Ohio Department of Natural Resources (ODNR) DRASTIC map for the county to fully assess the county-wide pollution potential of CAFOs. The CAFO DRASTIC map indicates that almost half of Williams County has elevated groundwater pollution potential. The rest of the county, primarily the southeast corner, has lower CAFO groundwater pollution potential. Future CAFO development within the county should focus on the southeastern portion of the county where the groundwater table is deeper, and the aquifer is composed of shale substrate with low hydraulic conductivity. The CAFO DRASTIC results are intended to be used as a screening tool and are not to replace site-specific hydrogeologic investigations.     

玄武岩成分变异原因

笔者等研究发现山东栖霞和浙江西垄两地新生代玄武岩中分别产有奇特的富钾霞石质和富透长石质熔体玻璃地幔捕虏体,而且它们与寄主玄武岩之间有强烈的混染反应.表明玄武岩浆不是一元系岩浆,而是不同期多元系岩浆.多元系所占比例差别很大,决定了玄武岩浆成分的多样性.另外,此玄武岩成分也很特别:①不见斜长石,主要是铬透辉石(Mg质太多);②含有较多霞石;③全岩SiO2低,37％ ～39％.此玄武岩应称为透辉石岩.